公开(公告)号：US20020002316A1

公开(公告)日：2002-01-03

申请号：US09761781

申请日：2001-01-18

Applicant: Snamprogetti S.p.A.

Inventor： Marco Di Girolamo ,  Mario Marchionna ,  Lorenzo Tagliabue

IPC: C07C002/02 ,  C07C002/04

CPC classification number: C10G32/00 ,  C07C2/08 ,  C10G2400/02 ,  C07C11/02

Abstract: A process is described for the production of hydrocarbons with a high octane number starting from hydrocarbon cuts containing isobutene by means of selective dimerization with acid catalysts, characterized in that the dimerization reaction is carried out in a tubular reactor using a feeding containing isobutene in quantities of less than 20% by weight and with a molar ratio linear olefins/isobutene greater than 3, preferably operating at a reaction temperature ranging from 30 to 120null C., at a pressure of less than 5 MPa and at feeding space velocities of less than 60 hnull1.

公开(公告)号：US20040187380A1

公开(公告)日：2004-09-30

申请号：US10716501

申请日：2003-11-20

Applicant: ENI S.p.A. ,  SNAMPROGETTI S.p.A.

Inventor： Domenico Sanfilippo ,  Renata Patrini ,  Mario Marchionna

IPC: C10L001/18

CPC classification number: C10L1/1852 ,  C10L1/026 ,  C10L1/1985 ,  C10L10/02

Abstract: Use of a liquid oxygenated product with a cetane number higher than 50, consisting of one or more compounds selected from dialkyl-polyformals represented by the formula RO(CH2O)mR wherein R is an alkyl chain CnH2nnull1, m is an integer equal to or higher than 2, n is an integer between 1 and 10, as a substitute of gas oil in diesel engines.

Abstract translation: 使用十五烷值高于50的液体氧化产物，由一种或多种选自式RO（CH 2 O）m R表示的二烷基 - 聚异构体的化合物组成，其中R是烷基链C n H 2n + 1，m是等于 或高于2，n为1〜10的整数，作为柴油发动机中瓦斯油的替代品。

公开(公告)号：US20020183576A1

公开(公告)日：2002-12-05

申请号：US10109660

申请日：2002-04-01

Applicant: SNAMPROGETTI S.p.A.

Inventor： Cristina Flego ,  Carlo Perego ,  Mario Marchionna

IPC: C07C002/12

CPC classification number: C10G50/00 ,  C10G2400/04

Abstract: Process for obtaining a nulldiesel cutnull fuel having a CN cetane number equal to or greater than 48 and a content of aromatics lower than 0.4% by weight starting from olefins or their mixtures, characterized in that it comprises the following steps: oligomerizing said olefins having from 2 to 10 carbon atoms in the presence of synthetic zeolites containing silicon, titanium and aluminum oxides, having a molar ratio SiO2/Al2O3 ranging from 100 to 300, a molar ratio SiO2/TiO2 greater than 41 and a extraframework titanium oxide content which is zero or less than 25% with respect to the whole titanium oxide present, at a temperature ranging from 180 to 300null C., at a pressure greater than 40 atm and a WHSV space velocity equal to or greater than 1 hnull1, in order to obtain a stream essentially consisting of oligomerized C5-C24 hydrocarbons; distilling the stream obtained from the oligomerization in order to separate a C12-C24 hydrocarbon stream from a C5-C12 hydrocarbon stream; hydrogenating the separated C12-C24 hydrocarbon stream.

Abstract translation: 获得CN十六烷值等于或大于48的“柴油切割”燃料和烯烃或其混合物开始的低于0.4重量％的芳烃含量的方法，其特征在于其包括以下步骤：使所述烯烃低聚 在含有硅，钛和氧化铝的合成沸石存在下具有2至10个碳原子，摩尔比为SiO 2 / Al 2 O 3的摩尔比为100-300，SiO 2 / TiO 2的摩尔比大于41，以及外部结构的二氧化钛含量 相对于存在的整个氧化钛，在180-300℃的温度，大于40atm的压力和等于或大于1h -1的WHSV空速下，为零或小于25％ 以获得基本上由低聚C5-C24烃组成的物流; 蒸馏从低聚获得的物流，以分离C 12 -C 24烃物流与C5-C12烃物流; 氢化分离的C12-C24烃流。

公开(公告)号：US20020087040A1

公开(公告)日：2002-07-04

申请号：US09986562

申请日：2001-11-09

Applicant: SNAMPROGETTI S.p.A.

Inventor： Mario Marchionna ,  Marco Di Girolamo ,  Domenico Sanfilippo ,  Alberto Paggini

IPC: C07C011/00 ,  C07C002/00

CPC classification number: C07C9/14 ,  C10L1/06

Abstract: A process is described for the production of hydrocarbons with a high octane number starting from mixtures essentially consisting of n-butane and isobutane (such as for example field butanes) comprising a skeleton isomerization section, a dehydrogenation section of paraffins, a selective hydrogenation section of butadiene, two conversion sections of olefins, in which the isobutene is firstly selectively transformed by means of dimerization and/or etherification, followed by the linear butenes by means of alkylation, in order to obtain, by joining the products of the two conversion sections, a product having excellent motoristic properties (octane number, volatility and distillation curve).

Abstract translation: 描述了一种用于生产具有高辛烷值的烃的方法，其起始于基本上由正丁烷和异丁烷（例如现场丁烷）组成的混合物，其包含骨架异构化部分，链烷烃的脱氢部分，选择氢化部分 丁二烯，烯烃的两个转化段，其中首先通过二聚和/或醚化选择性地转化异丁烯，然后通过烷基化进行线性丁烯，以便通过连接两个转化段的产物， 具有优异的运动特性（辛烷值，挥发性和蒸馏曲线）的产品。

公开(公告)号：US20040010171A1

公开(公告)日：2004-01-15

申请号：US10420895

申请日：2003-04-23

Applicant: SNAMPROGETTI S.p.A.

Inventor： Mario Marchionna ,  Marco Di Girolamo ,  Domenico Sanfilippo ,  Alberto Paggini

IPC: C07C001/00 ,  C07C002/00 ,  C07C004/00 ,  C07C005/00

CPC classification number: C07C9/14 ,  C10L1/06

Abstract: A process is described for the production of hydrocarbons with a high octane number starting from mixtures essentially consisting of n-butane and isobutane (such as for example field butanes) comprising a skeleton isomerization section, a dehydrogenation section of paraffins, a selective hydrogenation section of butadiene, two conversion sections of olefins, in which the isobutene is firstly selectively transformed by means of dimerization and/or etherification, followed by the linear butenes by means of alkylation, in order to obtain, by joining the products of the two conversion sections, a product having excellent motoristic properties (octane number, volatility and distillation curve).

Abstract translation: 描述了一种用于生产具有高辛烷值的烃的方法，其起始于基本上由正丁烷和异丁烷（例如现场丁烷）组成的混合物，其包含骨架异构化部分，链烷烃的脱氢部分，选择氢化部分 丁二烯，烯烃的两个转化段，其中首先通过二聚和/或醚化选择性地转化异丁烯，然后通过烷基化进行线性丁烯，以便通过连接两个转化段的产物， 具有优异的运动特性（辛烷值，挥发性和蒸馏曲线）的产品。

公开(公告)号：US20030159341A1

公开(公告)日：2003-08-28

申请号：US10373781

申请日：2003-02-27

Applicant: SNAMPROGETTI S.p.A.

Inventor： Renata Patrini ,  Mario Marchionna

IPC: C10L001/18

CPC classification number: C10L10/12 ,  C07C41/56 ,  C08G2/08 ,  C10L1/026 ,  C10L1/143 ,  C10L1/1811 ,  C10L1/1852 ,  C10L1/1985 ,  C10L1/231 ,  C07C43/30

Abstract: A liquid mixture having a cetane number higher than 40, comprising a typical diesel gas oil cut having a boiling point ranging from 150 to 380null C., and a density ranging from 0.76 and 0.935 g/ml at 15 null C.; and one or more compounds selected from dialkyl-polyformals represented by the formula RO(CH2O)mR, wherein R is a CnH2nnull1 alkyl chain, m is an integer equal to or greater than 2 and less than or equal to 6, n is an integer ranging from 1 to 10, wherein the concentration of these dialkyl-polyformals in the gas oil ranges from 1 to 20%; and a process for production of dialkyl-polyformals using sulfonic acid-based catalysts.

Abstract translation: 十六烷值高于40的液体混合物，包含沸点范围为150-380℃的典型柴油机油馏分，在15℃下密度为0.76和0.935g / ml。 和一种或多种选自式RO（CH 2 O）m R表示的二烷基 - 聚异构体的化合物，其中R是C n H 2n + 1烷基链，m是等于或大于2并且小于或等于6的整数，n是 1〜10的整数，其中，这些二烷基 - 多元醇在瓦斯油中的浓度为1〜20％。 以及使用磺酸类催化剂生产二烷基聚合物的方法。

公开(公告)号：US20030078462A1

公开(公告)日：2003-04-24

申请号：US10265436

申请日：2002-10-07

Applicant: SNAMPROGETTI S.p.A.

Inventor： Marco Di Gerolamo ,  Roberto Catani ,  Mario Marchionna

IPC: C07C002/04

CPC classification number: C10G50/00 ,  C07C5/03 ,  C07C9/16 ,  C07C2523/38 ,  C07C2523/75 ,  C07C2523/755 ,  C07C2523/883 ,  C10G65/04 ,  C10G65/16 ,  C10G69/126

Abstract: A process is described for the hydrogenation of olefinic streams containing sulfurated compounds, obtained starting from hydrocarbon cuts containing isobutene (by means of selective dimerization), characterized by fractionating said streams in one or more distillation columns and hydrogenating separately the two fractions obtained. The stream at the head, with a minimum content of sulfurated compounds, is hydrogenated with conventional catalysts based on nickel or noble metals (Platinum and/or Palladium), extremely active but also very sensitive to sulfur, whereas the bottom of the column, rich in sulfurated compounds, is treated with bimetallic catalysts (for example Ni/Co and/or Ni/Mo), less active but not deactivated by sulfur.

Abstract translation: 描述了一种从包含异丁烯（通过选择性二聚）的烃馏分开始获得的含有硫化物的烯烃流的氢化方法，其特征在于将一个或多个蒸馏塔中的所述物流分馏并分别氢化得到的两个馏分。 具有最低含量的硫化物的头部的料流用基于镍或贵金属（铂和/或钯）的常规催化剂进行氢化，其活性极高，但对硫非常敏感，而塔的底部富含 在硫化物中，用双金属催化剂（例如Ni / Co和/或Ni / Mo）处理，活性较低但未被硫失活。