PROCESS AND COMPOSITION FOR TREATING METAL SURFACES USING TRIVALENT CHROMIUM COMPOUNDS
    1.
    发明申请
    PROCESS AND COMPOSITION FOR TREATING METAL SURFACES USING TRIVALENT CHROMIUM COMPOUNDS 有权
    使用多种铬化合物处理金属表面的方法和组合物

    公开(公告)号:US20140050855A1

    公开(公告)日:2014-02-20

    申请号:US14058902

    申请日:2013-10-21

    申请人: Richard J. Church

    发明人: Richard J. Church

    IPC分类号: C09D5/00 C09D5/08

    摘要: An acidic, aqueous composition contains a trivalent chromium compound, an organo-functional silane, and a compound of a group IV-B element. The composition protects metal surfaces, preferably aluminum and aluminum alloys, against corrosion and improves their paint adhesion. The trivalent chromium compound may comprise chromium fluoride and optionally others, such as chromium nitrate. The organo-functional silane is preferably an aminopropyltriethoxy silane, and the compound of a group IV-B element is preferably fluorozirconic acid. The composition can either be dried-in-place or rinsed before a further coating layer is applied. The composition may also include at least one polymer having a plurality of both carboxylic functional groups, alone or with hydroxyl groups. A process uses the aqueous composition either with or without the organo-functional silane along with a sealing step following the application of the aqueous composition; the sealing step involves applying a sealing composition, including an organo-functional silane, to the metal surface.

    摘要翻译: 酸性水性组合物含有三价铬化合物,有机功能性硅烷和IV-B族元素的化合物。 该组合物保护金属表面,优选铝和铝合金,防止腐蚀并改善其涂料附着力。 三价铬化合物可以包含氟化铬和任选的其它物质,例如硝酸铬。 有机官能硅烷优选为氨基丙基三乙氧基硅烷,IV-B族元素的化合物优选为氟锆酸。 组合物可以在施加另外的涂层之前进行就地干燥或漂洗。 该组合物还可以包括至少一种具有多个单独或与羟基的两个羧基官能团的聚合物。 一种方法使用具有或不具有有机官能硅烷的水性组合物以及施加含水组合物之后的密封步骤; 密封步骤包括将包括有机功能性硅烷的密封组合物施加到金属表面。

    PROCESS AND COMPOSITION FOR TREATING METAL SURFACES USING TRIVALENT CHROMIUM COMPOUNDS
    2.
    发明申请
    PROCESS AND COMPOSITION FOR TREATING METAL SURFACES USING TRIVALENT CHROMIUM COMPOUNDS 有权
    使用多种铬化合物处理金属表面的方法和组合物

    公开(公告)号:US20090280253A1

    公开(公告)日:2009-11-12

    申请号:US12116513

    申请日:2008-05-07

    申请人: Richard J. Church

    发明人: Richard J. Church

    IPC分类号: C09K13/08 C23F1/00 B05D3/10

    摘要: An acidic, aqueous composition contains a trivalent chromium compound, an organo-functional silane, and a compound of a group IV-B element. The composition protects metal surfaces, preferably aluminum and aluminum alloys, against corrosion and improves their paint adhesion. The trivalent chromium compound may comprise chromium fluoride and optionally others, such as chromium nitrate. The organo-functional silane is preferably an aminopropyltriethoxy silane, and the compound of a group IV-B element is preferably fluorozirconic acid. The composition can either be dried-in-place or rinsed before a further coating layer is applied. The composition may also include at least one polymer having a plurality of both carboxylic functional groups, alone or with hydroxyl groups. A process uses the aqueous composition either with or without the organo-functional silane along with a sealing step following the application of the aqueous composition; the sealing step involves applying a sealing composition, including an organo-functional silane, to the metal surface.

    摘要翻译: 酸性水性组合物含有三价铬化合物,有机功能性硅烷和IV-B族元素的化合物。 该组合物保护金属表面,优选铝和铝合金,防止腐蚀并改善其涂料附着力。 三价铬化合物可以包含氟化铬和任选的其它物质,例如硝酸铬。 有机官能硅烷优选为氨基丙基三乙氧基硅烷,IV-B族元素的化合物优选为氟锆酸。 组合物可以在施加另外的涂层之前进行就地干燥或漂洗。 该组合物还可以包括至少一种具有多个单独或与羟基的两个羧基官能团的聚合物。 一种方法使用具有或不具有有机官能硅烷的水性组合物以及施加含水组合物之后的密封步骤; 密封步骤包括将包括有机功能性硅烷的密封组合物施加到金属表面。

    Process and composition for treating metal surfaces using trivalent chromium compounds
    3.
    发明授权
    Process and composition for treating metal surfaces using trivalent chromium compounds 有权
    使用三价铬化合物处理金属表面的方法和组成

    公开(公告)号:US08591670B2

    公开(公告)日:2013-11-26

    申请号:US12116513

    申请日:2008-05-07

    申请人: Richard J. Church

    发明人: Richard J. Church

    IPC分类号: C23C22/30 C23C22/34 C23C22/00

    摘要: An acidic, aqueous composition contains a trivalent chromium compound, an organo-functional silane, and a compound of a group IV-B element. The composition protects metal surfaces, preferably aluminum and aluminum alloys, against corrosion and improves their paint adhesion. The trivalent chromium compound may comprise chromium fluoride and optionally others, such as chromium nitrate. The organo-functional silane is preferably an aminopropyltriethoxy silane, and the compound of a group IV-B element is preferably fluorozirconic acid. The composition can either be dried-in-place or rinsed before a further coating layer is applied. The composition may also include at least one polymer having a plurality of both carboxylic functional groups, alone or with hydroxyl groups. A process uses the aqueous composition either with or without the organo-functional silane along with a sealing step following the application of the aqueous composition; the sealing step involves applying a sealing composition, including an organo-functional silane, to the metal surface.

    摘要翻译: 酸性水性组合物含有三价铬化合物,有机功能性硅烷和IV-B族元素的化合物。 该组合物保护金属表面,优选铝和铝合金,防止腐蚀并改善其涂料附着力。 三价铬化合物可以包含氟化铬和任选的其它物质,例如硝酸铬。 有机官能硅烷优选为氨基丙基三乙氧基硅烷,IV-B族元素的化合物优选为氟锆酸。 组合物可以在施加另外的涂层之前进行就地干燥或漂洗。 该组合物还可以包括至少一种具有多个单独或与羟基的两个羧基官能团的聚合物。 一种方法使用具有或不具有有机官能硅烷的水性组合物以及施加含水组合物之后的密封步骤; 密封步骤包括将包括有机功能性硅烷的密封组合物施加到金属表面。

    Cleaning metal salts of intermediate length carboxylic acids from surfaces
    5.
    发明授权
    Cleaning metal salts of intermediate length carboxylic acids from surfaces 失效
    从表面清除中等长度羧酸的金属盐

    公开(公告)号:US06727214B1

    公开(公告)日:2004-04-27

    申请号:US10110493

    申请日:2002-04-15

    IPC分类号: C11D304

    CPC分类号: C11D3/044 C11D3/2075

    摘要: A process of cleaning very sparingly water soluble soaps off workpieces after cold forming them is made considerably more economical by using a cleaning solution that causes the removed soap anions to form a separate floating solid phase that can easily be skimmed from the surface of the cleaning solution. When such a separation is made, much longer intervals between replacement of the cleaning solution are possible while still obtaining satisfactory results. A preferred cleaning solution for such a process comprises hydroxides, neutral salts, polymeric quaternary ammonium cations, and a sequestering agent for the counterions of the soap anions to be cleaned.

    摘要翻译: 通过使用清洁溶液使清除的皂阴离子形成分离的漂浮固相,其可以很容易地从清洁溶液的表面上撇去,在冷成型之后将非常微小的水溶性肥皂清除掉的工艺变得更加经济 。 当进行这种分离时,更换清洁溶液之间的更长的间隔是可能的,同时仍然获得令人满意的结果。 用于这种方法的优选的清洁溶液包括氢氧化物,中性盐,聚合季铵阳离子和用于待洗涤的皂阴离子的抗衡离子的螯合剂。

    Process and composition for treating metal surfaces
    8.
    发明授权
    Process and composition for treating metal surfaces 有权
    处理金属表面的方法和组成

    公开(公告)号:US08425692B2

    公开(公告)日:2013-04-23

    申请号:US12789108

    申请日:2010-05-27

    IPC分类号: C23C22/34 C23C22/30

    摘要: A composition for forming a protective coating on a metal surface includes water; Cr2(GF6)3 in which G is a Group IV-B element; and at least one polymer having a plurality of carboxylic acid groups and at least one polymer having a plurality of hydroxyl groups, and/or at least one polymer having a plurality of both carboxylic acid and hydroxyl groups; wherein the composition contains less than 500 ppm of alkali metal ions and less than 200 ppm of halide ions relative to chromium. A method of forming a protective coating on a metal surface includes contacting the metal surface with the composition.

    摘要翻译: 用于在金属表面形成保护涂层的组合物包括水; Cr 2(GF 6)3,其中G为IV-B族元素; 和至少一种具有多个羧酸基团的聚合物和至少一种具有多个羟基的聚合物,和/或至少一种具有多个羧酸和羟基的聚合物; 其中所述组合物相对于铬含有小于500ppm的碱金属离子和小于200ppm的卤离子。 在金属表面上形成保护涂层的方法包括使金属表面与组合物接触。

    PROCESS AND COMPOSITION FOR TREATING METAL SURFACES
    9.
    发明申请
    PROCESS AND COMPOSITION FOR TREATING METAL SURFACES 有权
    用于处理金属表面的方法和组合物

    公开(公告)号:US20110293841A1

    公开(公告)日:2011-12-01

    申请号:US12789108

    申请日:2010-05-27

    IPC分类号: B05D3/02 C09D1/00

    摘要: A composition for forming a protective coating on a metal surface includes water;Cr2(GF6)3 in which G is a Group IV-B element; andat least one polymer having a plurality of carboxylic acid groups and at least one polymer having a plurality of hydroxyl groups, and/or at least one polymer having a plurality of both carboxylic acid and hydroxyl groups;wherein the composition contains less than 500 ppm of alkali metal ions and less than 200 ppm of halide ions relative to chromium. A method of forming a protective coating on a metal surface includes contacting the metal surface with the composition.

    摘要翻译: 用于在金属表面形成保护涂层的组合物包括水; Cr 2(GF 6)3,其中G为IV-B族元素; 和至少一种具有多个羧酸基团的聚合物和至少一种具有多个羟基的聚合物,和/或至少一种具有多个羧酸和羟基的聚合物; 其中所述组合物相对于铬含有小于500ppm的碱金属离子和小于200ppm的卤离子。 在金属表面上形成保护涂层的方法包括使金属表面与组合物接触。

    Cleaning metal salts of intermediate length carboxylic acids from surfaces
    10.
    发明授权
    Cleaning metal salts of intermediate length carboxylic acids from surfaces 失效
    从表面清除中等长度羧酸的金属盐

    公开(公告)号:US06440917B1

    公开(公告)日:2002-08-27

    申请号:US09530300

    申请日:2000-04-27

    IPC分类号: C11D304

    摘要: Problems of extensive foaming and/or of sticky deposits on process equipment that often arise when metal soaps from metal articles that have been given a metal soap containing surface to aid in drawing are removed with aqueous alkaline clearners can be avoided by including in the cleaners used anions such as calcium and magnesium that are capable of precipitating the anions of the metal soaps. The cleaners advantageously also contain chelants, a mixture of nonionic and anionic surfactants, and phosphorus containing anions. Anions from the metal soaps are eventually precipitated from the cleaners used as non-sticky sludge that can be easily separated from the cleaners.

    摘要翻译: 通过在使用的清洁剂中包括在水性碱性清洁剂中除去已经被赋予含金属肥皂表面以辅助拉伸的金属制品的金属皂,通常在工艺设备上产生大量起泡和/或粘性沉积物的问题, 阴离子如钙和镁,能够沉淀金属皂的阴离子。 清洁剂有利地还含有螯合剂,非离子和阴离子表面活性剂的混合物以及含磷阴离子。 来自金属皂的阴离子最终从用作非粘性污泥的清洁剂沉淀出来,其可以容易地与清洁剂分离。