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公开(公告)号:US20180237573A1
公开(公告)日:2018-08-23
申请号:US15959596
申请日:2018-04-23
Applicant: RESINATE MATERIALS GROUP, INC.
Inventor: Rick Tabor , Eric David Vrabel , Matthew J. Beatty , Gary E. Spilman , Kevin Anthony Rogers , Michael Robert Christy , Matthew Thomas Brown , Jack Rogers Kovsky , Woo-Sung Bae , Shakti L. Mukerjee
IPC: C08G18/08 , C08G18/76 , C09D175/06 , C09D175/04 , C08G64/40 , C08G18/42 , C08G18/66 , C09D167/02 , C08G18/09 , C08J11/24 , C08G63/89 , C08G63/91 , C09D5/03 , C08F20/10 , C08G18/72 , C08G63/553 , C08J9/04 , C08G63/183 , C08G18/44 , C09D167/00 , C08J3/03 , C08G101/00
CPC classification number: C08G18/0866 , C08F20/10 , C08G18/092 , C08G18/4213 , C08G18/4288 , C08G18/44 , C08G18/664 , C08G18/722 , C08G18/7671 , C08G63/183 , C08G63/553 , C08G63/89 , C08G63/916 , C08G64/403 , C08G2101/0025 , C08G2150/20 , C08J3/03 , C08J9/04 , C08J11/24 , C08J2201/022 , C08J2205/06 , C08J2205/10 , C08J2367/02 , C08J2375/06 , C09D5/03 , C09D167/00 , C09D167/02 , C09D175/04 , C09D175/06 , Y02W30/706
Abstract: The present invention relates to polyester polyols made from aromatic polyacid sources such as thermoplastic polyesters. The polyols can be made by heating a thermoplastic polyester such as virgin polyethylene terephthalate, recycled polyethylene terephthalate, or mixtures thereof, with a glycol to give a digested intermediate which is then reacted with a digestible polymer, which can be obtained from various recycle waste streams. The polyester polyols comprise a glycol-digested polyacid source and a further digestible polymer. The polyester polyols provide a sustainable alternative to petrochemical or biochemical based polyester polyols.
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公开(公告)号:US20170029561A1
公开(公告)日:2017-02-02
申请号:US15205235
申请日:2016-07-08
Applicant: Resinate Materials Group, Inc.
Inventor: Rick Tabor , Eric David Vrabel , Matthew J. Beatty , Gary E. Spilman , Kevin Anthony Rogers , Michael Robert Christy , Matthew Thomas Brown , Jack Rogers Kovsky , Woo-Sung Bae , Shakti L. Mukerjee
IPC: C08G63/91 , C08G18/42 , C08F20/10 , C09D175/06 , C09D5/03 , C08G18/76 , C08G63/183
CPC classification number: C08G63/916 , C07C29/09 , C07C31/18 , C08F20/10 , C08F291/08 , C08G18/14 , C08G18/28 , C08G18/4213 , C08G18/664 , C08G18/722 , C08G18/7671 , C08G63/183 , C08G2101/00 , C08G2101/0025 , C08G2150/20 , C08J9/141 , C08J11/24 , C08J2203/14 , C08J2205/10 , C08J2367/02 , C08J2375/04 , C09D5/03 , C09D167/00 , C09D175/04 , C09D175/06 , Y02W30/706
Abstract: The present invention relates to polyester polyols made from aromatic polyacid sources such as thermoplastic polyesters. The polyols can be made by heating a thermoplastic polyester such as virgin polyethylene terephthalate, recycled polyethylene terephthalate, or mixtures thereof, with a glycol to give a digested intermediate which is then reacted with a digestible polymer, which can be obtained from various recycle waste streams. The polyester polyols comprise a glycol-digested polyacid source and a further digestible polymer. The polyester polyols provide a sustainable alternative to petrochemical or biochemical based polyester polyols.
Abstract translation: 本发明涉及由芳族多酸源如热塑性聚酯制成的聚酯多元醇。 多元醇可以通过将热塑性聚酯如原始聚对苯二甲酸乙二醇酯,再循环的聚对苯二甲酸乙二醇酯或其混合物与二醇加热来制备,从而得到消化的中间体,然后与可消化的聚合物反应,该可消化的聚合物可以从各种循环废物流 。 聚酯多元醇包含二醇消化的多酸源和另外的可消化的聚合物。 聚酯多元醇提供石油化学或生物化学基聚酯多元醇的可持续替代品。
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公开(公告)号:US10662364B2
公开(公告)日:2020-05-26
申请号:US15559151
申请日:2016-03-16
Applicant: RESINATE MATERIALS GROUP, INC.
Inventor: Shakti L. Mukerjee , Kevin Anthony Rogers , Rick Tabor
Abstract: A drilling fluid comprising a carrier fluid, an aromatic polyester polyol and an additive selected from a thickener, a wetting agent, an emulsifier, a weighting agent, a pH control agent, a lubricant or mixtures thereof.
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公开(公告)号:US09884938B2
公开(公告)日:2018-02-06
申请号:US15407317
申请日:2017-01-17
Applicant: Resinate Materials Group, Inc.
Inventor: Woo-Sung Bae , Rick Tabor , Kevin Anthony Rogers , Shakti L. Mukerjee
CPC classification number: C08G63/916 , C08J3/18 , C08J2300/22 , C08J2327/06 , C08J2367/02 , C08J2367/03 , C08J2467/02 , C08J2467/03 , C08J2469/00 , C08J2471/02 , C08K5/0016 , C08K5/09 , C08K5/092 , C08L27/06 , C08L67/02 , C08L67/03 , C08L69/00 , C08L2205/025 , C08L2205/03 , C08L2207/04 , C08L2207/20
Abstract: The present invention relates to polymeric plasticizer compositions made from an aromatic acid source, a glycol, and a C4-C36 monocarboxylic acid, or ester or anhydride thereof. The aromatic acid source can include polymeric materials such as recycled polyethylene terephthalate (PET). The present invention also relates to methods for making the polymeric plasticizer compositions, to methods of plasticizing polymeric materials, and to plasticized polymeric compositions. The polymeric plasticizers are useful for plasticizing various polymers, such as thermoplastic polymers, including, for example, polyvinyl chloride (PVC). The polymeric plasticizers provide a sustainable alternative to conventional phthalate ester plasticizers, such as diisooctyl phthalate (DOP).
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公开(公告)号:US20170260353A1
公开(公告)日:2017-09-14
申请号:US15602566
申请日:2017-05-23
Applicant: RESINATE MATERIALS GROUP, INC.
Inventor: Rick Tabor , Shakti L. Mukerjee , Kevin Anthony Rogers , Adam W. Emerson , Eric David Vrabel , Brian Douglas Phillips
CPC classification number: C08J11/24 , C08G18/0823 , C08G18/10 , C08G18/36 , C08G18/42 , C08G18/4288 , C08G18/7664 , C08G63/16 , C08G63/916 , C08J5/24 , C08J2367/02 , C08J2375/04 , C08J2375/06 , C08J2423/02 , C08J2467/02 , C08J2475/04 , C08K5/12 , Y02P20/125
Abstract: A process for producing a polyester polyol comprising reacting a recycle stream selected from recycled PET carpet, carpet fiber, containers, textiles, articles or mixtures thereof, with a glycol in a reactor, thereby forming a digested product stream comprising polyols, and an undigested stream; and then reacting the digested product stream with a hydrophobe selected from dimer fatty acids, trimer fatty acids, oleic acid, ricinoleic acid, tung oil, corn oil, canola oil, soybean oil, sunflower oil, bacterial oil, yeast oil, algae oil, castor oil, triglycerides or alkyl carboxylate esters having saturated or unsaturated C6-C36 fatty acid units, saturated or unsaturated C6-C36 fatty acids, alkoxylated castor oil, saturated or unsaturated C9-C18 dicarboxylic acids or diols, cardanol-based products, recycled cooking oil, branched or linear C6-C36 fatty alcohols, hydroxy-functional materials derived from epoxidized, ozonized, or hydroformylated fatty esters or acids, or mixtures thereof.
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公开(公告)号:US20170226310A1
公开(公告)日:2017-08-10
申请号:US15497288
申请日:2017-04-26
Applicant: RESINATE MATERIALS GROUP, INC.
Inventor: Rick Tabor , Shakti L. Mukerjee , Kevin Anthony Rogers , Eric David Vrabel , Brian Chermside , Adam W. Emerson , Brian Douglas Phillips
CPC classification number: C08J11/24 , C08G18/0823 , C08G18/10 , C08G18/36 , C08G18/42 , C08G18/4288 , C08G18/7664 , C08G63/16 , C08G63/916 , C08J5/24 , C08J2367/02 , C08J2375/04 , C08J2375/06 , C08J2423/02 , C08J2467/02 , C08J2475/04 , C08K5/12 , Y02P20/125
Abstract: A process for producing a polyester polyol comprising reacting a recycle stream selected from recycled PET carpet, carpet fiber, containers, textiles, articles or mixtures thereof, with a glycol in a reactor, thereby forming a digested product stream comprising polyols, and an undigested stream; and then reacting the digested product stream with a hydrophobe selected from dimer fatty acids, trimer fatty acids, oleic acid, ricinoleic acid, tung oil, corn oil, canola oil, soybean oil, sunflower oil, bacterial oil, yeast oil, algae oil, castor oil, triglycerides or alkyl carboxylate esters having saturated or unsaturated C6-C36 fatty acid units, saturated or unsaturated C6-C36 fatty acids, alkoxylated castor oil, saturated or unsaturated C9-C18 dicarboxylic acids or diols, cardanol-based products, recycled cooking oil, branched or linear C6-C36 fatty alcohols, hydroxy-functional materials derived from epoxidized, ozonized, or hydroformylated fatty esters or acids, or mixtures thereof.
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公开(公告)号:US09714334B2
公开(公告)日:2017-07-25
申请号:US15099807
申请日:2016-04-15
Applicant: Resinate Materials Group, Inc.
Inventor: Rick Tabor , Shakti L. Mukerjee , Kevin Rogers , Eric David Vrabel , Adam W. Emerson , Brian Douglas Phillips
CPC classification number: C08J11/24 , C08G18/0823 , C08G18/10 , C08G18/36 , C08G18/42 , C08G18/4288 , C08G63/916 , C08J5/24 , C08J2367/02 , C08J2375/06 , C08J2423/02 , C08K5/12 , Y02P20/125
Abstract: A process for producing a polyester polyol comprising reacting a recycle stream selected from recycled PET carpet, carpet fiber, containers, textiles, articles or mixtures thereof, with a glycol in a reactor, thereby forming a digested product stream comprising polyols, and an undigested stream; and then reacting the digested product stream with a hydrophobe selected from dimer fatty acids, trimer fatty acids, oleic acid, ricinoleic acid, tung oil, corn oil, canola oil, soybean oil, sunflower oil, bacterial oil, yeast oil, algae oil, castor oil, triglycerides or alkyl carboxylate esters having saturated or unsaturated C6-C36 fatty acid units, saturated or unsaturated C6-C36 fatty acids, alkoxylated castor oil, saturated or unsaturated C9-C18 dicarboxylic acids or diols, cardanol-based products, recycled cooking oil, branched or linear C6-C36 fatty alcohols, hydroxy-functional materials derived from epoxidized, ozonized, or hydroformylated fatty esters or acids, or mixtures thereof.
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公开(公告)号:US20170051103A1
公开(公告)日:2017-02-23
申请号:US15306774
申请日:2015-04-30
Applicant: RESINATE MATERIALS GROUP, INC.
Inventor: Rick Tabor , Eric D. Vrabel , Kevin Anthony Rogers , Shakti L. Mukerjee , Matthew J. Beatty , Adam William Emerson , Matthew T. Brown , Jack Rogers Kovsky , Michael D. Kellerman , Michael Robert Christy
IPC: C08G63/87 , C08G18/42 , C08G18/72 , C08G63/183
CPC classification number: C08G63/87 , C07C67/03 , C08G18/42 , C08G18/4213 , C08G18/72 , C08G63/183 , C08G63/553 , C08J11/24 , C08J2367/02 , Y02P20/582 , Y02W30/706 , C07C69/82
Abstract: Polyester polyols made from recycled polyethylene terephthalate (rPET) and processes for making them are disclosed. The rPET is heated with a C3-C10 glycol reactant to give a digested intermediate comprising glycols and a terephthalate component, which comprises 45 to 70 wt. % of bis(hydroxyalkyl)terephthalates, and preferably lesser amounts of terephthalate dimers and trimers. Treatment of the digested intermediate with activated carbon gives a polyester polyol having a color index less than 20. The polyols have desirable hydroxyl numbers, viscosities, appearance, and other attributes for formulating polyurethane products and are a sustainable alternative to bio- or petrochemical-based polyols.
Abstract translation: 公开了由回收聚对苯二甲酸乙二醇酯(rPET)制成的聚酯多元醇及其制备方法。 用C 3 -C 10二醇反应物加热rPET,得到包含二醇和对苯二甲酸酯组分的消化的中间体,其包含45至70重量% %的双(羟烷基)对苯二甲酸酯,优选较少量的对苯二甲酸酯二聚体和三聚体。 用活性炭处理消化的中间体可得到颜色指数小于20的聚酯多元醇。多元醇具有理想的羟基数,粘度,外观和其他配方聚氨酯产品的特性,是生物或石油化学品的可持续替代品 多元醇。
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公开(公告)号:US20160122471A1
公开(公告)日:2016-05-05
申请号:US14959499
申请日:2015-12-04
Applicant: Resinate Materials Group, Inc.
Inventor: Woo-Sung Bae , Rick Tabor , Kevin Anthony Rogers , Shakti L. Mukerjee
CPC classification number: C08G63/916 , C08J3/18 , C08J2300/22 , C08J2327/06 , C08J2367/02 , C08J2367/03 , C08J2467/02 , C08J2467/03 , C08J2469/00 , C08J2471/02 , C08K5/0016 , C08K5/09 , C08K5/092 , C08L27/06 , C08L67/02 , C08L67/03 , C08L69/00 , C08L2205/025 , C08L2205/03 , C08L2207/04 , C08L2207/20
Abstract: The present invention relates to polymeric plasticizer compositions made from an aromatic acid source, a glycol, and a C4-C36 monocarboxylic acid, or ester or anhydride thereof. The aromatic acid source can include polymeric materials such as recycled polyethylene terephthalate (PET). The present invention also relates to methods for making the polymeric plasticizer compositions, to methods of plasticizing polymeric materials, and to plasticized polymeric compositions. The polymeric plasticizers are useful for plasticizing various polymers, such as thermoplastic polymers, including, for example, polyvinyl chloride (PVC). The polymeric plasticizers provide a sustainable alternative to conventional phthalate ester plasticizers, such as diisooctyl phthalate (DOP).
Abstract translation: 本发明涉及由芳族酸源,二醇和C 4 -C 36单羧酸或其酯或酸酐制成的聚合物增塑剂组合物。 芳族酸源可以包括聚合物材料,例如再循环的聚对苯二甲酸乙二醇酯(PET)。 本发明还涉及制备聚合物增塑剂组合物,聚合物材料增塑方法和增塑聚合物组合物的方法。 聚合物增塑剂可用于增塑各种聚合物,例如热塑性聚合物,包括例如聚氯乙烯(PVC)。 聚合物增塑剂提供了常规邻苯二甲酸酯增塑剂的可持续替代方法,如邻苯二甲酸二异辛酯(DOP)。
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公开(公告)号:US20190241702A1
公开(公告)日:2019-08-08
申请号:US16383951
申请日:2019-04-15
Applicant: RESINATE MATERIALS GROUP, INC.
Inventor: Shakti L. Mukerjee , Rick Tabor , Adam William Emerson , Kevin Anthony Rogers , Eric D. Vrabel , Matthew T. Brown , Matthew J. Beatty , Jack Rogers Kovsky , Michael D. Kellerman , Michael Robert Christy
IPC: C08G63/91 , C08G18/42 , C08J11/24 , C08G18/75 , C09D175/06 , C08G18/73 , C08G63/553 , C08G18/36 , C07C69/82 , C07C67/08 , C07C67/03
CPC classification number: C08G63/916 , C07C67/03 , C07C67/08 , C07C69/82 , C07C2601/14 , C08G18/36 , C08G18/4213 , C08G18/4288 , C08G18/735 , C08G18/755 , C08G63/553 , C08G2101/0008 , C08G2101/0025 , C08J11/24 , C08J2367/02 , C09D167/07 , C09D175/06 , Y02W30/706
Abstract: Polyester polyols made from thermoplastic polyesters are disclosed. The polyols can be made by heating a thermoplastic polyester such as virgin PET, recycled PET, or mixtures thereof, with a glycol to give a digested intermediate, which is then condensed with a dimer fatty acid to give the polyol. The invention includes a polyester polyol comprising recurring units of a glycol-digested thermoplastic polyester and a dimer fatty acid. The polyester polyol can also be made in a single step by reacting the thermoplastic polyester, glycol, and dimer acid under conditions effective to produce the polyol. High-recycle-content polyols having desirable properties and attributes for formulating polyurethane products, including aqueous polyurethane dispersions, can be made. The polyols provide a sustainable alternative to bio- or petrochemical-based polyols.
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