公开(公告)号：US10414859B2

公开(公告)日：2019-09-17

申请号：US14886219

申请日：2015-10-19

Applicant: Resinate Materials Group, Inc.

Inventor： Rick Tabor ,  Kevin Anthony Rogers ,  Eric D Vrabel ,  Matthew James Beatty ,  Woo-Sung Bae ,  Shakti L Mukerjee

IPC: C08G63/91 ,  C09D175/06 ,  C08G18/66 ,  C08G18/72 ,  C08G18/73 ,  C08G18/75 ,  C08G18/08 ,  C08G18/22 ,  C08G18/34 ,  C08G18/42

Abstract: Polyester polyols made from thermoplastic polyesters are disclosed. The polyols are reaction products of a thermoplastic polyester, a glycol, and a hydrophobe selected from ricinoleic acid, ethoxylated castor oil, saturated or unsaturated C9-C18 dicarboxylic acids, tung oil, soybean oil, sunflower oil, cardanol-based products, recycled cooking oil, isostearyl alcohol, hydroxy-functional materials derived from epoxidized, ozonized, or hydroformylated fatty esters or fatty acids, and mixtures thereof. In one process, the polyols are made by reacting the thermoplastic polyester with a glycol to give a digested intermediate, which is then reacted with the hydrophobe. In another process, the thermoplastic polyester, glycol, and hydrophobe are combined and reacted in a single step. These hydrophobes facilitate the production from recycled thermoplastics of polyols that have good transparency and little or no particulate settling or phase separation. High-recycle-content polyols having desirable properties and attributes for formulating polyurethane products, including aqueous polyurethane dispersions, can be made. The polyols provide a sustainable alternative to bio- or petrochemical-based polyols.

公开(公告)号：US20180237573A1

公开(公告)日：2018-08-23

申请号：US15959596

申请日：2018-04-23

Applicant: RESINATE MATERIALS GROUP, INC.

Inventor： Rick Tabor ,  Eric David Vrabel ,  Matthew J. Beatty ,  Gary E. Spilman ,  Kevin Anthony Rogers ,  Michael Robert Christy ,  Matthew Thomas Brown ,  Jack Rogers Kovsky ,  Woo-Sung Bae ,  Shakti L. Mukerjee

IPC: C08G18/08 ,  C08G18/76 ,  C09D175/06 ,  C09D175/04 ,  C08G64/40 ,  C08G18/42 ,  C08G18/66 ,  C09D167/02 ,  C08G18/09 ,  C08J11/24 ,  C08G63/89 ,  C08G63/91 ,  C09D5/03 ,  C08F20/10 ,  C08G18/72 ,  C08G63/553 ,  C08J9/04 ,  C08G63/183 ,  C08G18/44 ,  C09D167/00 ,  C08J3/03 ,  C08G101/00

CPC classification number: C08G18/0866 ,  C08F20/10 ,  C08G18/092 ,  C08G18/4213 ,  C08G18/4288 ,  C08G18/44 ,  C08G18/664 ,  C08G18/722 ,  C08G18/7671 ,  C08G63/183 ,  C08G63/553 ,  C08G63/89 ,  C08G63/916 ,  C08G64/403 ,  C08G2101/0025 ,  C08G2150/20 ,  C08J3/03 ,  C08J9/04 ,  C08J11/24 ,  C08J2201/022 ,  C08J2205/06 ,  C08J2205/10 ,  C08J2367/02 ,  C08J2375/06 ,  C09D5/03 ,  C09D167/00 ,  C09D167/02 ,  C09D175/04 ,  C09D175/06 ,  Y02W30/706

Abstract: The present invention relates to polyester polyols made from aromatic polyacid sources such as thermoplastic polyesters. The polyols can be made by heating a thermoplastic polyester such as virgin polyethylene terephthalate, recycled polyethylene terephthalate, or mixtures thereof, with a glycol to give a digested intermediate which is then reacted with a digestible polymer, which can be obtained from various recycle waste streams. The polyester polyols comprise a glycol-digested polyacid source and a further digestible polymer. The polyester polyols provide a sustainable alternative to petrochemical or biochemical based polyester polyols.

公开(公告)号：US20170327638A1

公开(公告)日：2017-11-16

申请号：US15663881

申请日：2017-07-31

Applicant: Resinate Materials Group, Inc.

Inventor： Shakti Mukerjee ,  Kevin Anthony Rogers ,  Matthew James Beatty ,  Gary E. Spilman

IPC: C08G63/91 ,  C09D167/03 ,  C08G18/32 ,  C09D167/02 ,  C08J11/24 ,  C08G63/676 ,  C08G63/668 ,  C08G63/133 ,  C08G18/75 ,  C08G18/73 ,  C08G18/66 ,  C08G18/64 ,  C08G18/42 ,  C09D175/06

CPC classification number: C08G63/916 ,  C08G18/3206 ,  C08G18/4225 ,  C08G18/6492 ,  C08G18/664 ,  C08G18/73 ,  C08G18/755 ,  C08G63/133 ,  C08G63/668 ,  C08G63/676 ,  C08G63/914 ,  C08J11/24 ,  C08J2367/02 ,  C09D167/02 ,  C09D167/03 ,  C09D175/06 ,  Y02P20/582 ,  Y02W30/706

Abstract: Polyester polyols, processes for making them, and applications for the polyols are disclosed. In some aspects, the polyols comprise recurring units from a thermoplastic polyester or an aromatic polyacid source, a glycol, and a lignin, tannin, or mixture thereof. Optionally, the polyols incorporate recurring units of a hydrophobe. The polyols are made in one or multiple steps; in some aspects, the thermoplastic polyester or aromatic polyacid source and the glycol are reacted first, followed by reaction with the lignin, tannin, or mixture thereof. High-recycle-content polyols having desirable properties and attributes for formulating polyurethane products, including two-component polyurethane coatings, can be made. The polyols provide a sustainable alternative to bio- or petrochemical-based polyols.

公开(公告)号：US20170029561A1

公开(公告)日：2017-02-02

申请号：US15205235

申请日：2016-07-08

Applicant: Resinate Materials Group, Inc.

Inventor： Rick Tabor ,  Eric David Vrabel ,  Matthew J. Beatty ,  Gary E. Spilman ,  Kevin Anthony Rogers ,  Michael Robert Christy ,  Matthew Thomas Brown ,  Jack Rogers Kovsky ,  Woo-Sung Bae ,  Shakti L. Mukerjee

IPC: C08G63/91 ,  C08G18/42 ,  C08F20/10 ,  C09D175/06 ,  C09D5/03 ,  C08G18/76 ,  C08G63/183

CPC classification number: C08G63/916 ,  C07C29/09 ,  C07C31/18 ,  C08F20/10 ,  C08F291/08 ,  C08G18/14 ,  C08G18/28 ,  C08G18/4213 ,  C08G18/664 ,  C08G18/722 ,  C08G18/7671 ,  C08G63/183 ,  C08G2101/00 ,  C08G2101/0025 ,  C08G2150/20 ,  C08J9/141 ,  C08J11/24 ,  C08J2203/14 ,  C08J2205/10 ,  C08J2367/02 ,  C08J2375/04 ,  C09D5/03 ,  C09D167/00 ,  C09D175/04 ,  C09D175/06 ,  Y02W30/706

Abstract: The present invention relates to polyester polyols made from aromatic polyacid sources such as thermoplastic polyesters. The polyols can be made by heating a thermoplastic polyester such as virgin polyethylene terephthalate, recycled polyethylene terephthalate, or mixtures thereof, with a glycol to give a digested intermediate which is then reacted with a digestible polymer, which can be obtained from various recycle waste streams. The polyester polyols comprise a glycol-digested polyacid source and a further digestible polymer. The polyester polyols provide a sustainable alternative to petrochemical or biochemical based polyester polyols.

Abstract translation: 本发明涉及由芳族多酸源如热塑性聚酯制成的聚酯多元醇。 多元醇可以通过将热塑性聚酯如原始聚对苯二甲酸乙二醇酯，再循环的聚对苯二甲酸乙二醇酯或其混合物与二醇加热来制备，从而得到消化的中间体，然后与可消化的聚合物反应，该可消化的聚合物可以从各种循环废物流 。 聚酯多元醇包含二醇消化的多酸源和另外的可消化的聚合物。 聚酯多元醇提供石油化学或生物化学基聚酯多元醇的可持续替代品。

公开(公告)号：US20170002138A1

公开(公告)日：2017-01-05

申请号：US15266247

申请日：2016-09-15

Applicant: Resinate Materials Group, Inc.

Inventor： Shakti Mukerjee ,  Kevin Anthony Rogers ,  Matthew James Beatty ,  Gary E. Spilman

IPC: C08G63/91 ,  C08G63/676 ,  C08G18/32 ,  C08G18/73 ,  C08G18/64 ,  C09D175/06 ,  C09D167/02

CPC classification number: C08G63/916 ,  C08G18/3206 ,  C08G18/4225 ,  C08G18/6492 ,  C08G18/664 ,  C08G18/73 ,  C08G18/755 ,  C08G63/133 ,  C08G63/668 ,  C08G63/676 ,  C08G63/914 ,  C08J11/24 ,  C08J2367/02 ,  C09D167/02 ,  C09D167/03 ,  C09D175/06 ,  Y02P20/582 ,  Y02W30/706

Abstract: Polyester polyols, processes for making them, and applications for the polyols are disclosed. In some aspects, the polyols comprise recurring units from a thermoplastic polyester or an aromatic polyacid source, a glycol, and a lignin, tannin, or mixture thereof. Optionally, the polyols incorporate recurring units of a hydrophobe. The polyols are made in one or multiple steps; in some aspects, the thermoplastic polyester or aromatic polyacid source and the glycol are reacted first, followed by reaction with the lignin, tannin, or mixture thereof. High-recycle-content polyols having desirable properties and attributes for formulating polyurethane products, including two-component polyurethane coatings, can be made. The polyols provide a sustainable alternative to bio- or petrochemical-based polyols.

Abstract translation: 公开了聚酯多元醇，其制备方法和多元醇的应用。 在一些方面，多元醇包含来自热塑性聚酯或芳族多酸源，二醇和木质素，单宁或其混合物的重复单元。 任选地，多元醇包含疏水物的重复单元。 多元醇制成一个或多个步骤; 在一些方面，首先使热塑性聚酯或芳族多酸源和二醇反应，然后与木质素，单宁或其混合物反应。 可以制备具有用于配制聚氨酯产品，包括双组分聚氨酯涂料的所需性能和特性的高回收含量的多元醇。 多元醇为生物或石油化学的多元醇提供了可持续的替代方案。

公开(公告)号：US10344121B2

公开(公告)日：2019-07-09

申请号：US15805600

申请日：2017-11-07

Applicant: RESINATE MATERIALS GROUP, INC.

Inventor： Shakti L. Mukerjee ,  Rick Tabor ,  Adam William Emerson ,  Kevin Anthony Rogers ,  Eric D. Vrabel ,  Matthew T. Brown ,  Matthew J. Beatty ,  Jack Rogers Kovsky ,  Michael D. Kellerman ,  Michael Robert Christy

IPC: C08G18/36 ,  C08G63/91 ,  C09D175/06 ,  C08G18/75 ,  C08G18/73 ,  C08G18/42 ,  C08J11/24 ,  C08G63/553 ,  C07C67/03 ,  C07C67/08 ,  C07C69/82 ,  C08G101/00

Abstract: Polyester polyols made from thermoplastic polyesters are disclosed. The polyols can be made by heating a thermoplastic polyester such as virgin PET, recycled PET, or mixtures thereof, with a glycol to give a digested intermediate, which is then condensed with a dimer fatty acid to give the polyol. The invention includes a polyester polyol comprising recurring units of a glycol-digested thermoplastic polyester and a dimer fatty acid. The polyester polyol can also be made in a single step by reacting the thermoplastic polyester, glycol, and dimer acid under conditions effective to produce the polyol. High-recycle-content polyols having desirable properties and attributes for formulating polyurethane products, including aqueous polyurethane dispersions, can be made. The polyols provide a sustainable alternative to bio- or petrochemical-based polyols.

公开(公告)号：US09951171B2

公开(公告)日：2018-04-24

申请号：US14882584

申请日：2015-10-14

Applicant: Resinate Materials Group, Inc.

Inventor： Rick Tabor ,  Eric David Vrabel ,  Matthew J Beatty ,  Gary E. Spilman ,  Kevin Anthony Rogers ,  Michael Robert Christy ,  Matthew Thomas Brown ,  Jack Rogers Kovsky ,  Woo-Sung Bae ,  Shakti L Mukerjee

IPC: C08G18/08 ,  C08G63/183 ,  C08G63/91 ,  C08G18/42 ,  C08F20/10 ,  C09D5/03 ,  C08J3/03 ,  C09D167/00 ,  C09D175/06 ,  C08G63/553 ,  C08G18/72 ,  C08G18/76 ,  C08G63/89 ,  C08G18/66 ,  C08G64/40 ,  C08G18/44 ,  C09D167/02 ,  C08J9/04 ,  C08J11/24 ,  C08G18/09 ,  C09D175/04 ,  C08G101/00

CPC classification number: C08G18/0866 ,  C08F20/10 ,  C08G18/092 ,  C08G18/4213 ,  C08G18/4288 ,  C08G18/44 ,  C08G18/664 ,  C08G18/722 ,  C08G18/7671 ,  C08G63/183 ,  C08G63/553 ,  C08G63/89 ,  C08G63/916 ,  C08G64/403 ,  C08G2101/0025 ,  C08G2150/20 ,  C08J3/03 ,  C08J9/04 ,  C08J11/24 ,  C08J2201/022 ,  C08J2205/06 ,  C08J2205/10 ,  C08J2367/02 ,  C08J2375/06 ,  C09D5/03 ,  C09D167/00 ,  C09D167/02 ,  C09D175/04 ,  C09D175/06 ,  Y02W30/706

Abstract: The present invention relates to polyester polyols made from aromatic polyacid sources such as thermoplastic polyesters. The polyols can be made by heating a thermoplastic polyester such as virgin polyethylene terephthalate, recycled polyethylene terephthalate, or mixtures thereof, with a glycol to give a digested intermediate which is then reacted with a digestible polymer, which can be obtained from various recycle waste streams. The polyester polyols comprise a glycol-digested polyacid source and a further digestible polymer. The polyester polyols provide a sustainable alternative to petrochemical or biochemical based polyester polyols.

公开(公告)号：US20180066174A1

公开(公告)日：2018-03-08

申请号：US15559151

申请日：2016-03-16

Applicant: RESINATE MATERIALS GROUP, INC.

Inventor： Shakti L. Mukerjee ,  Kevin Anthony Rogers ,  Rick Tabor

IPC: C09K8/34 ,  E21B21/00

CPC classification number: C09K8/34 ,  C09K8/035 ,  C09K8/32 ,  C09K2208/34 ,  E21B21/00

Abstract: A drilling fluid comprising a carrier fluid, an aromatic polyester polyol and an additive selected from a thickener, a wetting agent, an emulsifier, a weighting agent, a pH control agent, a lubricant or mixtures thereof.

公开(公告)号：US09751978B2

公开(公告)日：2017-09-05

申请号：US15266247

申请日：2016-09-15

Applicant: Resinate Materials Group, Inc.

Inventor： Shakti Mukerjee ,  Kevin Anthony Rogers ,  Matthew James Beatty ,  Gary E. Spilman

IPC: C08G18/32 ,  C08G18/42 ,  C08G18/64 ,  C08G18/66 ,  C08G18/73 ,  C08G18/75 ,  C08G63/133 ,  C08G63/668 ,  C08G63/676 ,  C08G63/91 ,  C08J11/24 ,  C09D167/02 ,  C09D167/03 ,  C09D175/06

CPC classification number: C08G63/916 ,  C08G18/3206 ,  C08G18/4225 ,  C08G18/6492 ,  C08G18/664 ,  C08G18/73 ,  C08G18/755 ,  C08G63/133 ,  C08G63/668 ,  C08G63/676 ,  C08G63/914 ,  C08J11/24 ,  C08J2367/02 ,  C09D167/02 ,  C09D167/03 ,  C09D175/06 ,  Y02P20/582 ,  Y02W30/706

Abstract: Polyester polyols, processes for making them, and applications for the polyols are disclosed. In some aspects, the polyols comprise recurring units from a thermoplastic polyester or an aromatic polyacid source, a glycol, and a lignin, tannin, or mixture thereof. Optionally, the polyols incorporate recurring units of a hydrophobe. The polyols are made in one or multiple steps; in some aspects, the thermoplastic polyester or aromatic polyacid source and the glycol are reacted first, followed by reaction with the lignin, tannin, or mixture thereof. High-recycle-content polyols having desirable properties and attributes for formulating polyurethane products, including two-component polyurethane coatings, can be made. The polyols provide a sustainable alternative to bio- or petrochemical-based polyols.

公开(公告)号：US20170121457A1

公开(公告)日：2017-05-04

申请号：US15407317

申请日：2017-01-17

Applicant: Resinate Materials Group, Inc.

Inventor： Woo-Sung Bae ,  Rick Tabor ,  Kevin Anthony Rogers ,  Shakti L. Mukerjee

IPC: C08G63/91 ,  C08L67/02 ,  C08L27/06

CPC classification number: C08G63/916 ,  C08J3/18 ,  C08J2300/22 ,  C08J2327/06 ,  C08J2367/02 ,  C08J2367/03 ,  C08J2467/02 ,  C08J2467/03 ,  C08J2469/00 ,  C08J2471/02 ,  C08K5/0016 ,  C08K5/09 ,  C08K5/092 ,  C08L27/06 ,  C08L67/02 ,  C08L67/03 ,  C08L69/00 ,  C08L2205/025 ,  C08L2205/03 ,  C08L2207/04 ,  C08L2207/20

Abstract: The present invention relates to polymeric plasticizer compositions made from an aromatic acid source, a glycol, and a C4-C36 monocarboxylic acid, or ester or anhydride thereof. The aromatic acid source can include polymeric materials such as recycled polyethylene terephthalate (PET). The present invention also relates to methods for making the polymeric plasticizer compositions, to methods of plasticizing polymeric materials, and to plasticized polymeric compositions. The polymeric plasticizers are useful for plasticizing various polymers, such as thermoplastic polymers, including, for example, polyvinyl chloride (PVC). The polymeric plasticizers provide a sustainable alternative to conventional phthalate ester plasticizers, such as diisooctyl phthalate (DOP).