公开(公告)号：US20180237573A1

公开(公告)日：2018-08-23

申请号：US15959596

申请日：2018-04-23

Applicant: RESINATE MATERIALS GROUP, INC.

Inventor： Rick Tabor ,  Eric David Vrabel ,  Matthew J. Beatty ,  Gary E. Spilman ,  Kevin Anthony Rogers ,  Michael Robert Christy ,  Matthew Thomas Brown ,  Jack Rogers Kovsky ,  Woo-Sung Bae ,  Shakti L. Mukerjee

IPC: C08G18/08 ,  C08G18/76 ,  C09D175/06 ,  C09D175/04 ,  C08G64/40 ,  C08G18/42 ,  C08G18/66 ,  C09D167/02 ,  C08G18/09 ,  C08J11/24 ,  C08G63/89 ,  C08G63/91 ,  C09D5/03 ,  C08F20/10 ,  C08G18/72 ,  C08G63/553 ,  C08J9/04 ,  C08G63/183 ,  C08G18/44 ,  C09D167/00 ,  C08J3/03 ,  C08G101/00

CPC classification number: C08G18/0866 ,  C08F20/10 ,  C08G18/092 ,  C08G18/4213 ,  C08G18/4288 ,  C08G18/44 ,  C08G18/664 ,  C08G18/722 ,  C08G18/7671 ,  C08G63/183 ,  C08G63/553 ,  C08G63/89 ,  C08G63/916 ,  C08G64/403 ,  C08G2101/0025 ,  C08G2150/20 ,  C08J3/03 ,  C08J9/04 ,  C08J11/24 ,  C08J2201/022 ,  C08J2205/06 ,  C08J2205/10 ,  C08J2367/02 ,  C08J2375/06 ,  C09D5/03 ,  C09D167/00 ,  C09D167/02 ,  C09D175/04 ,  C09D175/06 ,  Y02W30/706

Abstract: The present invention relates to polyester polyols made from aromatic polyacid sources such as thermoplastic polyesters. The polyols can be made by heating a thermoplastic polyester such as virgin polyethylene terephthalate, recycled polyethylene terephthalate, or mixtures thereof, with a glycol to give a digested intermediate which is then reacted with a digestible polymer, which can be obtained from various recycle waste streams. The polyester polyols comprise a glycol-digested polyacid source and a further digestible polymer. The polyester polyols provide a sustainable alternative to petrochemical or biochemical based polyester polyols.

公开(公告)号：US20170029561A1

公开(公告)日：2017-02-02

申请号：US15205235

申请日：2016-07-08

Applicant: Resinate Materials Group, Inc.

Inventor： Rick Tabor ,  Eric David Vrabel ,  Matthew J. Beatty ,  Gary E. Spilman ,  Kevin Anthony Rogers ,  Michael Robert Christy ,  Matthew Thomas Brown ,  Jack Rogers Kovsky ,  Woo-Sung Bae ,  Shakti L. Mukerjee

IPC: C08G63/91 ,  C08G18/42 ,  C08F20/10 ,  C09D175/06 ,  C09D5/03 ,  C08G18/76 ,  C08G63/183

CPC classification number: C08G63/916 ,  C07C29/09 ,  C07C31/18 ,  C08F20/10 ,  C08F291/08 ,  C08G18/14 ,  C08G18/28 ,  C08G18/4213 ,  C08G18/664 ,  C08G18/722 ,  C08G18/7671 ,  C08G63/183 ,  C08G2101/00 ,  C08G2101/0025 ,  C08G2150/20 ,  C08J9/141 ,  C08J11/24 ,  C08J2203/14 ,  C08J2205/10 ,  C08J2367/02 ,  C08J2375/04 ,  C09D5/03 ,  C09D167/00 ,  C09D175/04 ,  C09D175/06 ,  Y02W30/706

Abstract: The present invention relates to polyester polyols made from aromatic polyacid sources such as thermoplastic polyesters. The polyols can be made by heating a thermoplastic polyester such as virgin polyethylene terephthalate, recycled polyethylene terephthalate, or mixtures thereof, with a glycol to give a digested intermediate which is then reacted with a digestible polymer, which can be obtained from various recycle waste streams. The polyester polyols comprise a glycol-digested polyacid source and a further digestible polymer. The polyester polyols provide a sustainable alternative to petrochemical or biochemical based polyester polyols.

Abstract translation: 本发明涉及由芳族多酸源如热塑性聚酯制成的聚酯多元醇。 多元醇可以通过将热塑性聚酯如原始聚对苯二甲酸乙二醇酯，再循环的聚对苯二甲酸乙二醇酯或其混合物与二醇加热来制备，从而得到消化的中间体，然后与可消化的聚合物反应，该可消化的聚合物可以从各种循环废物流 。 聚酯多元醇包含二醇消化的多酸源和另外的可消化的聚合物。 聚酯多元醇提供石油化学或生物化学基聚酯多元醇的可持续替代品。

公开(公告)号：US20170335057A1

公开(公告)日：2017-11-23

申请号：US15522801

申请日：2015-10-27

Applicant: RESINATE MATERIALS GROUP, INC.

Inventor： Rick Tabor ,  Eric David Vrabel ,  Kevin Anthony Rogers ,  Matthew James Beatty ,  Woo-Sung Bae ,  Jack Rogers Kovsky ,  Michael Robert Christy

IPC: C08G63/66 ,  C09D175/06 ,  C08G18/08 ,  C08G18/76 ,  C08G18/48 ,  C08G18/42 ,  C09J175/06 ,  C08G101/00

CPC classification number: C08G63/66 ,  C08G18/14 ,  C08G18/4244 ,  C08G18/4252 ,  C08G18/4837 ,  C08G18/7621 ,  C08G63/60 ,  C08G2101/0008 ,  C08G2101/0083 ,  C08J11/24 ,  C08J2367/02 ,  C09D175/06 ,  C09J175/06 ,  Y02P20/582 ,  Y02W30/706

Abstract: Polyester polyols, processes for making them, and applications for the polyols are disclosed. In some aspects, the polyols comprise recurring units from a thermoplastic polyester or an aromatic polyacid source, a glycol, and a hydroxy-functional ketal acid, ester or amide. Optionally, the polyols incorporate recurring units of a hydrophobe. The polyols are made in one or multiple steps; in some aspects, the thermoplastic polyester or aromatic polyacid source and the glycol are reacted first, followed by reaction with the hydroxy-functional ketal acid, ester or amide. The resulting polyols have good transparency and little or no particulate settling or phase separation. High-recycle-content polyols having desirable properties and attributes for formulating polyurethane products, including aqueous polyurethane dispersions, flexible and rigid foams, coatings, adhesives, sealants, and elastomers can be made. The polyols provide a sustainable alternative to bio- or petrochemical-based polyols.

公开(公告)号：US20170051103A1

公开(公告)日：2017-02-23

申请号：US15306774

申请日：2015-04-30

Applicant: RESINATE MATERIALS GROUP, INC.

Inventor： Rick Tabor ,  Eric D. Vrabel ,  Kevin Anthony Rogers ,  Shakti L. Mukerjee ,  Matthew J. Beatty ,  Adam William Emerson ,  Matthew T. Brown ,  Jack Rogers Kovsky ,  Michael D. Kellerman ,  Michael Robert Christy

IPC: C08G63/87 ,  C08G18/42 ,  C08G18/72 ,  C08G63/183

CPC classification number: C08G63/87 ,  C07C67/03 ,  C08G18/42 ,  C08G18/4213 ,  C08G18/72 ,  C08G63/183 ,  C08G63/553 ,  C08J11/24 ,  C08J2367/02 ,  Y02P20/582 ,  Y02W30/706 ,  C07C69/82

Abstract: Polyester polyols made from recycled polyethylene terephthalate (rPET) and processes for making them are disclosed. The rPET is heated with a C3-C10 glycol reactant to give a digested intermediate comprising glycols and a terephthalate component, which comprises 45 to 70 wt. % of bis(hydroxyalkyl)terephthalates, and preferably lesser amounts of terephthalate dimers and trimers. Treatment of the digested intermediate with activated carbon gives a polyester polyol having a color index less than 20. The polyols have desirable hydroxyl numbers, viscosities, appearance, and other attributes for formulating polyurethane products and are a sustainable alternative to bio- or petrochemical-based polyols.

Abstract translation: 公开了由回收聚对苯二甲酸乙二醇酯（rPET）制成的聚酯多元醇及其制备方法。 用C 3 -C 10二醇反应物加热rPET，得到包含二醇和对苯二甲酸酯组分的消化的中间体，其包含45至70重量％ ％的双（羟烷基）对苯二甲酸酯，优选较少量的对苯二甲酸酯二聚体和三聚体。 用活性炭处理消化的中间体可得到颜色指数小于20的聚酯多元醇。多元醇具有理想的羟基数，粘度，外观和其他配方聚氨酯产品的特性，是生物或石油化学品的可持续替代品 多元醇。

公开(公告)号：US20190241702A1

公开(公告)日：2019-08-08

申请号：US16383951

申请日：2019-04-15

Applicant: RESINATE MATERIALS GROUP, INC.

Inventor： Shakti L. Mukerjee ,  Rick Tabor ,  Adam William Emerson ,  Kevin Anthony Rogers ,  Eric D. Vrabel ,  Matthew T. Brown ,  Matthew J. Beatty ,  Jack Rogers Kovsky ,  Michael D. Kellerman ,  Michael Robert Christy

IPC: C08G63/91 ,  C08G18/42 ,  C08J11/24 ,  C08G18/75 ,  C09D175/06 ,  C08G18/73 ,  C08G63/553 ,  C08G18/36 ,  C07C69/82 ,  C07C67/08 ,  C07C67/03

CPC classification number: C08G63/916 ,  C07C67/03 ,  C07C67/08 ,  C07C69/82 ,  C07C2601/14 ,  C08G18/36 ,  C08G18/4213 ,  C08G18/4288 ,  C08G18/735 ,  C08G18/755 ,  C08G63/553 ,  C08G2101/0008 ,  C08G2101/0025 ,  C08J11/24 ,  C08J2367/02 ,  C09D167/07 ,  C09D175/06 ,  Y02W30/706

Abstract: Polyester polyols made from thermoplastic polyesters are disclosed. The polyols can be made by heating a thermoplastic polyester such as virgin PET, recycled PET, or mixtures thereof, with a glycol to give a digested intermediate, which is then condensed with a dimer fatty acid to give the polyol. The invention includes a polyester polyol comprising recurring units of a glycol-digested thermoplastic polyester and a dimer fatty acid. The polyester polyol can also be made in a single step by reacting the thermoplastic polyester, glycol, and dimer acid under conditions effective to produce the polyol. High-recycle-content polyols having desirable properties and attributes for formulating polyurethane products, including aqueous polyurethane dispersions, can be made. The polyols provide a sustainable alternative to bio- or petrochemical-based polyols.

公开(公告)号：US09840584B2

公开(公告)日：2017-12-12

申请号：US14822528

申请日：2015-08-10

Applicant: Resinate Materials Group, Inc.

Inventor： Shakti L Mukerjee ,  Rick Tabor ,  Adam William Emerson ,  Kevin Anthony Rogers ,  Eric D Vrabel ,  Matthew T Brown ,  Matthew J Beatty ,  Jack Rogers Kovsky ,  Michael D Kellerman ,  Michael Robert Christy

IPC: C08G63/91 ,  C09D175/06 ,  C08G18/75 ,  C08G18/73 ,  C08G18/42 ,  C08J11/24 ,  C08G63/553 ,  C08G18/36 ,  C07C67/03 ,  C07C67/08 ,  C07C69/82 ,  C08G101/00

CPC classification number: C08G63/916 ,  C07C67/03 ,  C07C67/08 ,  C07C69/82 ,  C07C2601/14 ,  C08G18/36 ,  C08G18/4213 ,  C08G18/4288 ,  C08G18/735 ,  C08G18/755 ,  C08G63/553 ,  C08G2101/0008 ,  C08G2101/0025 ,  C08J11/24 ,  C08J2367/02 ,  C09D167/07 ,  C09D175/06 ,  Y02W30/706

Abstract: Polyester polyols made from thermoplastic polyesters are disclosed. The polyols can be made by heating a thermoplastic polyester such as virgin PET, recycled PET, or mixtures thereof, with a glycol to give a digested intermediate, which is then condensed with a dimer fatty acid to give the polyol. The invention includes a polyester polyol comprising recurring units of a glycol-digested thermoplastic polyester and a dimer fatty acid. The polyester polyol can also be made in a single step by reacting the thermoplastic polyester, glycol, and dimer acid under conditions effective to produce the polyol. High-recycle-content polyols having desirable properties and attributes for formulating polyurethane products, including aqueous polyurethane dispersions, can be made. The polyols provide a sustainable alternative to bio- or petrochemical-based polyols.

公开(公告)号：US10344121B2

公开(公告)日：2019-07-09

申请号：US15805600

申请日：2017-11-07

Applicant: RESINATE MATERIALS GROUP, INC.

Inventor： Shakti L. Mukerjee ,  Rick Tabor ,  Adam William Emerson ,  Kevin Anthony Rogers ,  Eric D. Vrabel ,  Matthew T. Brown ,  Matthew J. Beatty ,  Jack Rogers Kovsky ,  Michael D. Kellerman ,  Michael Robert Christy

IPC: C08G18/36 ,  C08G63/91 ,  C09D175/06 ,  C08G18/75 ,  C08G18/73 ,  C08G18/42 ,  C08J11/24 ,  C08G63/553 ,  C07C67/03 ,  C07C67/08 ,  C07C69/82 ,  C08G101/00

Abstract: Polyester polyols made from thermoplastic polyesters are disclosed. The polyols can be made by heating a thermoplastic polyester such as virgin PET, recycled PET, or mixtures thereof, with a glycol to give a digested intermediate, which is then condensed with a dimer fatty acid to give the polyol. The invention includes a polyester polyol comprising recurring units of a glycol-digested thermoplastic polyester and a dimer fatty acid. The polyester polyol can also be made in a single step by reacting the thermoplastic polyester, glycol, and dimer acid under conditions effective to produce the polyol. High-recycle-content polyols having desirable properties and attributes for formulating polyurethane products, including aqueous polyurethane dispersions, can be made. The polyols provide a sustainable alternative to bio- or petrochemical-based polyols.

公开(公告)号：US09951171B2

公开(公告)日：2018-04-24

申请号：US14882584

申请日：2015-10-14

Applicant: Resinate Materials Group, Inc.

Inventor： Rick Tabor ,  Eric David Vrabel ,  Matthew J Beatty ,  Gary E. Spilman ,  Kevin Anthony Rogers ,  Michael Robert Christy ,  Matthew Thomas Brown ,  Jack Rogers Kovsky ,  Woo-Sung Bae ,  Shakti L Mukerjee

IPC: C08G18/08 ,  C08G63/183 ,  C08G63/91 ,  C08G18/42 ,  C08F20/10 ,  C09D5/03 ,  C08J3/03 ,  C09D167/00 ,  C09D175/06 ,  C08G63/553 ,  C08G18/72 ,  C08G18/76 ,  C08G63/89 ,  C08G18/66 ,  C08G64/40 ,  C08G18/44 ,  C09D167/02 ,  C08J9/04 ,  C08J11/24 ,  C08G18/09 ,  C09D175/04 ,  C08G101/00

CPC classification number: C08G18/0866 ,  C08F20/10 ,  C08G18/092 ,  C08G18/4213 ,  C08G18/4288 ,  C08G18/44 ,  C08G18/664 ,  C08G18/722 ,  C08G18/7671 ,  C08G63/183 ,  C08G63/553 ,  C08G63/89 ,  C08G63/916 ,  C08G64/403 ,  C08G2101/0025 ,  C08G2150/20 ,  C08J3/03 ,  C08J9/04 ,  C08J11/24 ,  C08J2201/022 ,  C08J2205/06 ,  C08J2205/10 ,  C08J2367/02 ,  C08J2375/06 ,  C09D5/03 ,  C09D167/00 ,  C09D167/02 ,  C09D175/04 ,  C09D175/06 ,  Y02W30/706

Abstract: The present invention relates to polyester polyols made from aromatic polyacid sources such as thermoplastic polyesters. The polyols can be made by heating a thermoplastic polyester such as virgin polyethylene terephthalate, recycled polyethylene terephthalate, or mixtures thereof, with a glycol to give a digested intermediate which is then reacted with a digestible polymer, which can be obtained from various recycle waste streams. The polyester polyols comprise a glycol-digested polyacid source and a further digestible polymer. The polyester polyols provide a sustainable alternative to petrochemical or biochemical based polyester polyols.

公开(公告)号：US20150344622A1

公开(公告)日：2015-12-03

申请号：US14822528

申请日：2015-08-10

Applicant: Resinate Materials Group, Inc.

Inventor： Shakti L. Mukerjee ,  Rick Tabor ,  Adam William Emerson ,  Kevin Anthony Rogers ,  Eric D. Vrabel ,  Matthew T. Brown ,  Matthew J. Beatty ,  Jack Rogers Kovsky ,  Michael D. Kellerman ,  Michael Robert Christy

IPC: C08G63/91 ,  C08G18/42 ,  C08G18/75 ,  C08G18/73 ,  C09D175/06 ,  C09D167/07

CPC classification number: C08G63/916 ,  C07C67/03 ,  C07C67/08 ,  C07C69/82 ,  C07C2601/14 ,  C08G18/36 ,  C08G18/4213 ,  C08G18/4288 ,  C08G18/735 ,  C08G18/755 ,  C08G63/553 ,  C08G2101/0008 ,  C08G2101/0025 ,  C08J11/24 ,  C08J2367/02 ,  C09D167/07 ,  C09D175/06 ,  Y02W30/706

Abstract: Polyester polyols made from thermoplastic polyesters are disclosed. The polyols can be made by heating a thermoplastic polyester such as virgin PET, recycled PET, or mixtures thereof, with a glycol to give a digested intermediate, which is then condensed with a dimer fatty acid to give the polyol. The invention includes a polyester polyol comprising recurring units of a glycol-digested thermoplastic polyester and a dimer fatty acid. The polyester polyol can also be made in a single step by reacting the thermoplastic polyester, glycol, and dimer acid under conditions effective to produce the polyol. High-recycle-content polyols having desirable properties and attributes for formulating polyurethane products, including aqueous polyurethane dispersions, can be made. The polyols provide a sustainable alternative to bio- or petrochemical-based polyols.

Abstract translation: 公开了由热塑性聚酯制成的聚酯多元醇。 多元醇可以通过将热塑性聚酯如原始PET，再循环PET或其混合物与二醇加热来制备，得到消化的中间体，然后将其与二聚脂肪酸缩合得到多元醇。 本发明包括含有二醇消化的热塑性聚酯和二聚脂肪酸的重复单元的聚酯多元醇。 聚酯多元醇也可以通过在有效制备多元醇的条件下使热塑性聚酯，二醇和二聚酸反应在一个步骤中制备。 可以制备具有用于配制聚氨酯产品（包括水性聚氨酯分散体）的所需性质和特性的高回收含量的多元醇。 多元醇为生物或石油化学的多元醇提供了可持续的替代方案。

公开(公告)号：US10273332B2

公开(公告)日：2019-04-30

申请号：US15306774

申请日：2015-04-30

Applicant: Resinate Materials Group, Inc.

Inventor： Rick Tabor ,  Eric D. Vrabel ,  Kevin Anthony Rogers ,  Shakti L. Mukerjee ,  Matthew J. Beatty ,  Adam William Emerson ,  Matthew T. Brown ,  Jack Rogers Kovsky ,  Michael D. Kellerman ,  Michael Robert Christy

IPC: C07C67/03 ,  C07C69/82 ,  C08G18/42 ,  C08G18/72 ,  C08G63/87 ,  C08J11/24 ,  C08G63/183 ,  C08G63/553

Abstract: Polyester polyols made from recycled polyethylene terephthalate (rPET) and processes for making them are disclosed. The rPET is heated with a C3-C10 glycol reactant to give a digested intermediate comprising glycols and a terephthalate component, which comprises 45 to 70 wt. % of bis(hydroxyalkyl)terephthalates, and preferably lesser amounts of terephthalate dimers and trimers. Treatment of the digested intermediate with activated carbon gives a polyester polyol having a color index less than 20. The polyols have desirable hydroxyl numbers, viscosities, appearance, and other attributes for formulating polyurethane products and are a sustainable alternative to bio- or petrochemical-based polyols.