公开(公告)号：US09776179B2

公开(公告)日：2017-10-03

申请号：US15354916

申请日：2016-11-17

申请人： PROVIVI, INC.

发明人： Keith M Wampler ,  Peter Meinhold ,  Pedro Coelho ,  Vu Bui ,  Levente Ondi ,  Hasan Mehdi

IPC分类号： B01J31/22 ,  C07C29/147 ,  C07C67/08 ,  C07C67/343 ,  C07C45/41 ,  C07C6/04 ,  C07C67/293

CPC分类号： B01J31/2278 ,  B01J2231/543 ,  B01J2531/64 ,  B01J2531/66 ,  C07B2200/09 ,  C07C6/04 ,  C07C29/147 ,  C07C45/41 ,  C07C67/08 ,  C07C67/293 ,  C07C67/343 ,  C07C2531/22 ,  C07C69/533 ,  C07C33/025 ,  C07C69/145 ,  C07C47/21 ,  C07C11/21

摘要： In one aspect, the invention provides a method for synthesizing a fatty olefin derivative. The method includes: a) contacting an olefin according to Formula I with a metathesis reaction partner according to Formula IIb in the presence of a metathesis catalyst under conditions sufficient to form a metathesis product according to Formula IIIb: and b) converting the metathesis product to the fatty olefin derivative. Each R1 is independently selected from H, C1-18 alkyl, and C2-18 alkenyl; R2b is C1-8 alkyl; subscript y is an integer ranging from 0 to 17; and subscript z is an integer ranging from 0 to 17. In certain embodiments, the metathesis catalyst is a tungsten catalyst or a molybdenum catalyst. In various embodiments, the fatty olefin derivative is a pheromone. Pheromone compositions and methods of using them are also described.

公开(公告)号：US10596562B2

公开(公告)日：2020-03-24

申请号：US15721018

申请日：2017-09-29

申请人： Provivi, Inc.

发明人： Keith M. Wampler ,  Peter Meinhold ,  Pedro Coelho ,  Vu Bui ,  Levente Ondi ,  Hasan Mehdi

IPC分类号： B01J31/22 ,  C07C67/293 ,  C07C67/343 ,  C07C67/08 ,  C07C45/41 ,  C07C29/147 ,  C07C6/04

摘要： In one aspect, the invention provides a method for synthesizing a fatty olefin derivative. The method includes: a) contacting an olefin according to Formula I with a metathesis reaction partner according to Formula IIb in the presence of a metathesis catalyst under conditions sufficient to form a metathesis product according to Formula IIIb: and b) converting the metathesis product to the fatty olefin derivative. Each R1 is independently selected from H, C1-18 alkyl, and C2-18 alkenyl; R2b is C1-8 alkyl; subscript y is an integer ranging from 0 to 17; and subscript z is an integer ranging from 0 to 17. In certain embodiments, the metathesis catalyst is a tungsten catalyst or a molybdenum catalyst. In various embodiments, the fatty olefin derivative is a pheromone. Pheromone compositions and methods of using them are also described.

公开(公告)号：US20180099268A1

公开(公告)日：2018-04-12

申请号：US15721018

申请日：2017-09-29

申请人： Provivi, Inc.

发明人： Keith M. Wampler ,  Peter Meinhold ,  Pedro Coelho ,  Vu Bui ,  Levente Ondi ,  Hasan Mehdi

IPC分类号： B01J31/22 ,  C07C6/04 ,  C07C29/147 ,  C07C67/08 ,  C07C67/293 ,  C07C67/343 ,  C07C45/41

CPC分类号： B01J31/2278 ,  B01J2231/543 ,  B01J2531/64 ,  B01J2531/66 ,  C07B2200/09 ,  C07C6/04 ,  C07C29/147 ,  C07C45/41 ,  C07C67/08 ,  C07C67/293 ,  C07C67/343 ,  C07C2531/22 ,  C07C69/533 ,  C07C33/025 ,  C07C69/145 ,  C07C47/21 ,  C07C11/21

摘要： In one aspect, the invention provides a method for synthesizing a fatty olefin derivative. The method includes: a) contacting an olefin according to Formula I with a metathesis reaction partner according to Formula IIb in the presence of a metathesis catalyst under conditions sufficient to form a metathesis product according to Formula IIIb: and b) converting the metathesis product to the fatty olefin derivative. Each R1 is independently selected from H, C1-18 alkyl, and C2-18 alkenyl; R2b is C1-8 alkyl; subscript y is an integer ranging from 0 to 17; and subscript z is an integer ranging from 0 to 17. In certain embodiments, the metathesis catalyst is a tungsten catalyst or a molybdenum catalyst. In various embodiments, the fatty olefin derivative is a pheromone. Pheromone compositions and methods of using them are also described.

公开(公告)号：US11155505B2

公开(公告)日：2021-10-26

申请号：US16543384

申请日：2019-08-16

申请人： Provivi, Inc.

发明人： Keith M. Wampler ,  Vu Bui ,  David Rozzell ,  Pedro Coelho ,  Arthur Floruti ,  Levente Ondi ,  Hasan Mehdi ,  Gabor Eros

IPC分类号： C07C6/04 ,  B01J31/22

摘要： Methods for preparation of olefins, including 8- and 11-unsaturated monoenes and polyenes, via transition metathesis-based synthetic routes are described. Metathesis reactions in the methods are catalyzed by transition metal catalysts including tungsten-, molybdenum-, and ruthenium-based catalysts. The olefins include insect pheromones useful in a number of agricultural applications.

公开(公告)号：US11077433B2

公开(公告)日：2021-08-03

申请号：US16798954

申请日：2020-02-24

申请人： Provivi, Inc.

发明人： Keith M. Wampler ,  Peter Meinhold ,  Pedro Coelho ,  Vu Bui ,  Levente Ondi ,  Hasan Mehdi

IPC分类号： B01J31/22 ,  C07C29/147 ,  C07C67/08 ,  C07C67/343 ,  C07C45/41 ,  C07C6/04 ,  C07C67/293

摘要： In one aspect, the invention provides a method for synthesizing a fatty olefin derivative. The method includes: a) contacting an olefin according to Formula I with a metathesis reaction partner according to Formula IIb in the presence of a metathesis catalyst under conditions sufficient to form a metathesis product according to Formula IIIb: and b) converting the metathesis product to the fatty olefin derivative. Each R1 is independently selected from H, C1-18 alkyl, and C2-18 alkenyl; R2b is C1-8 alkyl; subscript y is an integer ranging from 0 to 17; and subscript z is an integer ranging from 0 to 17. In certain embodiments, the metathesis catalyst is a tungsten catalyst or a molybdenum catalyst. In various embodiments, the fatty olefin derivative is a pheromone. Pheromone compositions and methods of using them are also described.

公开(公告)号：US20200261898A1

公开(公告)日：2020-08-20

申请号：US16798954

申请日：2020-02-24

申请人： Provivi, Inc.

发明人： Keith M. Wampler ,  Peter Meinhold ,  Pedro Coelho ,  Vu Bui ,  Levente Ondi ,  Hasan Mehdi

IPC分类号： B01J31/22 ,  C07C67/293 ,  C07C6/04 ,  C07C45/41 ,  C07C67/343 ,  C07C67/08 ,  C07C29/147

摘要： In one aspect, the invention provides a method for synthesizing a fatty olefin derivative. The method includes: a) contacting an olefin according to Formula I with a metathesis reaction partner according to Formula IIb in the presence of a metathesis catalyst under conditions sufficient to form a metathesis product according to Formula IIIb: and b) converting the metathesis product to the fatty olefin derivative. Each R1 is independently selected from H, C1-18 alkyl, and C2-18 alkenyl; R2b is C1-8 alkyl; subscript y is an integer ranging from 0 to 17; and subscript z is an integer ranging from 0 to 17. In certain embodiments, the metathesis catalyst is a tungsten catalyst or a molybdenum catalyst. In various embodiments, the fatty olefin derivative is a pheromone. Pheromone compositions and methods of using them are also described.

公开(公告)号：US20200039900A1

公开(公告)日：2020-02-06

申请号：US16543384

申请日：2019-08-16

申请人： Provivi, Inc.

发明人： Keith M. Wampler ,  Vu Bui ,  David Rozzell ,  Pedro Coelho ,  Arthur Floruti ,  Levente Ondi ,  Hasan Mehdi ,  Gabor Eros

IPC分类号： C07C6/04 ,  B01J31/22

摘要： Methods for preparation of olefins, including 8- and 11-unsaturated monoenes and polyenes, via transition metathesis-based synthetic routes are described. Metathesis reactions in the methods are catalyzed by transition metal catalysts including tungsten-, molybdenum-, and ruthenium-based catalysts. The olefins include insect pheromones useful in a number of agricultural applications.