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1.发明授权Process for preparing nonionic surfactants-oxyalkylation with calcium and/or strontium catalysts 失效用钙和/或锶催化剂制备非离子表面活性剂 - 烷氧基化的方法
公开(公告)号：US4453022A
公开(公告)日：1984-06-05
申请号：US370204
申请日：1982-04-21
IPC分类号： C11D1/72 , B01F17/42 , B01J27/00 , B01J27/04 , B01J27/16 , B01J27/20 , B01J31/00 , B01J31/02 , B01J31/04 , C07B61/00 , C07C41/00 , C07C41/02 , C07C41/03 , C07C43/11 , C07C67/00 , C08G65/26 , C08G65/28
CPC分类号： C08G65/2651 , B01J31/0212 , B01J31/0214 , C07C41/03 , B01J2231/48
摘要： The process for preparing nonionic surfactants wherein a narrower molecular weight distribution is obtained by the use of a calcium and/or strontium catalyst which comprises reacting a reactive hydrogen compound selected from the group consisting of monohydric alcohols having from about 8 to about 20 carbon atoms and a difunctional polypropylene oxide polymer having an average molecular weight in the range of 1000 to 5000 with an alkylene oxide having 2 to 4 carbon atoms at a temperature at which the reaction proceeds in the presence of at least a catalytic amount of a basic salt of calcium and/or strontium selected from the group consisting of hydroxide, alkoxide and phenoxides and a catalytic amount of an oxyalkylation catalyst promoter.
摘要翻译： 制备非离子表面活性剂的方法，其中通过使用钙和/或锶催化剂获得较窄的分子量分布，该方法包括使选自具有约8至约20个碳原子的一元醇的反应性氢化合物与 在至少催化量的碱性盐的存在下，在反应进行的温度下，平均分子量为1000〜5000的具有2〜4个碳原子的烯化氧的双官能聚环氧丙烷聚合物 和/或选自氢氧化物，醇盐和苯氧化物的锶和催化量的烷氧基化催化剂促进剂。
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2.发明授权Process for preparing nonionic surfactants-oxyalkylation with promoted barium catalysts 失效用促进的钡催化剂制备非离子表面活性剂 - 烷氧基化的方法
公开(公告)号：US4453023A
公开(公告)日：1984-06-05
申请号：US454573
申请日：1982-12-30
IPC分类号： C07C41/02 , B01F17/42 , B01J27/00 , B01J27/16 , B01J31/00 , B01J31/02 , B01J31/26 , C07B61/00 , C07C41/00 , C07C41/03 , C07C43/11 , C07C67/00 , C08G65/26 , B01J23/02
CPC分类号： C08G65/2651 , C07C41/03
摘要： The process for preparing nonionic surfactants wherein a narrower molecular weight distribution is obtained by the use of a barium catalyst which comprises reacting a reactive hydrogen compound selected from the group consisting of monohydric alcohols having from about 8 to about 20 carbon atoms and a difunctional polypropylene oxide polymer having an average molecular weight in the range of 1000 to 5000 with an alkylene oxide having 2 to 4 carbon atoms at a temperature at which the reaction proceeds in the presence of at least a catalytic amount of a barium salt selected from the group consisting of barium hydroxide, barium alkoxides, barium phenoxides, hydrates thereof or mixtures thereof and a catalytic amount of an oxyalkylation catalyst promoter.
摘要翻译： 制备非离子表面活性剂的方法，其中通过使用钡催化剂获得较窄的分子量分布，该钡催化剂包括使选自具有约8至约20个碳原子的一元醇的反应性氢化合物与二官能聚环氧丙烷 在至少催化量的选自以下的钡盐的存在下，在反应进行的温度下，平均分子量为1000-5000的聚合物与具有2至4个碳原子的烯化氧反应， 氢氧化钡，烷氧化钡，苯氧化钡，其水合物或其混合物和催化量的烷氧基化催化剂促进剂。
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公开(公告)号：US4187383A
公开(公告)日：1980-02-05
申请号：US755046
申请日：1976-12-28
摘要： Low color residue acrylate esters are produced by reacting an organic polyol such as neopentyl glycol, pentaerythritol, or 3'-hydroxy-2',2'-dimethylpropyl 3-hydroxy-2,2-dimethylpropionate with acrylic or methacrylic acid in contact with a lower alkoxy substituted phenolic or alkylated alkoxyphenolic polymerization inhibitor at a critical low reaction temperature of from 20.degree. C. to 80.degree. C.
摘要翻译： 低级残留丙烯酸酯通过有机多元醇如新戊二醇，季戊四醇或3'-羟基-2'，2'-二甲基丙基3-羟基-2,2-二甲基丙酸酯与丙烯酸或甲基丙烯酸与 低级烷氧基取代的酚或烷基化烷氧基酚聚合抑制剂在20℃至80℃的临界低反应温度
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公开(公告)号：US4448977A
公开(公告)日：1984-05-15
申请号：US411620
申请日：1982-08-26
IPC分类号： A01N35/02 , C07C41/58 , C07C45/60 , C07C45/86 , C07D309/10 , C07D309/06 , C07C41/46 , C07C47/198
CPC分类号： C07D309/10 , A01N35/02 , C07C41/58 , C07C45/60 , C07C45/86 , Y10S507/92
摘要： A storage stable composition of glutaraldehyde acetals and an organic acidic catalyst, which can be converted to glutaraldehyde at the site and upon demand, by the addition of water.
摘要翻译： 戊二醛缩醛和有机酸性催化剂的储存稳定组合物，可通过加入水在现场和需要时转化成戊二醛。
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公开(公告)号：US4820673A
公开(公告)日：1989-04-11
申请号：US156733
申请日：1988-02-18
CPC分类号： C07C43/11 , B01J31/1805 , B01J31/181 , B01J31/223 , B01J31/2243 , B01J31/24 , C07C41/03 , B01J2231/4288 , B01J2231/48 , B01J2531/23 , B01J31/26
摘要： Narrow, balanced alkoxylation product mixture distributions having at least one alkoxylation product constituting more than 20 weight percent of the mixture can be provided by modified, calcium-containing catalysts. Catalysts for alkoxylation processes can be produced from lime and can, with modification, be used to make the narrow, balanced alkoxylation product mixture distribution.
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公开(公告)号：US4754075A
公开(公告)日：1988-06-28
申请号：US916012
申请日：1986-10-06
CPC分类号： C07C43/11 , B01J31/1805 , B01J31/181 , B01J31/223 , B01J31/2243 , B01J31/24 , C07C41/03 , B01J2231/4288 , B01J2231/48 , B01J2531/23 , B01J31/26
摘要： Narrow, balanced alkoxylation product mixture distributions having at least one alkoxylation product constituting more than 20 weight percent of the mixture can be provided by modified, calcium-containing catalysts. Catalysts for alkoxylation processes can be produced from lime and can, with modification, be used to make the narrow, balanced alkoxylation product mixture distribution.
摘要翻译： 通过改性的含钙催化剂可以提供具有构成混合物的20重量％以上的至少一个烷氧基化产物的窄的平衡的烷氧基化产物混合物分布。 用于烷氧基化方法的催化剂可以由石灰生产，并且可以通过改性来制备窄的平衡的烷氧基化产物混合物分布。
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公开(公告)号：US4886917A
公开(公告)日：1989-12-12
申请号：US916015
申请日：1986-10-06
CPC分类号： C07C43/11 , B01J31/1805 , B01J31/181 , B01J31/223 , B01J31/2243 , B01J31/24 , C07C41/03 , B01J2231/4288 , B01J2231/48 , B01J2531/23 , B01J31/26
摘要： Narrow, balanced alkoxylation product mixture distributions having at least one alkoxylation product constituting more than 20 weight percent of the mixture can be provided by modified, calcium-containing catalysts. Catalysts for alkoxylation processes can be produced from lime and can, with modification, be used to make the narrow, balanced alkoxylation product mixture distribution.
摘要翻译： 通过改性的含钙催化剂可以提供具有构成混合物的20重量％以上的至少一个烷氧基化产物的窄的平衡的烷氧基化产物混合物分布。 用于烷氧基化方法的催化剂可以由石灰生产，并且可以通过改性来制备窄的平衡的烷氧基化产物混合物分布。
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公开(公告)号：US4172097A
公开(公告)日：1979-10-23
申请号：US936843
申请日：1978-08-25
CPC分类号： C07C45/48
摘要： In the production of propiophenone by a vapor-phase, cross-decarboxylation process, an undesirable by-product, isobutyrophenone, is suppressed by addition of water or steam to the reactant stream.
摘要翻译： {PG，1在通过气相生产苯丙酮的交叉脱羧方法中，通过向反应物流中加入水或蒸汽来抑制不期望的副产物异丁酰苯。
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公开(公告)号：US4167635A
公开(公告)日：1979-09-11
申请号：US936726
申请日：1978-08-25
IPC分类号： C07D295/205 , C07D295/18
CPC分类号： C07D295/205
摘要： There are claimed novel carbamoyloxy acrylate compounds of the formula ##STR1## wherein R.sub.1 and R.sub.2 are each hydrogen or alkyl of up to 10 carbon atoms; R.sub.5 and R.sub.6 are each methylene, ethylene, or 1,2-propylene; and R.sub.10 is hydrogen or methyl. The compounds are polymerizable to produce materials useful, for example, in coatings.
摘要翻译： 要求新的式（ⅠA）的氨基甲酰氧基丙烯酸酯化合物，其中R 1和R 2各自为氢或至多10个碳原子的烷基; R5和R6各自为亚甲基，亚乙基或1,2-亚丙基; R 10为氢或甲基。 这些化合物是可聚合的，以产生可用于例如涂料中的材料。
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公开(公告)号：US4126747A
公开(公告)日：1978-11-21
申请号：US755063
申请日：1976-12-28
IPC分类号： C07D295/205 , C07C125/06 , C07D295/16
CPC分类号： C07D295/205
摘要： Unsaturated carbamoyloxy carboxylates having low color are produced by reacting hydroxyalkyl carbamates such as N-methyl 2-hydroxyethyl carbamate with acrylic or methacrylic acid in contact with a lower alkoxy substituted phenolic or alkylated alkoxyphenolic polymerization inhibitor at a critical low reaction temperature of 40.degree. C. to 80.degree. C. Novel unsaturated carbamoyloxy carboxylates are also disclosed.
摘要翻译： 具有低颜色的不饱和的氨基甲酰氧基羧酸盐通过氨基甲酸羟烷基酯如氨基甲酸2-甲基-2-羟乙酯与丙烯酸或甲基丙烯酸与低级烷氧基取代的酚或烷基化烷氧基酚聚合抑制剂在40℃的临界低反应温度下接触而制备。 还公开了新的不饱和氨基甲酰氧基羧酸盐。
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