发明授权
US4453022A Process for preparing nonionic surfactants-oxyalkylation with calcium
and/or strontium catalysts
失效
用钙和/或锶催化剂制备非离子表面活性剂 - 烷氧基化的方法
- 专利标题: Process for preparing nonionic surfactants-oxyalkylation with calcium and/or strontium catalysts
- 专利标题(中): 用钙和/或锶催化剂制备非离子表面活性剂 - 烷氧基化的方法
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申请号: US370204申请日: 1982-04-21
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公开(公告)号: US4453022A公开(公告)日: 1984-06-05
- 发明人: James H. McCain , Louis F. Theiling, Jr.
- 申请人: James H. McCain , Louis F. Theiling, Jr.
- 申请人地址: CT Danbury
- 专利权人: Union Carbide Corporation
- 当前专利权人: Union Carbide Corporation
- 当前专利权人地址: CT Danbury
- 主分类号: C11D1/72
- IPC分类号: C11D1/72 ; B01F17/42 ; B01J27/00 ; B01J27/04 ; B01J27/16 ; B01J27/20 ; B01J31/00 ; B01J31/02 ; B01J31/04 ; C07B61/00 ; C07C41/00 ; C07C41/02 ; C07C41/03 ; C07C43/11 ; C07C67/00 ; C08G65/26 ; C08G65/28
摘要:
The process for preparing nonionic surfactants wherein a narrower molecular weight distribution is obtained by the use of a calcium and/or strontium catalyst which comprises reacting a reactive hydrogen compound selected from the group consisting of monohydric alcohols having from about 8 to about 20 carbon atoms and a difunctional polypropylene oxide polymer having an average molecular weight in the range of 1000 to 5000 with an alkylene oxide having 2 to 4 carbon atoms at a temperature at which the reaction proceeds in the presence of at least a catalytic amount of a basic salt of calcium and/or strontium selected from the group consisting of hydroxide, alkoxide and phenoxides and a catalytic amount of an oxyalkylation catalyst promoter.
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