发明授权
US4453022A Process for preparing nonionic surfactants-oxyalkylation with calcium and/or strontium catalysts 失效
用钙和/或锶催化剂制备非离子表面活性剂 - 烷氧基化的方法

Process for preparing nonionic surfactants-oxyalkylation with calcium
and/or strontium catalysts
摘要:
The process for preparing nonionic surfactants wherein a narrower molecular weight distribution is obtained by the use of a calcium and/or strontium catalyst which comprises reacting a reactive hydrogen compound selected from the group consisting of monohydric alcohols having from about 8 to about 20 carbon atoms and a difunctional polypropylene oxide polymer having an average molecular weight in the range of 1000 to 5000 with an alkylene oxide having 2 to 4 carbon atoms at a temperature at which the reaction proceeds in the presence of at least a catalytic amount of a basic salt of calcium and/or strontium selected from the group consisting of hydroxide, alkoxide and phenoxides and a catalytic amount of an oxyalkylation catalyst promoter.
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