摘要:
Dyestuffs of the formula ##STR1## WHEREIN R.sub.1 denotes halogen, alkyl, cycloalkyl, aralkyl, nitro, cyano, acyl, acylamino, amino, aminocarbonyl, aminosulphonyl, arylsulphonyl, alkylsulphonyl, alkoxy, aryloxy, aralkoxy, carboxyl, alkoxycarbonyl, aryloxycarbonyl or aralkoxycarbonyl or arylazo,R.sub.2 denotes alkyl, alkenyl, cycloalkyl, aryl or aralkyl,R.sub.3 denotes alkyl, cycloalkyl or aralkyl,R.sub.4 denotes alkyl, cycloalkyl or aralkyl,R.sub.5, r.sub.6, r.sub.7 and R.sub.8 denote hydrogen, alkyl, cycloalkyl, aralkyl or aryl and R.sub.6 and R.sub.7 conjointly can form a fused cycloaliphatic ring,R.sub.9 denotes chlorine, bromine, nitro, cyano, C.sub.1 -C.sub.4 -alkyl, phenyl, benzyl, C.sub.1 -C.sub.4 -alkoxy, phenoxy, benzyloxy, C.sub.1 -C.sub.4 -alkoxycarbonyl, phenoxycarbonyl, benzyloxycarbonyl, carboxyl, C.sub.1 -C.sub.4 -alkylsulphonyl, phenylsulphonyl, benzylsulphonyl, C.sub.1 -C.sub.4 -alkoxysulphonyl, phenoxysulphonyl, benzyloxysulphonyl, aminocarbonyl, mono- or di- C.sub.1 -C.sub.4 -alkylaminocarbonyl, aminosulphonyl, mono- di- C.sub.1 -C.sub.4 -alkylamino-sulphonyl, C.sub.1 -C.sub.3 -alkylcarbonyl, C.sub.1 -C.sub.3 -alkylcarbonylamino, benzoylamino, phenylamino, mono- or di- C.sub.1 -C.sub.4 -alkylamino, benzylamino or phenylazo,n denotes 0, 1 or 2,m denotes 0, 1, 2 or 3 andAnd whereinAt least one of the radicals R.sub.1, R.sub.2 or R.sub.9 denotes a radical of the formula--A--O--(B--O).sub.p --E--a--o--co--f--o--(b--o).sub.p --E or--A--(O--F).sub.q --CO--O--(B--O).sub.p --Eor is substituted by such a radical,WhereinA represents an alkylene or alkenylene radical or a direct bond,B represents an alkylene or alkenylene radical,E represents an alkyl, alkenyl, cycloalkyl, formyl, alkylcarbonyl, alkenylcarbonyl or cycloalkylcarbonyl radical, a phenylcarbonyl, phenylalkylcarbonyl, phenoxyalkylcarbonyl or phenylalkyl radical or hydrogen,F represents an optionally substituted alkylene radical,p represents 1 to 5 andq represents 0 or 1.
摘要:
Dyestuffs of the formula ##SPC1##Wherein:R.sub.1 denotes cyano, halogen, alkoxy, alkylsulphonyl, arylsulphonyl, optionally mono or disubstituted carbamoyl or optionally mono- or disubstituted sulphamoyl,R.sub.2 denotes hydrogen, cyano carboxyl, halogen, alkoxy, alkyl, alkylsulphonyl or arylsulphonyl,R.sub.3 denotes hydrogen cyano, halogen or alkyl,K denotes the residue of a coupling component of the arylamine series,X denotes O, NH or N--C.sub.1 -C.sub.4 -alkyl andn denotes an integer of from 1 to 4,The XH groups being attached to one or more substituents R.sub.1, R.sub.2, R.sub.3, or to a substituent of the coupling component are added to the reaction mixture or to one of the components are suitable for the dyeing of polyurethane resins by incorporating into the resins by the formation of covalent bonds.
摘要:
Dyestuff formulations which contain a dyestuff with at least one of the groupings of the formula ##STR1## and an emulsifying polar-nonpolar compound, are outstanding suitable for dyeing synthetic fibres since they are well soluble in the dyeing bath and do not require expensive formulation process for their preparation.In the formulae, the symbols have the following meanings:G is a bridge member,A is alkylene,X is hydrogen, Y, --COY or --CONR.sub.1 R.sub.2,Y is alkyl, cycloalkyl, aralkyl or aryl,R.sub.1 is hydrogen or Y,R.sub.2 is hydrogen or alkyl andn is a number from 1 to 7, with the proviso that n is at least 2 if X is --COY.
摘要:
Valuable dyestuff formulations for dyeing polyester fibres are obtained without expensive finishing techniques by simple mixing of emulsifiers with dyestuffs of the formula ##STR1## wherein A=alkylene,B and D=a direct bond or a bridge member,V and Q=hydrogen, alkyl, alkenyl, cycloalkyl, aralkyl, aryl or acyl,X and Y=a non-ionic substituent,m and n=0 to 3 andp and r=0 to 10, with the proviso that p represents 3-10 if r=0 or 1 and D=a direct bond.The dyeing formulations are present in the liquid or dissolved form under the dyeing conditions. The use of dispersing agents, protective colloids, levelling agents and carriers is thus superfluous.
摘要:
Azo dyestuffs of the formula ##STR1## wherein R.sub.1 denotes hydrogen, C.sub.1 -C.sub.4 -alkoxy or C.sub.1 -C.sub.4 -alkoxyethoxy andX denotes acyl,are distinguished by good levelling properties and good allround fastness properties. They dye polyester fibres in a bright blue shade.
摘要:
Dyestuffs of the formula ##STR1## wherein R.sub.1 represents hydrogen, alkyl or aralkyl,R.sub.2 represents R.sub.1 or aryl,A represents C.sub.2 -C.sub.6 -alkylene,X represents R.sub.2 or acyl,n represents 1-7,m represents 1 or 2 andthe rings B and D can contain customary radicals,with the proviso that n is at least 2 if X represents acyl,give, when mixed with emulsifiers, dyestuff preparations which are in the liquid or dissolved form under dyeing conditions. The use of additional dispersing agents, protective colloids, levelling agents and carriers when dyeing polyester fibres thereby becomes superfluous.
摘要:
Cationic dyestuffs of the formula[(D--N.dbd.N--K) (--R).sub.n ].sup.m.sym. m An.crclbar.whereinD denotes the radical of a diazo component,K denotes the radical of a coupling component,m and n independently of one another denote 1 or 2,An.crclbar. denotes an anion andR denotes a radical of the general formulae--A--O --(B--O).sub.p --E--A--O--CO--F--O--(B--O).sub.p --E or--A--(O--F).sub.p.sbsb.1 --CO--O--(B--O).sub.p --EwhereinA represents optionally substituted alkylene with 2 to 4 C-atoms or a direct bond,B represents optionally substituted alkylene with 2 to 4 C atoms,E represents hydrogen or optionally substituted alkyl, alkenyl, cycloalkyl, formyl, alkylcarbonyl or alkenylcarbonyl or optionally substituted phenylcarbonyl, phenylalkylcarbonyl, phenoxyalkylcarbonyl, phenylalkyl or phenyl,F represents alkylene,p represents 1-3 andp.sub.1 represents 0 or 1,at least one of the radicals A or B represents substituted alkylenepossess good coloristic properties. The dyestuffs are characterized by good water solubility, good fastness to light and to wet processing and have affinity to fibers, as well as good migrating capacity and substantial insensitivity to thiocyanate ions.
摘要:
Exhaustion process for dyeing synthetic fiber materials with dispersions of azo dyestuffs which contain carbamate groups, in organic water-immiscible solvents. The dyestuffs are distinguished by good drawing properties and good general fastness properties.
摘要:
Azo dyestuffs of the formula ##STR1## wherein R.sub.1 denotes hydrogen, C.sub.1 -C.sub.4 -alkoxy or C.sub.1 -C.sub.4 -alkoxyethoxy andX denotes acyl,are distinguished by good levelling properties and good allround fastness properties. They dye polyester fibres in a bright blue shade.
摘要:
Formulations for dyeing polyesters and polyamides, the dyestuff component of which does not tend to crystallize in the dyebath and the effluents of which can be readily degraded biologically, are obtained in an inexpensive manner when those organophilic dyestuffs which have melting points below 140.degree. C., preferably below 100.degree. C., are used and these dyestuffs are homogeneously mixed with emulsifying polar/non-polar compounds, such as, for example, fatty sulphates and sulphonates, without expensive fine comminution processes.