公开(公告)号：US5376703A

公开(公告)日：1994-12-27

申请号：US38131

申请日：1993-03-26

Applicant: Ernst Noelken ,  Helmut Rinno ,  Hans-Ullrich Huth

Inventor： Ernst Noelken ,  Helmut Rinno ,  Hans-Ullrich Huth

IPC: C08F6/16 ,  C08F6/00 ,  C08F8/12 ,  C08L31/02 ,  C08J3/00

CPC classification number: C08L31/02 ,  C08F6/003 ,  C08F6/006

Abstract: Process for lowering the residual monomer content in aqueous plastic dispersions based on polyvinyl esters.Preparation of vinyl ester polymers or vinyl ester copolymers containing aqueous plastic dispersions having reduced contents of undesired residual vinyl ester monomers, caused by the preparation, and, optionally, acetaldehyde from corresponding starting dispersions, such as are obtainable from ethylenically unsaturated monomers by conventional polymerization or copolymerization methods, by selective alkaline saponification of the residual vinyl ester monomers saponifiable under alkaline conditions in the dispersions and preferably simultaneous removal of the acetaldehyde and unsaponified residual vinyl ester monomers from the aqueous dispersions by distillation.Use of the plastic dispersions free from residual monomer as binders in low-emission or emission-free aqueous formulations, for example for paints, coatings, plaster mortars, adhesives, paper sizing agents, nonwoven binders, textile auxiliaries, and the like, in particular for applications in indoor areas or in closed rooms.

Abstract translation: 基于聚乙烯基酯降低水性塑料分散体中残留单体含量的方法。 含有水性塑料分散体的乙烯基酯聚合物或乙烯基酯共聚物的制备，其由制备引起的含有不需要的残余乙烯基酯单体的含量降低，并且任选地由相应的起始分散体的乙醛制备，例如可通过常规聚合从烯属不饱和单体获得， 通过在碱性条件下在分散体中可皂化的残余乙烯基酯单体的选择性碱皂化，并优选通过蒸馏从水性分散体中同时除去乙醛和未皂化的残余乙烯基酯单体的共聚方法。 特别是使用不含残留单体的塑料分散体作为低排放或无排放的水性配方中的粘合剂，例如涂料，涂料，石膏砂浆，粘合剂，造纸剂，非织造粘合剂，纺织助剂等。 用于室内或室内的应用。

公开(公告)号：US5453485A

公开(公告)日：1995-09-26

申请号：US172050

申请日：1993-12-22

Applicant: Hans-Ullrich Huth ,  Helmut Rinno ,  Bernahard Momper

Inventor： Hans-Ullrich Huth ,  Helmut Rinno ,  Bernahard Momper

IPC: C08F6/00 ,  C08F218/02 ,  C08F218/04 ,  C08F6/16

CPC classification number: C08F6/006

Abstract: Preparation of aqueous plastics dispersions which contain vinyl ester polymers or vinyl ester copolymers and have reduced contents of undesirable preparation-related residual monomeric vinyl esters and, where appropriate, acetaldehyde, from corresponding starting dispersions such as are obtainable by customary polymerization or copolymerization methods from ethylenically unsaturated monomers, by selective alkaline hydrolysis of the residual monomeric vinyl esters which can be hydrolyzed under alkaline conditions and if appropriate oxidation of the acetaldehyde to acetic acid in the aqueous dispersions.

Abstract translation: 制备含有乙烯基酯聚合物或乙烯基酯共聚物的水性塑料分散体，并且从相应的起始分散体中减少不需要的制备相关的残余单体乙烯基酯的含量以及适当的乙醛，例如通过常规聚合或共聚方法从烯属 不饱和单体，通过选择碱性水解残留的单体乙烯基酯，其可在碱性条件下水解，如果乙醛在水分散体中适当氧化成乙酸。

公开(公告)号：US5319093A

公开(公告)日：1994-06-07

申请号：US039923

申请日：1993-03-29

Applicant: Hans-Ullrich Huth ,  Wolfgang Lindner

Inventor： Hans-Ullrich Huth ,  Wolfgang Lindner

IPC: C08L101/00 ,  A01N47/18 ,  C07D235/32 ,  C08F20/52 ,  C08F30/02 ,  C08F220/58 ,  C08F230/02 ,  C08F246/00 ,  C08L101/02 ,  A61K31/415

CPC classification number: C08F246/00 ,  A01N47/18

Abstract: Preparation of biocidal polymers and copolymers based on free radical-polymerizable and copolymerizable ethylenically unsaturated monomers containing monomer units composed of BCM salts of ethylenically unsaturated carboxylic acids, sulfonic acids or phosphonic acids, solutions thereof and preferably aqueous dispersions thereof. Processes for their preparation and their use as fungicidal and algicidal impregnating agents, paints and finishing agents for scumbles and dispersion paints providing protection against blue staining on wood, for synthetic resin renderings, for exposed concrete paints and for textile finishing agents.

Abstract translation: 制备基于可自由基聚合和可共聚的烯属不饱和单体的杀生物聚合物和共聚物，其含有由烯键式不饱和羧酸，磺酸或膦酸的BCM盐，其溶液和优选其水分散体组成的单体单元。 它们的制备方法及其作为杀真菌剂和杀藻剂浸渍剂，涂料和整理剂的用途，用于提供防止木材上的蓝色染色，用于合成树脂效果，用于暴露的混凝土涂料和纺织品整理剂的防污染和分散涂料。

公开(公告)号：US5102936A

公开(公告)日：1992-04-07

申请号：US600513

申请日：1990-10-19

Applicant: Hans-Ullrich Huth ,  Klaus Zimmerschied

Inventor： Hans-Ullrich Huth ,  Klaus Zimmerschied

IPC: C11D3/37 ,  A01N25/10 ,  A61K8/87 ,  A61Q19/00 ,  C05G3/00 ,  C08F16/34 ,  C08F16/38 ,  C08F20/10 ,  C08F20/34 ,  C08F20/38 ,  C08F20/52 ,  C08F22/10 ,  C08F26/10 ,  C08F28/00 ,  C08F30/02 ,  C08F210/00 ,  C08F210/02 ,  C08F216/34 ,  C08F216/36 ,  C08F218/02 ,  C08F218/04 ,  C08F220/00 ,  C08F220/04 ,  C08F220/12 ,  C08F220/36 ,  C08F220/38 ,  C08F220/44 ,  C08F220/58 ,  C08F220/60 ,  C08F222/00 ,  C08F222/02 ,  C08F222/14 ,  C08F222/16 ,  C08F226/10 ,  C08F228/02 ,  C08F230/02 ,  C08F246/00 ,  C08G18/81 ,  C09D5/00 ,  C09D5/02 ,  C09D7/00 ,  C09D7/02 ,  C09K3/00 ,  D06M15/21 ,  D06P1/52 ,  D06P1/607

CPC classification number: A61K8/87 ,  A61Q19/00 ,  C08F220/36 ,  C08F220/60 ,  C08F246/00 ,  C09D7/002 ,  D06P1/5285 ,  D06P1/607 ,  C08L75/04

Abstract: Copolymers based on ethylenically unsaturated monomers and containing urethane groups, processes for their preparation and their use.Copolymers prepared by free-radical-initiated copolymerization of ethylenically unsaturated copolymerizable monomers, in which the copolymers are preferably synthesized froma) 25 to 85% by weight of ethylenically unsaturated hydrophobic monomers, andb) 1 to 50% by weight of ethylenically unsaturated monomers capable of salt formation, andc) 0.1 to 30% by weight of surface-active urethane derivatives containing ethylenically unsaturated carboxyl or carbamido radicals, andd) 0 to 10% by weight of other ethylenically unsaturated monomers different from a) to c) and containing functional radicals, ande) 0 to 5% by weight of ethylenically unsaturated carbonyl compounds, andf) 0 to 5% by weight of ethylenically polyunsaturated or polyfunctional monomers capable of crosslinking, andg) 0 to 5% by weight of molecular weight regulators, and, if aqueous dispersions or the copolymers isolated therefrom are present, these furthermore containh) 0.1 to 10% by weight, relative to the total amount of all monomer units in the copolymer, of emulsifiers and/or protective colloids, and, if desired, the copolymers are partially or completely neutralized and converted into water-soluble or colloid-water-dispersible copolymer salts and, if desired, are obtained in solid form.Use of the products as viscosity-increasing and rheology-modifying thickener substances in aqueous systems.

Abstract translation: 基于烯属不饱和单体并含有氨基甲酸酯基团的共聚物，其制备方法及其应用。 通过烯键式不饱和可共聚单体的自由基引发共聚制备的共聚物，其中共聚物优选由a）25至85重量％的烯属不饱和疏水单体合成，和b）1至50重量％的烯属不饱和单体 能够形成盐，和c）0.1-30重量％的含有烯属不饱和羧基或氨基甲酰基的表面活性氨基甲酸酯衍生物，和d）0-10重量％的不同于a）至c）的其它烯属不饱和单体和 和e）0-5重量％的烯键式不饱和羰基化合物，和f）0-5重量％的能够交联的烯属多不饱和或多官能单体，和g）0-5重量％的分子量 并且如果存在水分散体或从其中分离出的共聚物，则这些还包含h）相对于总Amo为0.1至10重量％ 共聚物中的所有单体单元，乳化剂和/或保护胶体的共聚物，以及如果需要，共聚物被部分或完全中和并转化成水溶性或胶体 - 水分散性共聚物盐，并且如果需要，获得 以固体形式。 在水系统中使用该产品作为粘度增加和流变改性增稠剂物质。

公开(公告)号：US5079356A

公开(公告)日：1992-01-07

申请号：US547793

申请日：1990-07-02

Applicant: Hans-Ullrich Huth

Inventor： Hans-Ullrich Huth

IPC: C07D295/20 ,  C07C275/10 ,  C07C275/28 ,  C07D211/58 ,  C07D295/215 ,  C08F20/34 ,  C08F20/36

CPC classification number: C07D295/215 ,  C07C275/10 ,  C07C275/28 ,  C07D211/58 ,  C07C2101/14

Abstract: Urea derivatives with .alpha.,.beta.-ethylenically unsaturated carboxyl or carboxamide radicals, produced by reaction of ethylenically unsaturated isocyanates with ammonia or amines or by reaction of ethylenically unsaturated amines with isocyanates in the absence of water, optionally in bulk, it being possible to carry out the reaction for improved reaction control advantageously in inert organic solvents or also in so-called reactive diluents, i.e. copolymerizable ethylenically unsaturated monomeric compounds which remain inert under the reaction conditions, such as for example vinyl esters, (meth)acrylates, vinyl aromatics.The urea derivatives produced according to the invention have in their monomeric form slight to moderate or in some cases good solubility in water and/or in organic solvents. They are polymerizable or copolymerizable via their .alpha., .beta.-ethylenically unsaturated carboxyl or carboxamide groups and can be multiferiously used by free-radical initiated polymerization or copolymerization for the production of polymers or copolymers.

Abstract translation: 通过烯键式不饱和异氰酸酯与氨或胺反应产生的具有α，β-烯键式不饱和羧基或羧酰胺基团的脲衍生物，或通过烯键式不饱和胺与异氰酸酯在不存在水的情况下任选地大量反应，可以进行 有利地在惰性有机溶剂或所谓的反应性稀释剂即可在反应条件下保持惰性的可共聚的烯键式不饱和单体化合物，例如乙烯基酯，（甲基）丙烯酸酯，乙烯基芳族化合物的改进反应控制的反应。 根据本发明生产的脲衍生物在其单体形式中具有轻微至中等或在某些情况下在水和/或有机溶剂中具有良好的溶解性。 它们可以通过它们的α，β-烯属不饱和羧基或羧酰胺基团聚合或共聚，并且可以通过自由基引发的聚合或共聚来生产聚合物或共聚物而被多重使用。

公开(公告)号：US5049383A

公开(公告)日：1991-09-17

申请号：US458966

申请日：1989-12-29

Applicant: Hans-Ullrich Huth ,  Helmut Braun ,  Franz Konig

Inventor： Hans-Ullrich Huth ,  Helmut Braun ,  Franz Konig

IPC: B27K5/00 ,  A01N25/04 ,  A01N33/12 ,  B27K3/15 ,  B27K3/50 ,  C08L101/00 ,  C09D5/14

CPC classification number: A01N25/10 ,  A01N25/04 ,  C08L97/02 ,  C09D131/04 ,  C09D133/066 ,  C09D5/025 ,  C09D5/14 ,  B27K3/005 ,  B27K3/15 ,  C08K5/16 ,  C08K5/23 ,  C08L33/04 ,  Y10S514/937

Abstract: Use of fine-particled biocidal aqueous cationic dispersions of polymers as biocidal treatment agents for substrates at risk from microbes, preferably for fungicidal, bactericidal and/or algicidal treatments. The dispersions of polymers used are biocidal cationic dispersions of polymers which can be obtained from suitable monomers by emulsion polymerization and which contain biocidal cationically surfactant quaternary organic ammonium compounds, preferably tetra-substituted ammonium compounds of the formula (I) and/or alkyl- or alkenylpyridinium compounds of the formula (II), in particular in an amount of 0.1 to 20% by weight, based on the disperse polymer. The average particle diameter of the polymer particles in the biocidal cationic dispersions of polymers is preferably 0.02 to 0.5 .mu.m at a cationic activity of 1.5 to 600 .mu.mol per g of solid, measured at pH 7, and the solids content of the dispersions is preferably 3 to 40% by weight. The biocidal cationic dispersions are preferably used as treatment agents for the preservation of wood, for emulsion paint films and for polymer plasters or synthetic resin plasters, it being possible for the biocidal treatments which can be achieved to display surprising long-term biological actions.

Abstract translation: 使用细颗粒的杀生物剂水性阳离子分散体作为生物杀伤处理剂，用于处理微生物危险的基质，优选用于杀真菌，杀菌和/或杀藻处理。 所使用的聚合物的分散体是聚合物的杀生物阳离子分散体，其可以通过乳液聚合由合适的单体获得并且含有杀生物阳离子表面活性剂季有机铵化合物，优选式（I）的四取代铵化合物和/或烷基 - 或 基于分散聚合物，式（II）的烯基吡啶鎓化合物，特别是0.1至20重量％的量。 聚合物的杀生物阳离子分散体中的聚合物颗粒的平均粒径优选为0.02〜0.5μm，阳离子活性为1.5〜600μmol/ g，在pH7下测定，分散体的固体成分为 优选为3〜40重量％。 杀生物阳离子分散体优选用作保存木材，乳液漆膜和聚合物膏药或合成树脂膏剂的处理剂，可以实现可以实现令人惊讶的长期生物作用的杀生物处理。

公开(公告)号：US06960627B2

公开(公告)日：2005-11-01

申请号：US10486937

申请日：2002-08-16

Applicant: Hans-Ullrich Huth ,  Heinz Jörg Rath

Inventor： Hans-Ullrich Huth ,  Heinz Jörg Rath

IPC: C08F8/00 ,  C08F26/04

CPC classification number: C08F8/14 ,  C08F2810/30 ,  C08F8/46 ,  C08F16/06

Abstract: The invention relates to a partially cross-linked polyvinyl alcohol, obtained by reacting a polyvinyl alcohol with a polycarboxylic acid, in particular a hydroxypolycarboxylic acid. The partially cross-linked polyvinyl alcohol can be used to produce foils, which have a good water-solubility or water-swelling capacity. Due to this property, such foils can be used as packing material for detergents, cosmetics and the like. According to the invention, the packing dissolves in water, releases its contents or is suitable for releasing (permeation) chemical compounds or agents.

Abstract translation: 本发明涉及通过使聚乙烯醇与多元羧酸，特别是羟基多羧酸反应获得的部分交联的聚乙烯醇。 部分交联的聚乙烯醇可以用于生产具有良好的水溶性或水溶胀能力的箔。 由于这种性质，这种箔可以用作洗涤剂，化妆品等的包装材料。 根据本发明，包装溶解在水中，释放其内容物或适于释放（渗透）化合物或试剂。

公开(公告)号：US5089570A

公开(公告)日：1992-02-18

申请号：US412845

申请日：1989-09-26

Applicant: Karl J. Rauterkus ,  Matthias Kroggel ,  Hans-Ullrich Huth

Inventor： Karl J. Rauterkus ,  Matthias Kroggel ,  Hans-Ullrich Huth

IPC: C04B26/04 ,  C04B41/48 ,  C08F2/16 ,  C08F2/18 ,  C08F2/20 ,  C08F2/22 ,  C08F2/24 ,  C08F2/30 ,  C08F290/14 ,  C08G18/63 ,  D21H19/24

CPC classification number: C04B41/009 ,  C04B26/04 ,  C04B41/48 ,  C08F2/16 ,  C08F290/147 ,  D21H19/24

Abstract: Dispersion polymers of ethylenically unsaturated monomers which are prepared in the presence of protective colloids and if appropriate emulsifiers by polymerization in an aqueous medium and are present in aqueous dispersion form or in finely dispersed dry powder form. They contain, as protective colloids, water-soluble graft polymers containing vinyl alcohol units on a polyurethane grafting base, the polyurethane grafting bases containing at least 2 urethane groups in the molecule prepared by reacting diisocyanates and diols, and polymer radicals of units of carboxylic acid vinyl esters having 3 to 20 carbon atoms and/or hydrolysis products thereof and if appropriate units of other ethylenically unsaturated monomers and/or hydrolysis products thereof being grafted onto the polyurethane grafting bases. The amount of vinyl alcohol units in the water-soluble graft polymers is at least 20% by weight and the degree of hydrolysis of the monomer units originally grafted onto the polyurethane grafting bases is at least 50 mol%.The organic dispersion polymers are useful as a coating composition, as binders for building materials and as a starting material for the preparation of molding compositions, adhesives, binders, impregnating agents and paints.

Abstract translation: 烯属不饱和单体的分散聚合物，其在保护胶体存在下制备，如果合适的乳化剂通过聚合在水性介质中并以水分散体形式存在或以细分散的干粉形式存在。 它们作为保护胶体含有在聚氨酯接枝基体上含有乙烯醇单元的水溶性接枝聚合物，在通过二异氰酸酯和二醇反应制备的分子中含有至少2个氨基甲酸酯基团的聚氨酯接枝基团和羧酸单元的聚合物基团 具有3至20个碳原子的乙烯基酯和/或其水解产物，并且如果合适的其它烯属不饱和单体和/或其水解产物的单元被接枝到聚氨酯接枝基材上。 水溶性接枝聚合物中的乙烯醇单元的量为至少20重量％，原始接枝到聚氨酯接枝基材上的单体单元的水解度为至少50摩尔％。 有机分散聚合物可用作涂料组合物，作为建筑材料的粘合剂和用于制备模塑组合物，粘合剂，粘合剂，浸渍剂和涂料的起始材料。

公开(公告)号：US4871594A

公开(公告)日：1989-10-03

申请号：US177680

申请日：1988-04-05

Applicant: Erhard Bister ,  Hans-Ullrich Huth ,  Werner Stelzel

Inventor： Erhard Bister ,  Hans-Ullrich Huth ,  Werner Stelzel

IPC: B05D7/00 ,  B05D7/24 ,  B27K3/15 ,  C04B41/48 ,  C08F2/00 ,  C09D5/00 ,  C09D123/04 ,  C09D125/00 ,  C09D127/06 ,  C09D133/14 ,  C09D135/00 ,  C09D139/06 ,  C09D143/02

CPC classification number: C04B41/4857 ,  C08L97/02 ,  B27K3/15 ,  C08L27/06 ,  C08L33/04 ,  C08L39/06 ,  Y10T428/249994 ,  Y10T428/4935 ,  Y10T428/662

Abstract: Use of finely divided aqueous cationic dispersions of synthetic resins obtainable by emulsion polymerization from suitable monomers and which contain cationic dispersion polymers, as impregnants and primers for consolidating and priming of porous absorbent substrates, preferably inorganic substrates such as, for example, masonry, concrete, plaster surfaces, gypsum surfaces, bricks or wood, by treating these substrates with the aqueous cationic dispersions whose polymer particles have mean particle diameters of 0.02 to 0.2 .mu.m.Aqueous cationic dispersions of synthetic resins exhibit a superior penetrating and permeating power, in particular on smooth plaster surfaces and smooth gypsum surfaces, compared with aqueous anionic or non-ionic dispersions of synthetic resins. Moreover they have no tendency to foam formation and can, in contrast to aqueous anionic or non-ionic dispersions of synthetic resins, exhibit a sealing action against staining, water-soluble substances, such as tarry products (tobacco smoke), resins, wood constituents (tanning) and dyes, which is of particular advantage for example in the building trade in the renovation of old buildings.

Abstract translation: 使用可由合适的单体通过乳液聚合获得并且含有阳离子分散体聚合物的合成树脂的细碎水性阳离子分散体，作为用于固化和引发多孔吸收剂基材的浸渍剂和底漆，优选无机基材例如砖石，混凝土， 石膏表面，石膏表面，砖或木材，通过用聚合物颗粒的平均粒径为0.02至0.2μm的阳离子水溶液处理这些底物。 与合成树脂的水性阴离子或非离子分散体相比，合成树脂的水性阳离子分散体表现出优异的渗透力和渗透力，特别是在平滑的石膏表面和平滑的石膏表面上。 此外，它们不具有泡沫形成的倾向，并且与合成树脂的水性阴离子或非离子分散体相反，可以显示针对染色的密封作用，水溶性物质，例如焦油产品（烟草烟雾），树脂，木材成分 （鞣制）和染料，这在旧建筑的翻新建筑行业尤为有利。

公开(公告)号：US5256731A

公开(公告)日：1993-10-26

申请号：US661053

申请日：1991-02-25

Applicant: Hans-Ullrich Huth ,  Karl-Hans Angelmayer

Inventor： Hans-Ullrich Huth ,  Karl-Hans Angelmayer

IPC: C08F26/02 ,  C04B24/26 ,  C04B26/08 ,  C08F26/00 ,  C08F212/14 ,  C08F220/36 ,  C08F220/60 ,  C08F290/00 ,  C08F299/06 ,  C09D7/00 ,  C14C9/00 ,  D21H17/34 ,  D21H19/20 ,  C08L35/02 ,  C08F120/22

CPC classification number: C04B26/08 ,  C04B24/2682 ,  C08F212/14 ,  C08F220/36 ,  C08F220/60 ,  C09D7/002 ,  C14C9/00 ,  D21H17/34 ,  D21H19/20 ,  C08L57/08

Abstract: Polymers based on ethylenically unsaturated monomers contain at least 0.1% by weight of monomer units comprising specific ethylenically unsaturated, fluorine-containing and polymerization-capable or copolymerization-capable urethane derivatives (see formula I).The process for the preparation of the polymers or copolymers from the monomers from which they are built up by free-radical initiated polymerization or copolymerization, preferably by a method of emulsion polymerization.The use of the polymers as a starting material for the production of films, sheets, fibers, adhesives, paints, compression-molding compositions and moldings, as a thickener in aqueous preparations, as an impregnant, binder or coating agent for various industrial or chemotechnological areas of application.

Abstract translation: 基于烯属不饱和单体的聚合物含有至少0.1重量％的包含特定的烯键式不饱和，含氟和聚合反应或可共聚的氨基甲酸酯衍生物的单体单元（参见式I）。 从通过自由基引发聚合或共聚合成的单体制备聚合物或共聚物的方法，优选通过乳液聚合方法制备聚合物或共聚物。 使用聚合物作为生产薄膜，片材，纤维，粘合剂，油漆，压缩成型组合物和模制品的起始材料，作为水性制剂中的增稠剂，作为浸渍剂，粘合剂或用于各种工业或化学技术的涂料 应用领域。