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1.发明授权Attrition resistant zeolitic layered catalyst composition and aromatics alkylation process for using the composition 有权耐磨沸石层状催化剂组合物和芳烃烷基化方法使用该组合物公开(公告)号：US06376730B1
公开(公告)日：2002-04-23
申请号：US09603769
申请日：2000-06-26
IPC分类号： C07C266
CPC分类号： B01J23/626 , B01J23/40 , B01J29/06 , B01J29/7007 , B01J37/0219 , B01J37/0242 , B01J37/0246 , Y10T428/2991 , Y10T428/2993
摘要： A layered catalyst composition is disclosed where the composition is prepared by bonding an outer layer comprising a bound zeolite (e.g. zeolite beta) to an inner core material (e.g. cordierite). The use of an organic bonding agent in the catalyst preparation procedure provides a composition that is sufficiently resistant to mechanical attrition to be used commercially in aromatic alkylation processes (e.g. benzene alkylation to ethylbenzene). Advantages associated with the use of layered compositions include a significant reduction in the amount of zeolite used for a given reactor loading and improved selectivity to desired alkylated aromatic products. Further benefits are realized when the layered composition is formed into shapes having a sufficiently high void volume to reduce pressure drop across the alkylation catalyst bed. This is especially relevant for operation involving high recycle rates and consequently low alkylating agent concentrations in the reaction zone. Such conditions are known to promote reduced byproduct formation.
摘要翻译： 公开了一种分层催化剂组合物，其中通过将包含结合的沸石（例如β沸石）的外层粘合到内芯材料（例如堇青石）来制备组合物。 在催化剂制备方法中使用有机粘合剂提供了足够耐机械磨损的组合物，其可以在芳族烷基化方法（例如苯烷基化至乙苯）中商业使用。 与使用分层组合物相关的优点包括用于给定反应器负载的沸石的量的显着减少和对所需烷基化芳族产物的改进的选择性。 当层状组合物形成为具有足够高的空隙体积的形状以减少跨越烷基化催化剂床的压降时，可实现进一步的益处。 这对于涉及高回收率和因此反应区中低烷基化剂浓度的操作特别有用。 已知这种条件促进副产物形成。
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2.发明授权Process for preparing attrition resistant zeolitic layered catalyst composition 有权制备耐磨沸石层状催化剂组合物的方法公开(公告)号：US06710003B2
公开(公告)日：2004-03-23
申请号：US10022024
申请日：2001-12-13
IPC分类号： B01J2904
CPC分类号： B01J23/626 , B01J23/40 , B01J29/06 , B01J29/7007 , B01J37/0219 , B01J37/0242 , B01J37/0246 , Y10T428/2991 , Y10T428/2993
摘要： A layered catalyst composition is disclosed where the composition is prepared by bonding an outer layer comprising a bound zeolite (e.g. zeolite beta) to an inner core material (e.g. cordierite). The use of an organic bonding agent in the catalyst preparation procedure provides a composition that is sufficiently resistant to mechanical attrition to be used commercially in aromatic alkylation processes (e.g. benzene alkylation to ethylbenzene). Advantages associated with the use of layered compositions include a significant reduction in the amount of zeolite used for a given reactor loading and improved selectivity to desired alkylated aromatic products. Further benefits are realized when the layered composition is formed into shapes having a sufficiently high void volume to reduce pressure drop across the alkylation catalyst bed. This is especially relevant for operation involving high recycle rates and consequently low alkylating agent concentrations in the reaction zone. Such conditions are known to promote reduced byproduct formation.
摘要翻译： 公开了一种分层催化剂组合物，其中通过将包含结合的沸石（例如β沸石）的外层粘合到内芯材料（例如堇青石）来制备组合物。 在催化剂制备方法中使用有机粘合剂提供了足够耐机械磨损的组合物，其可以在芳族烷基化方法（例如苯烷基化至乙苯）中商业使用。 与使用分层组合物相关的优点包括用于给定反应器负载的沸石的量的显着减少和对所需烷基化芳族产物的改进的选择性。 当层状组合物形成为具有足够高的空隙体积的形状以减少跨越烷基化催化剂床的压降时，可实现进一步的益处。 这对于涉及高回收率和因此反应区中低烷基化剂浓度的操作特别有用。 已知这种条件促进副产物形成。
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公开(公告)号：US07622622B1
公开(公告)日：2009-11-24
申请号：US10872615
申请日：2004-06-21
申请人： Guy B. Woodle , Robert J. Schmidt , Deng-Yang Jan , James A. Johnson , Elena Z. Maurukas , Raelynn M. Miller
发明人： Guy B. Woodle , Robert J. Schmidt , Deng-Yang Jan , James A. Johnson , Elena Z. Maurukas , Raelynn M. Miller
IPC分类号： C07C2/66
CPC分类号： C07C2/66 , C07C2521/04 , C07C2521/08 , C07C2529/40 , C07C2529/70 , C07C15/073 , C07C15/085
摘要： Disclosed is a process and apparatus for alkylating light olefin with benzene at near but less than full conversion of the olefin. We have found that stopping below full conversion of the olefin maximizes yield of monoalkylbenzene.
摘要翻译： 公开了一种使烯烃与烯烃烷基化近似但小于完全转化的方法和装置。 我们已经发现，在烯烃完全转化之前停止使单烷基苯的产率最大化。
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公开(公告)号：US20080171902A1
公开(公告)日：2008-07-17
申请号：US11622941
申请日：2007-01-12
申请人： Deng-Yang Jan , Robert J. Schmidt , Guy B. Woodle , Mathias P. Koljack , Elena Z. Maurukas , Thomas M. Reynolds , Christopher J. Garrett
发明人： Deng-Yang Jan , Robert J. Schmidt , Guy B. Woodle , Mathias P. Koljack , Elena Z. Maurukas , Thomas M. Reynolds , Christopher J. Garrett
IPC分类号： C07C5/22
CPC分类号： C07C6/126 , B01J29/084 , B01J29/90 , B01J35/002 , B01J37/0009 , B01J2229/22 , B01J2229/36 , B01J2229/37 , B01J2229/42 , C01B39/026 , C07C2529/08 , Y02P20/52 , Y02P20/584 , C07C15/085 , C07C15/073
摘要： A process for converting polyalkylaromatics to monoalkylaromatics, particulary cumene, in the presence of a modified Y-85 zeolite is disclosed. The process attains greater selectivity, reduced formation of undesired byproducts, and increased activity.
摘要翻译： 公开了在改性Y-85沸石存在下将聚烷基芳烃转化为单烷基芳族化合物特别是枯烯的方法。 该方法获得更大的选择性，减少不期望的副产物的形成和增加的活性。
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5.发明申请AROMATIC ALKYLATION PROCESS USING UZM-5, UZM-5P AND UZM-6 ZEOLITES 审中-公开使用UZM-5，UZM-5P和UZM-6沸石的芳族烷基化方法公开(公告)号：US20120142987A1
公开(公告)日：2012-06-07
申请号：US13330014
申请日：2011-12-19
IPC分类号： C07C15/04
CPC分类号： C07C2/66 , B01J29/70 , B01J35/002 , B01J35/1019 , B01J35/1038 , B01J37/08 , B01J37/30 , B01J2229/42 , C01B39/48 , C07C6/126 , C07C2529/70 , Y02P20/52 , C07C15/073 , C07C15/085
摘要： A process for alkylating aromatic compounds using a family of zeolites, examples of which have been designated UZM-5, UZM-5P and UZM-6, and are represented by the empirical formula: Mmn+Cgh+Rrp+Al(1-x)ExSiyOz where M is an alkali or alkaline earth metal, E is an optional framework element, C organic nitrogen containing cation template, and R is an organic cation crystallization template. The zeolites have at least two x-ray diffraction peaks, one at a d-spacing of 3.9±0.12 Å and one at a d-spacing 8.6±0.20 Å; a tetragonal unit cell; and a micropore volume ranging from about 0.10 cc/g to about 0.18 cc/g.
摘要翻译： 使用一系列沸石烷基化芳族化合物的方法，其实例被称为UZM-5，UZM-5P和UZM-6，并且由经验式：Mmn + Cgh + Rrp + Al（1-x） ExSiyOz其中M是碱金属或碱土金属，E是可选的骨架元素，C有机氮阳离子模板，R是有机阳离子结晶模板。 沸石具有至少两个x射线衍射峰，一个在d-间隔为3.9±0.12A处，一个在d-间隔为8.6±0.20处; 四方晶胞; 和微孔体积为约0.10cc / g至约0.18cc / g。
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公开(公告)号：US07268267B2
公开(公告)日：2007-09-11
申请号：US11170420
申请日：2005-06-29
IPC分类号： C07C2/66
CPC分类号： C07C2/66 , B01J29/06 , B01J29/70 , B01J29/7007 , B01J2229/42 , C07C6/126 , C07C2521/04 , C07C2529/70 , Y02P20/52 , Y02P20/584 , C07C15/073 , C07C15/085
摘要： A process for the alkylation of aromatics with olefins using a solid catalyst bed containing UZM-8 zeolite is disclosed. A polyalkylated aromatic is passed to the catalyst bed to reduce the concentration of the olefin at alkylation conditions. A portion of the effluent recovered from the catalyst bed may be recycled to the catalyst bed. Such operation can decrease the catalyst deactivation rate and the formation of diphenylalkanes. The process disclosed herein is applicable to processes for the production of a wide variety of commercially important alkylated aromatics, including ethylbenzene and cumene.
摘要翻译： 公开了使用含有UZM-8沸石的固体催化剂床用烯烃烷基化芳族化合物的方法。 将多烷基化芳族化合物通入催化剂床，以在烷基化条件下降低烯烃的浓度。 从催化剂床回收的一部分流出物可以再循环到催化剂床。 这种操作可以降低催化剂失活速率和二苯基烷烃的形成。 本文公开的方法适用于生产各种商业上重要的烷基化芳族化合物（包括乙苯和枯烯）的方法。
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公开(公告)号：US07205448B2
公开(公告)日：2007-04-17
申请号：US10740872
申请日：2003-12-19
CPC分类号： C07C7/13
摘要： At lower temperatures an acidic molecular sieve adsorbent preferentially adsorbs water and basic organic nitrogen compounds over weakly basic organic nitrogen compounds such as nitrites. Elevated temperatures improve the capacity of acidic molecular sieve adsorbents to adsorb nitrites in the presence of water.
摘要翻译： 在较低温度下，酸性分子筛吸附剂优先在弱碱性有机氮化合物如亚硝酸盐上吸附水和碱性有机氮化合物。 升高的温度提高了酸性分子筛吸附剂在水存在下吸附亚硝酸盐的能力。
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公开(公告)号：US20110144403A1
公开(公告)日：2011-06-16
申请号：US12639968
申请日：2009-12-16
IPC分类号： C07C2/66
CPC分类号： B01J29/088 , B01J29/087 , C07C2/66 , C07C2529/08 , C07C15/107
摘要： A process is disclosed using a new catalyst for use in the alkylation of benzene with a substantially linear olefin. The catalyst allows for cation exchange with a rare earth element to increase the alkylation of benzene, while reducing the amount of isomerization of the alkyl group. This is important for increasing the quality of the alkylbenzene by increasing the linearity of the alkylbenzene.
摘要翻译： 公开了一种使用用于烷基化苯和基本上线性烯烃的新催化剂的方法。 催化剂允许与稀土元素进行阳离子交换以增加苯的烷基化，同时减少烷基的异构化。 这对于通过增加烷基苯的线性来提高烷基苯的质量是重要的。
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9.发明授权公开(公告)号：US07888537B2
公开(公告)日：2011-02-15
申请号：US11959984
申请日：2007-12-19
IPC分类号： C07C37/08 , C07C27/00 , C07C45/53 , C07C1/24 , C07C407/00
CPC分类号： B01J29/40 , B01J29/06 , B01J29/082 , B01J29/7007 , B01J29/85 , B01J35/002 , B01J37/0009 , B01J37/0045 , B01J37/0221 , B01J37/0246 , B01J2229/36 , B01J2229/42 , C07C37/08 , C07C45/53 , C07C407/00 , C07C409/10 , Y02P20/52 , C07C49/08 , C07C39/04
摘要： The present invention provides a process for decomposing a cumene hydroperoxide to produce phenol and acetone. The process utilizes a solid catalyst that can be non-layered or layered. The process includes: (1) introducing a process stream containing cumene hydroperoxide into a reaction vessel; (2) contacting the process stream with catalyst particles to form a process stream; and (3) withdrawing a portion of the product stream from the reactor and recovering phenol and acetone products.
摘要翻译： 本发明提供了分解氢过氧化枯烯以产生苯酚和丙酮的方法。 该方法使用可以是非层状或分层的固体催化剂。 该方法包括：（1）将含有氢过氧化枯烯的工艺流引入反应容器中; （2）使工艺流与催化剂颗粒接触以形成工艺流; 和（3）从反应器中取出一部分产物流并回收苯酚和丙酮产物。
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10.发明授权UZM-5, UZM-5P, and UZM-6 crystalline aluminosilicate zeolites and methods for preparing the same 有权UZM-5，UZM-5P和UZM-6结晶硅铝酸盐沸石及其制备方法公开(公告)号：US08747807B2
公开(公告)日：2014-06-10
申请号：US13171890
申请日：2011-06-29
CPC分类号： B01J29/70 , C01B39/48 , C07C1/20 , C07C2/12 , C07C2/66 , C07C5/23 , C07C5/2518 , C07C5/2737 , C07C2529/70 , C10G50/00 , Y02P20/52 , C07C15/08
摘要： A method for preparing a family of zeolites, examples of which have been designated UZM-5, UZM-5P and UZM-6, and are represented by the empirical formula Mmn+Cgh+Rrp+Al(1-x)ExSiyOz The method includes forming a Charge Density Mismatch (CDM) reaction mixture comprising reactive sources of Al, Si, optionally a framework element, E, and at least one organic nitrogen containing cation template, C, in the hydroxide form. After the CDM mixture is mixed while aging, an organic cation crystallization template, R, and at least one alkali metal or alkaline earth metal, M, is added. The combined final reaction mixture is reacted with mixing to produce the zeolite, which may be used in various hydrocarbon conversion processes.
摘要翻译： 一种制备沸石族的方法，其实例被称为UZM-5，UZM-5P和UZM-6，并由经验式Mmn + Cgh + Rrp + Al（1-x）ExSiyOz表示。该方法包括 形成电荷密度不匹配（CDM）反应混合物，其包含氢氧化物形式的Al，Si，任选的骨架元素E和至少一种含有机氮的阳离子模板C的反应源。 在老化之后混合CDM混合物后，加入有机阳离子结晶模板R和至少一种碱金属或碱土金属M。 将组合的最终反应混合物与混合反应以产生可用于各种烃转化方法的沸石。
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