公开(公告)号：US08470726B2

公开(公告)日：2013-06-25

申请号：US12639973

申请日：2009-12-16

申请人： Mark G. Riley ,  Deng-Yang Jan ,  Stephen W. Sohn ,  Jaime G. Moscoso

发明人： Mark G. Riley ,  Deng-Yang Jan ,  Stephen W. Sohn ,  Jaime G. Moscoso

IPC分类号： B01J29/06

CPC分类号： B01J29/80 ,  B01J23/10 ,  B01J29/08 ,  B01J29/082 ,  B01J29/084 ,  B01J29/70 ,  B01J29/7019 ,  B01J29/7038 ,  C07C2/66 ,  C07C2529/08 ,  C07C2529/70 ,  C07C2529/78 ,  C07C15/02

摘要： A catalyst is presented for use in the production of linear alkylbenzenes. The catalyst includes two zeolites combined to improve the quality of the linear alkylbenzenes. The catalyst includes a first zeolite that is UZM-8 and a second zeolite that is a low silica to alumina ratio zeolite. The second zeolite is also cation exchanged with a rare earth elements to provide a zeolite that increases the alkylation of benzene while reducing the amount of skeletal isomerization.

摘要翻译： 呈现用于生产线性烷基苯的催化剂。 催化剂包括两种沸石结合以改善线性烷基苯的质量。 催化剂包括UZM-8的第一沸石和低二氧化硅与氧化铝比的沸石的第二沸石。 第二沸石也与稀土元素进行阳离子交换以提供增加苯的烷基化同时减少骨架异构化量的沸石。

公开(公告)号：US08247631B2

公开(公告)日：2012-08-21

申请号：US12820095

申请日：2010-06-21

申请人： Christopher P Nicholas ,  Deng-Yang Jan ,  Jaime G. Moscoso

发明人： Christopher P Nicholas ,  Deng-Yang Jan ,  Jaime G. Moscoso

IPC分类号： C07C4/06 ,  C10G11/00

CPC分类号： C07C4/06 ,  B01J29/40 ,  B01J29/50 ,  B01J29/70 ,  B01J29/80 ,  C07C2529/70 ,  C10G11/05 ,  C10G2300/1022 ,  C10G2300/1044 ,  C10G2300/1059 ,  C10G2300/107 ,  C10G2300/1088 ,  C10G2300/301 ,  C10G2400/20 ,  Y02P20/52 ,  C07C11/04 ,  C07C11/06 ,  C07C11/08

摘要： Catalytic cracking processes such as fluidized catalytic cracking, naphtha cracking, and olefin cracking are catalyzed by the UZM-35 family of crystalline aluminosilicate zeolitic compositions represented by the empirical formula: Mmn+Rr+Al(1-x)ExSiyOz where M represents a combination of potassium and sodium exchangeable cations, R is a singly charged organoammonium cation such as the dimethyldipropylammonium cation and E is a framework element such as gallium. These UZM-35 zeolitic compositions are active and selective in the catalytic cracking of hydrocarbons.

摘要翻译： 催化裂解过程如流化催化裂化，石脑油裂解和烯烃裂解由经验式：Mmn + Rr + Al（1-x）ExSiyOz表示的结晶硅铝酸盐沸石组合的UZM-35族催化，其中M表示组合 的钾和钠可交换阳离子，R是单电荷的有机铵阳离子，例如二甲基二丙基铵阳离子，E是骨架元素如镓。 这些UZM-35沸石组合物在烃的催化裂化中具有活性和选择性。

公开(公告)号：US20120142987A1

公开(公告)日：2012-06-07

申请号：US13330014

申请日：2011-12-19

申请人： Deng-Yang Jan ,  Jaime G. Moscoso ,  Raelynn M. Miller ,  Susan C. Koster ,  Julio C. Marte

发明人： Deng-Yang Jan ,  Jaime G. Moscoso ,  Raelynn M. Miller ,  Susan C. Koster ,  Julio C. Marte

IPC分类号： C07C15/04

CPC分类号： C07C2/66 ,  B01J29/70 ,  B01J35/002 ,  B01J35/1019 ,  B01J35/1038 ,  B01J37/08 ,  B01J37/30 ,  B01J2229/42 ,  C01B39/48 ,  C07C6/126 ,  C07C2529/70 ,  Y02P20/52 ,  C07C15/073 ,  C07C15/085

摘要： A process for alkylating aromatic compounds using a family of zeolites, examples of which have been designated UZM-5, UZM-5P and UZM-6, and are represented by the empirical formula: Mmn+Cgh+Rrp+Al(1-x)ExSiyOz where M is an alkali or alkaline earth metal, E is an optional framework element, C organic nitrogen containing cation template, and R is an organic cation crystallization template. The zeolites have at least two x-ray diffraction peaks, one at a d-spacing of 3.9±0.12 Å and one at a d-spacing 8.6±0.20 Å; a tetragonal unit cell; and a micropore volume ranging from about 0.10 cc/g to about 0.18 cc/g.

摘要翻译： 使用一系列沸石烷基化芳族化合物的方法，其实例被称为UZM-5，UZM-5P和UZM-6，并且由经验式：Mmn + Cgh + Rrp + Al（1-x） ExSiyOz其中M是碱金属或碱土金属，E是可选的骨架元素，C有机氮阳离子模板，R是有机阳离子结晶模板。 沸石具有至少两个x射线衍射峰，一个在d-间隔为3.9±0.12A处，一个在d-间隔为8.6±0.20处; 四方晶胞; 和微孔体积为约0.10cc / g至约0.18cc / g。

公开(公告)号：US20120003147A1

公开(公告)日：2012-01-05

申请号：US13234092

申请日：2011-09-15

申请人： Jaime G. Moscoso ,  Deng-Yang Jan

发明人： Jaime G. Moscoso ,  Deng-Yang Jan

IPC分类号： C01B39/46 ,  C01B39/48

CPC分类号： C07C2/66 ,  B01J29/40 ,  B01J29/50 ,  B01J29/70 ,  B01J29/80 ,  C07C2/58 ,  C07C5/02 ,  C07C5/22 ,  C07C5/32 ,  C07C6/123 ,  C07C6/126 ,  C07C2529/80 ,  C10G29/205 ,  C10G45/64 ,  C10G50/00 ,  C10G2300/1088 ,  C10G2400/20 ,  C10G2400/22

摘要： A new family of crystalline aluminosilicate zeolitic compositions, UZM-35 compositions, has been synthesized. These zeolitic compositions are represented by the empirical formula. Mmn+Rr+Al1-xExSiyOz where M represents a combination of potassium and sodium exchangeable cations, R is a singly charged organoammonium cation such as the dimethyldipropylammonium cation and E is a framework element such as gallium. These compositions comprise a MSE zeolite, a MFI zeolite and an ERI zeolite. The compositions are similar to MCM-68 but are characterized by unique x-ray diffraction patterns and have catalytic properties for carrying out various hydrocarbon conversion processes.

摘要翻译： 已经合成了一系列结晶硅铝酸盐沸石组合物UZM-35组合物。 这些沸石组合物由经验公式表示。 Mmn + Rr + Al1-xExSiyOz其中M表示钾和钠可交换阳离子的组合，R是单电荷的有机铵阳离子，例如二甲基二丙基铵阳离子，E是骨架元素如镓。 这些组合物包含MSE沸石，MFI沸石和ERI沸石。 组合物类似于MCM-68，但其特征在于独特的x射线衍射图，并且具有用于进行各种烃转化方法的催化性能。

公开(公告)号：US20110243838A1

公开(公告)日：2011-10-06

申请号：US12750923

申请日：2010-03-31

申请人： Jaime G. Moscoso ,  Deng-Yang Jan

发明人： Jaime G. Moscoso ,  Deng-Yang Jan

IPC分类号： C01B39/02 ,  C01B39/00

CPC分类号： C01B39/48

摘要： A new family of crystalline aluminosilicate zeolites has been synthesized. These zeolites are represented by the empirical formula. Mmn+Rr+Al(1-x)ExSiyOz where M represents a combination of potassium and sodium exchangeable cations, R is a singly charged organoammonium cation such as the propyltrimethylammonium cation and E is a framework element such as gallium. These zeolites are similar to MWW but are characterized by unique x-ray diffraction patterns and compositions and have catalytic properties for carrying out various hydrocarbon conversion processes.

摘要翻译： 已经合成了一系列结晶硅铝酸盐沸石。 这些沸石由经验公式表示。 Mmn + Rr + Al（1-x）ExSiyOz其中M表示钾和钠可交换阳离子的组合，R是单电荷的有机铵阳离子，例如丙基三甲基铵阳离子，E是骨架元素如镓。 这些沸石类似于MWW，但是其特征在于独特的x射线衍射图和组成，并且具有用于进行各种烃转化方法的催化性能。

公开(公告)号：US08022262B1

公开(公告)日：2011-09-20

申请号：US12820079

申请日：2010-06-21

申请人： Jaime G. Moscoso ,  Deng-Yang Jan

发明人： Jaime G. Moscoso ,  Deng-Yang Jan

IPC分类号： C07C6/12 ,  C07C5/22 ,  C07C2/08 ,  C10G25/00

CPC分类号： C10G50/00 ,  C07C2/66 ,  C07C6/123 ,  C07C6/126 ,  C07C2529/70 ,  C10G29/205 ,  C10G49/02

摘要： A new family of crystalline aluminosilicate zeolitic compositions, UZM-35 compositions, has been synthesized. These zeolitic compositions are represented by the empirical formula. Mmn+Rr+Al(1-x)ExSiyOz where M represents a combination of potassium and sodium exchangeable cations, R is a singly charged organoammonium cation such as the dimethyldipropylammonium cation and E is a framework element such as gallium. These compositions comprise a MSE zeolite, a MFI zeolite and an ERI zeolite. The compositions are similar to MCM-68 but are characterized by unique x-ray diffraction patterns and have catalytic properties for carrying out various hydrocarbon conversion processes.

摘要翻译： 已经合成了一系列结晶硅铝酸盐沸石组合物UZM-35组合物。 这些沸石组合物由经验公式表示。 Mmn + Rr + Al（1-x）ExSiyOz其中M表示钾和钠可交换阳离子的组合，R是单电荷的有机铵阳离子，例如二甲基二丙基铵阳离子，E是骨架元素如镓。 这些组合物包含MSE沸石，MFI沸石和ERI沸石。 组合物类似于MCM-68，但其特征在于独特的x射线衍射图，并且具有用于进行各种烃转化方法的催化性能。

公开(公告)号：US07985886B1

公开(公告)日：2011-07-26

申请号：US12751449

申请日：2010-03-31

申请人： Deng-Yang Jan ,  Jaime G. Moscoso

发明人： Deng-Yang Jan ,  Jaime G. Moscoso

IPC分类号： C07C2/66

CPC分类号： C07C2/66 ,  Y02P20/52 ,  C07C15/073 ,  C07C15/085 ,  C07C15/02

摘要： A new family of crystalline aluminosilicate zeolites has been synthesized. These zeolites are represented by the empirical formula. Mmn+Rr+Al(1-x)ExSiyOz where M represents a combination of potassium and sodium exchangeable cations, R is a singly charged organoammonium cation such as the propyltrimethylammonium cation and E is a framework element such as gallium. These zeolites are similar to MWW but are characterized by unique x-ray diffraction patterns and compositions and have catalytic properties for carrying out alkylation processes.

公开(公告)号：US07982084B1

公开(公告)日：2011-07-19

申请号：US12750939

申请日：2010-03-31

申请人： Jaime G. Moscoso ,  Deng-Yang Jan

发明人： Jaime G. Moscoso ,  Deng-Yang Jan

IPC分类号： C07C4/12 ,  C07C6/12 ,  C07C5/27 ,  C07C2/58 ,  C07C2/08 ,  C10G47/00 ,  C10G11/00 ,  C10G25/00

CPC分类号： C10G47/16 ,  C07C2/12 ,  C07C2/58 ,  C07C6/126 ,  C07C2529/70 ,  C10G11/05 ,  C10G29/205 ,  C10G47/04 ,  C10G2300/1081 ,  C10G2300/1088 ,  C10G2300/1096 ,  C10G2300/70 ,  C10G2400/02 ,  C07C9/16

摘要： A new family of crystalline aluminosilicate zeolites has been synthesized. These zeolites are represented by the empirical formula. Mmn+Rr+Al(1-x)ExSiyOz where M represents a combination of potassium and sodium exchangeable cations, R is a singly charged organoammonium cation such as the propyltrimethylammonium cation and E is a framework element such as gallium. These zeolites are similar to MWW but are characterized by unique x-ray diffraction patterns and compositions and have catalytic properties for carrying out various hydrocarbon conversion processes.

摘要翻译： 已经合成了一系列结晶硅铝酸盐沸石。 这些沸石由经验公式表示。 Mmn + Rr + Al（1-x）ExSiyOz其中M表示钾和钠可交换阳离子的组合，R是单电荷的有机铵阳离子，例如丙基三甲基铵阳离子，E是骨架元素如镓。 这些沸石类似于MWW，但是其特征在于独特的x射线衍射图和组成，并且具有用于进行各种烃转化方法的催化性能。

公开(公告)号：US07973206B1

公开(公告)日：2011-07-05

申请号：US12639971

申请日：2009-12-16

申请人： Mark G. Riley ,  Deng-Yang Jan ,  Stephen W. Sohn ,  Jaime G. Moscoso

发明人： Mark G. Riley ,  Deng-Yang Jan ,  Stephen W. Sohn ,  Jaime G. Moscoso

IPC分类号： C07C2/66

CPC分类号： B01J29/80 ,  B01J29/087 ,  B01J29/088 ,  B01J29/18 ,  B01J29/70 ,  B01J2229/42 ,  C07C2/66 ,  C07C2529/08 ,  C07C2529/80 ,  C07C15/107

摘要： A process is presented for the production of linear alkylbenzenes. The process includes contacting an aromatic compound with an olefin in the presence of a selective zeolite catalyst. The catalyst includes two zeolites combined to improve the linearity, and to produce detergent grade LAB. The two zeolites are selected to limit skeletal isomerization while producing a desired 2-phenyl content for the LAB.

摘要翻译： 介绍了生产线性烷基苯的方法。 该方法包括在选择性沸石催化剂存在下使芳族化合物与烯烃接触。 催化剂包括两种结合以提高线性的沸石，并生产洗涤剂级LAB。 选择两种沸石以限制骨架异构化，同时为LAB产生所需的2-苯基含量。

公开(公告)号：US20110034320A1

公开(公告)日：2011-02-10

申请号：US12535254

申请日：2009-08-04

申请人： Susan C. Koster ,  Jaime G. Moscoso

发明人： Susan C. Koster ,  Jaime G. Moscoso

IPC分类号： B01J29/87 ,  B01J29/04 ,  B01J29/072

CPC分类号： B01J35/002 ,  B01J29/70

摘要： This invention relates to a new family of crystalline microporous zeolite designated the UZM-29 family. These zeolites are represented by the empirical formula: Mmn+R+rAl1-xExSiyOz UZM-29 has the PHI structure type topology but is thermally stable up to a temperature of at least 350° C. The UZM-29 family of zeolite can be used in various hydrocarbon conversion processes such as, isomerization of butane.

摘要翻译： 本发明涉及一种称为UZM-29族的新型结晶微孔沸石系列。 这些沸石由经验式表示：Mmn + R + rAl1-xExSiyOz UZM-29具有PHI结构类型拓扑，但在至少350℃的温度下是热稳定的。可以使用UZM-29族沸石 在各种烃转化过程中，如丁烷的异构化。