摘要:
The invention relates to a solution containing a nitroxide radical for magnetometry by nuclear magnetic resonance. This solution is constituted by a nitroxide radical of formula: ##STR1## in which R.sup.1, R.sup.2, R.sup.3 and R.sup.4, which can be the same or different, represent an alkyl group or an alkoxy group which may be deuterated, or in which the pairs R.sup.1 -R.sup.2 and/or R.sup.3 -R.sup.4 together form an optionally deuterated cycloalkyl or polycycloalkyl group, and N represent .sup.14 N or .sup.15 N, dissolved in a solvent having an oxidizing power and an appropriate viscosity. The solvent can be constituted by a mixture of water and two compounds respectively playing the part of the oxidizing agent and viscosity modifying agent, e.g. water, ethylene glycol and NalO.sub.4, or can be solely constituted by a mixture of water and an oxidizing agent able to modify the viscosity, such as acetic acid.
摘要:
The LiMPO4 compound is synthesized by reacting a compound of general formula XMPO4, nH2O where X represents a radical selected from —NH4 and —H and M is a transition metal selected from Co, Ni and Mn, with a lithium source such as lithium nitrate, at a temperature lower than or equal to 350° C. The XMPO4, nH2O compound further exhibits a particular morphology in the form of platelets that is preserved during the reaction between the two precursors. The LiMPO4 compound thus synthesized is advantageously used as active material of an electrode for a lithium storage battery.
摘要:
The present invention relates to a method of chemically modifying a lithium-based oxide comprising at least one transition metal, which comprises, in succession: a step of bringing said oxide into contact with an aqueous solution comprising phosphate ions; a step of separating said oxide from the aqueous solution; and a step of drying said oxide. Use of the modified lithium transition metal oxide as active positive electrode material for a lithium secondary battery.
摘要:
A compound containing titanium diphosphate TiP2O7 and carbon covering at least part of the surface of the TiP2O7 particles presents properties which make it suitable for use as active material of an electrode for a lithium storage battery. A compound of this kind is prepared more particularly by mixing at least one first precursor containing the titanium element with a +4 oxidation state, a phosphorus-based second precursor and an organic precursor containing the carbon element. The mixture then undergoes heat treatment at a temperature of between 500° C. and 800° C. in an inert atmosphere.
摘要翻译:含有二磷酸钛TiP 2 O 7的化合物和覆盖TiP 2 O 7颗粒表面的至少一部分的碳的化合物具有使其适合用作锂蓄电池用电极的活性物质的性质。 通过将含有钛元素的至少一种第一前体与+4氧化态,磷系第二前体和含有碳元素的有机前体进行混合来制备这种化合物。 然后将混合物在惰性气氛中在500℃至800℃的温度下进行热处理。
摘要:
The invention relates to a two-phase positive electrode material for a lithium battery, which includes particles of a lithium-enriched lamellar oxide, the surface of which is at least partially covered by a metal oxide having formula LiyVOz, wherein 0
摘要翻译:本发明涉及一种用于锂电池的两相正极材料,其包括富含锂的层状氧化物的颗粒,其表面至少部分被具有式Li y V O z的金属氧化物覆盖,其中0
摘要:
A lamellar-type oxide, in particular used as active material of a positive electrode for a lithium battery and to a method for synthesizing such an oxide. The oxides are used as active materials for the positive electrode of a lithium battery. With such oxides, the specific capacity of a lithium battery is improved and stabilized on cycling.
摘要:
A spinel structure compound of the formula LiNi0.4Mn1.6O4-δ, wherein δ>0, has a lattice parameter of from 8.179 to 8.183 Å. The compound may be prepared by mixing carbonated precursors under stoichiometric conditions to produce a mixture, subjecting the mixture to a first heat treatment at a temperature of from 500 to 700° C., and then subjecting the mixture to one or more annealing treatments at a temperature of from 700 to 950° C., followed by cooling in a medium containing oxygen. The spinel structure compound may be used as an electrochemically active material in an electrode, for example an electrode of a battery.
摘要:
A non-volatile electrochemical memory cell formed of a stack of thin films comprising at least one first active layer, suited to releasing and accepting, in a reversible manner, at least one ion species, at least one second active layer, suited to releasing and accepting said ion species, in a reversible manner, the active layers being based on materials having different compositions and electrochemical potential profiles.
摘要:
Lithium insertion compound having the following formula (I): LiαMβM1vM2wM3xM4yM5zBγ(XO4−εZε)1 (I) M is selected from V2+, Mn2+, Fe2+, Co2+ and Ni2+; M1 is selected from Na+ and K+; M2 is selected from Mg2+, Zn2+, Cu2+, Ti2+, and Ca2+; M3 is selected from Al3+, Ti3+, Cr3+, Fe3+, Mn3+, Ga3+, and V3+; M4 is selected from Ti4+, Ge4+, Sn4+, V4+, and Zr4+; M5 is selected from V5+, Nb5+, and Ta5+; X is an element in oxidation state m, exclusively occupying a tetrahedral site and coordinated by oxygen or a halogen, which is selected from B3+, Al3+, V5+, Si4+, P5+, S6+, Ge4+ and mixtures thereof; Z is a halogen selected from F, Cl, Br and I; the coefficients α, β, v, w, x, y, z, γ and ε are all positive and satisfy the following equations: 0≦α≦2 (1); 1≦β≦2 (2); 0
摘要:
The present invention relates to a method of chemically modifying a lithium-based oxide comprising at least one transition metal, which comprises, in succession: a step of bringing said oxide into contact with an aqueous solution comprising phosphate ions; a step of separating said oxide from the aqueous solution; and a step of drying said oxide. Use of the modified lithium transition metal oxide as active positive electrode material for a lithium secondary battery.