公开(公告)号：US20140049227A1

公开(公告)日：2014-02-20

申请号：US13980132

申请日：2012-01-20

申请人： Nelly Martin ,  Frederic Le Cras

发明人： Nelly Martin ,  Frederic Le Cras

IPC分类号： H02J7/00

CPC分类号： H02J7/00 ,  H01M6/5088 ,  H01M10/0525 ,  H01M10/4285 ,  H01M10/44 ,  H01M10/446 ,  Y02P70/54

摘要： A method for determining the self-discharge current of a lithium-ion battery provided with a positive electrode, a negative electrode, and an electrolyte arranged between the positive and negative electrodes includes charging the battery until a metal lithium layer is formed between the electrolyte and the negative electrode, measuring the open-circuit voltage of the battery at two moments, and determining the self-discharge current from the variation of the voltage measured between the two moments.

摘要翻译： 一种确定设置在正极和负极之间的正极，负极和电解质的锂离子电池的自放电电流的方法包括对电池进行充电，直到在电解质和电解质之间形成金属锂层 负极，在两个时刻测量电池的开路电压，并根据两个时刻之间测量的电压变化来确定自放电电流。

公开(公告)号：US08404381B2

公开(公告)日：2013-03-26

申请号：US13307049

申请日：2011-11-30

申请人： Severine Jouanneau ,  Frederic Le Cras ,  Carole Bourbon ,  Helene Lignier

发明人： Severine Jouanneau ,  Frederic Le Cras ,  Carole Bourbon ,  Helene Lignier

IPC分类号： H01M4/13 ,  H01M4/00 ,  H01M4/58 ,  H01B1/02

CPC分类号： C01G53/54 ,  C01P2002/32 ,  C01P2002/52 ,  C01P2002/72 ,  C01P2004/61 ,  C01P2006/12 ,  C01P2006/40 ,  H01M4/131 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  H01M10/0525

摘要： A material or compound is provided having a spinel structure and corresponding to the formula LiyNi0.5Mn1.5−xIVMnxIIIAzO4−d, where: 0.02≦x≦0.35; d>0; A is selected from the group comprising Na, K, Mg, Nb, Al, Ni, Co, Zr, Cr, Fe, Cu, Ti, Zn, Si and Mo; 0.8≦y≦1.2; 0≦z≦0.1; and has a mesh parameter of between 8.174 and 8.179 Å.

摘要翻译： 提供了具有尖晶石结构并对应于Li y Ni 0.5 Mn 1.5-x IV Mn x IIa z O 4-d的材料或化合物，其中：0.02＆nlE; x＆nlE; 0.35; d> 0; A选自Na，K，Mg，Nb，Al，Ni，Co，Zr，Cr，Fe，Cu，Ti，Zn，Si和Mo; 0.8＆nlE; y＆nlE; 1.2; 0＆nlE; z＆nlE; 0.1; 并具有介于8.174与8.179之间的网格参数。

公开(公告)号：US07622224B2

公开(公告)日：2009-11-24

申请号：US10998985

申请日：2004-11-30

申请人： Severine Si Larbi Jouanneau ,  Frederic Le Cras ,  Carole Bourbon ,  Gilles Gauthier

发明人： Severine Si Larbi Jouanneau ,  Frederic Le Cras ,  Carole Bourbon ,  Gilles Gauthier

IPC分类号： H01M4/58 ,  H01M4/62 ,  H01M4/40

CPC分类号： H01M4/485 ,  H01M4/131 ,  H01M4/5825 ,  H01M4/621 ,  H01M10/052 ,  H01M10/0525 ,  H01M10/0568 ,  Y02E60/122

摘要： A lithium storage cell comprises at least a first electrode comprising an active material wherein Li+ cations can be inserted, a second electrode and an electrolyte. The active material of the first electrode comprises a linear condensed compound comprising at least two tetrahedra, respectively of AO4 and A′O4 type, bonded by a common oxygen atom. A transition metal ion M2+ with a degree of oxidation of +2 selected from the group consisting of Ni2+, Co2+, Mn2+, Fe2+ and Ti2+ is inserted in the linear condensed compound, and the ratio between the number of Li+ cations able to be inserted in the active material and the number of transition metal ions M2+ is strictly greater than 1. A and A′ are selected from the group consisting of P5+, Si4+, Al3+, S6+, Ge4+, B3+.

摘要翻译： 锂蓄电池至少包括第一电极，其包含可以插入Li +阳离子的活性材料，第二电极和电解质。 第一电极的活性材料包括线性缩合化合物，其包含分别由共同的氧原子键合的AO4和A'O4型的至少两个四面体。 将从Ni2 +，Co2 +，Mn2 +，Fe2 +和Ti2 +组成的组中选择的氧化度为+2的过渡金属离子M2 +插入线性缩合化合物中，并且能够插入的Li +阳离子数 活性物质和过渡金属离子数M2 +严格大于1.A和A'选自P5 +，Si4 +，Al3 +，S6 +，Ge4 +，B3 +。

公开(公告)号：US20090130558A1

公开(公告)日：2009-05-21

申请号：US11577910

申请日：2005-12-12

申请人： Severine Jouanneau ,  Frederic Le Cras ,  Carole Bourbon ,  Helene Lignier

发明人： Severine Jouanneau ,  Frederic Le Cras ,  Carole Bourbon ,  Helene Lignier

IPC分类号： H01M4/36 ,  H01M4/58 ,  H01M4/62 ,  H01M4/88

CPC分类号： C01G53/54 ,  C01P2002/32 ,  C01P2002/52 ,  C01P2002/72 ,  C01P2004/61 ,  C01P2006/12 ,  C01P2006/40 ,  H01M4/131 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  H01M10/0525

摘要： A material or compound is provided having a spinel structure and corresponding to the formula LiyNi0.5Mn1.5-xIVMnxIIIAzO4-d, where: 0.02≦x≦0.35; d>0; A is selected from the group comprising Na, K, Mg, Nb, Al, Ni, Co, Zr, Cr, Fe, Cu, Ti, Zn, Si and Mo; 0.8≦y≦1.2; 0≦z≦0.1; and has a mesh parameter of between 8.174 and 8.179 Å.

摘要翻译： 提供具有尖晶石结构并对应于Li y Ni 0.5 Mn 1.5-x IV Mn x Al x O 4-d的材料或化合物，其中：0.02 <= x <= 0.35; d> 0; A选自Na，K，Mg，Nb，Al，Ni，Co，Zr，Cr，Fe，Cu，Ti，Zn，Si和Mo; 0.8 <= y <= 1.2; 0 <= z <= 0.1; 并具有介于8.174与8.179之间的网格参数。

公开(公告)号：US20080272740A1

公开(公告)日：2008-11-06

申请号：US11630001

申请日：2005-06-29

申请人： Sebastien Martinet ,  Frederic Le Cras ,  Dominique Perrin ,  Djamel Mourzagh

发明人： Sebastien Martinet ,  Frederic Le Cras ,  Dominique Perrin ,  Djamel Mourzagh

IPC分类号： H02J7/00

CPC分类号： H01M4/485 ,  H01M4/505 ,  H01M4/5825 ,  H01M10/0525 ,  H01M10/44

摘要： The present invention relates to a method for charging a lithium-ion accumulator with a negative electrode at an operating potential larger than 0.5 volts relatively to the Li+/Li pair, which comprises a first charging step at a constant voltage between 2 volts and 5 volts.

摘要翻译： 本发明涉及一种对锂离子蓄电池进行充电的方法，所述锂离子蓄电池具有相对于Li + / Li对的工作电位大于0.5伏特的负极，其包括在2伏和5伏特之间的恒定电压下的第一充电步骤 。

公开(公告)号：US20080107968A1

公开(公告)日：2008-05-08

申请号：US11972263

申请日：2008-01-10

申请人： Sebastien Patoux ,  Frederic Le Cras ,  Carole Bourbon ,  Severine Jouanneau

发明人： Sebastien Patoux ,  Frederic Le Cras ,  Carole Bourbon ,  Severine Jouanneau

IPC分类号： H01M4/50 ,  H01M4/52 ,  C01G45/12 ,  C01G53/04

CPC分类号： H01M4/485 ,  C01G45/1242 ,  C01G53/54 ,  C01P2002/32 ,  C01P2002/72 ,  C01P2002/76 ,  C01P2002/77 ,  C01P2004/52 ,  C01P2004/61 ,  C01P2006/40 ,  H01M4/505 ,  H01M4/525

摘要： This material or spinel structure compound has the formula LiyNi0.5−xMn1.5+xO4−δ where: 0.9 0. Also, it has a lattice parameter of 8.167 to 8.190 Å, preferably from 8.179 to 8.183 Å.

摘要翻译： 该材料或尖晶石结构化合物具有以下分子式Li x Ni 0.5-x Mn 1.5 + x O 4-δ/ / SUB >其中：0.9 0。 此外，其具有8.167至8.190的晶格参数，优选为8.179至8.183。

公开(公告)号：US07909893B2

公开(公告)日：2011-03-22

申请号：US11631168

申请日：2005-07-21

申请人： Frederic Le Cras ,  Sebastien Martinet ,  Carole Bourbon ,  Sebastien Launois

发明人： Frederic Le Cras ,  Sebastien Martinet ,  Carole Bourbon ,  Sebastien Launois

IPC分类号： H01M4/82 ,  H01M4/58 ,  H01M4/88

CPC分类号： H01M4/131 ,  H01M4/366 ,  H01M4/5825 ,  H01M4/62 ,  H01M10/0525 ,  H01M2004/021 ,  Y10T29/49108

摘要： The invention relates to a lithium battery, comprising at least one lithium intercalation compound, made up of crystallites and obtained by a production method, comprising at least the following steps: formation of a homogeneous mixture of at least one precursor for the lithium intercalation compound with a given adjunct, chemically stable with relation to crystallites and designed to limit the growth of crystallites or crystallite precursors during the formation thereof, thermal treatment of the homogeneous mixture for the synthesis of the lithium intercalation compound in the form of crystallites and to give a composite material comprising at least two phases formed respectively by the lithium intercalation compound and the adjunct and forming of the composite material to give said electrode. The invention further relates to an electrode obtained by said method and lithium battery comprising such an electrode.

摘要翻译： 本发明涉及一种锂电池，其包含至少一种由微晶构成并通过制备方法获得的锂嵌入化合物，该锂嵌入化合物至少包括以下步骤：将至少一种锂嵌入化合物的前体的均匀混合物形成为 一种给定的助剂，与微晶相关，化学稳定，并设计成限制了微晶或微晶前体在其形成过程中的生长，用于合成锂嵌层化合物的微晶形式的均匀混合物的热处理，并得到复合材料 包含分别由锂嵌入化合物形成的至少两相的材料和复合材料的辅助和形成以产生所述电极。 本发明还涉及通过所述方法获得的电极和包含这种电极的锂电池。

公开(公告)号：US20080280207A1

公开(公告)日：2008-11-13

申请号：US12158798

申请日：2006-12-21

申请人： Sebastien Patoux ,  Frederic Le Cras

发明人： Sebastien Patoux ,  Frederic Le Cras

IPC分类号： H01M4/40 ,  C01B31/00 ,  H01B1/04 ,  D01F9/12 ,  H01M6/16 ,  H01M4/58

CPC分类号： H01M4/625 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/162 ,  C01B2202/08 ,  H01M4/134 ,  H01M4/366 ,  H01M4/386 ,  H01M10/052 ,  H01M2004/021

摘要： The invention relates to a material comprising carbon nanotubes, deposited at the surface of each of which is a substantially continuous film of nanoscale silicon particles, that can be used in negative electrodes for a lithium battery.

摘要翻译： 本发明涉及一种包含碳纳米管的材料，其沉积在每个表面上，其中的每一个是纳米级硅颗粒的基本连续的膜，其可用于锂电池的负极。

公开(公告)号：US20070245546A1

公开(公告)日：2007-10-25

申请号：US11631168

申请日：2005-07-21

申请人： Frederic Le Cras ,  Sebastien Martinet ,  Carole Bourbon ,  Sebastien Launois

发明人： Frederic Le Cras ,  Sebastien Martinet ,  Carole Bourbon ,  Sebastien Launois

IPC分类号： H01M4/04

CPC分类号： H01M4/131 ,  H01M4/366 ,  H01M4/5825 ,  H01M4/62 ,  H01M10/0525 ,  H01M2004/021 ,  Y10T29/49108

摘要： The invention relates to a lithium battery, comprising at least one lithium intercalation compound, made up of crystallites and obtained by a production method, comprising at least the following steps: formation of a homogeneous mixture of at least one precursor for the lithium intercalation compound with a given adjunct, chemically stable with relation to crystallites and designed to limit the growth of crystallites or crystallite precursors during the formation thereof, thermal treatment of the homogeneous mixture for the synthesis of the lithium intercalation compound in the form of crystallites and to give a composite material comprising at least two phases formed respectively by the lithium intercalation compound and the adjunct and forming of the composite material to give said electrode. The invention further relates to an electrode obtained by said method and lithium battery comprising such an electrode.

摘要翻译： 本发明涉及一种锂电池，其包含至少一种由微晶构成并通过制备方法获得的锂嵌入化合物，该锂嵌入化合物至少包括以下步骤：将至少一种锂嵌入化合物的前体的均匀混合物形成为 一种给定的助剂，与微晶相关，化学稳定，并设计成限制了微晶或微晶前体在其形成过程中的生长，用于合成锂嵌层化合物的微晶形式的均匀混合物的热处理，并得到复合材料 包含分别由锂嵌入化合物形成的至少两相的材料和复合材料的辅助和形成以产生所述电极。 本发明还涉及通过所述方法获得的电极和包含这种电极的锂电池。

公开(公告)号：US20050136331A1

公开(公告)日：2005-06-23

申请号：US10998985

申请日：2004-11-30

申请人： Severine Jouanneau-Si Larbi ,  Frederic Le Cras ,  Carole Bourbon ,  Gilles Gauthier

发明人： Severine Jouanneau-Si Larbi ,  Frederic Le Cras ,  Carole Bourbon ,  Gilles Gauthier

IPC分类号： H01M4/131 ,  H01M4/40 ,  H01M4/48 ,  H01M4/485 ,  H01M4/52 ,  H01M4/525 ,  H01M4/58 ,  H01M4/62 ,  H01M10/052 ,  H01M10/36

CPC分类号： H01M4/485 ,  H01M4/131 ,  H01M4/5825 ,  H01M4/621 ,  H01M10/052 ,  H01M10/0525 ,  H01M10/0568 ,  Y02E60/122

摘要： A lithium storage cell comprises at least a first electrode comprising an active material wherein Li+ cations can be inserted, a second electrode and an electrolyte. The active material of the first electrode comprises a linear condensed compound comprising at least two tetrahedra, respectively of AO4 and A′O4 type, bonded by a common oxygen atom. A transition metal ion M2+ with a degree of oxidation of +2 selected from the group consisting of Ni2+, Co2+, Mn2+, Fe2+ and Ti2+ is inserted in the linear condensed compound, and the ratio between the number of Li+ cations able to be inserted in the active material and the number of transition metal ions M2+ is strictly greater than 1. A and A′ are selected from the group consisting of P5+, Si4+, Al3+, S6+, Ge4+, B3+.

摘要翻译： 锂蓄电池包括至少第一电极，其包含可插入Li + +阳离子的活性材料，第二电极和电解质。 第一电极的活性材料包括线性缩合化合物，其包含分别由共同氧原子键合的至少两个四面体的AO 4和A 4 O 4类型。 氧化度为+2的过渡金属离子M 2+，选自Ni 2+，Co 2+， 在线性缩合化合物中插入Mn 2+，Fe 2+和Ti 2+，并且Li ，B + 3 + 。