公开(公告)号：US07622224B2

公开(公告)日：2009-11-24

申请号：US10998985

申请日：2004-11-30

申请人： Severine Si Larbi Jouanneau ,  Frederic Le Cras ,  Carole Bourbon ,  Gilles Gauthier

发明人： Severine Si Larbi Jouanneau ,  Frederic Le Cras ,  Carole Bourbon ,  Gilles Gauthier

IPC分类号： H01M4/58 ,  H01M4/62 ,  H01M4/40

CPC分类号： H01M4/485 ,  H01M4/131 ,  H01M4/5825 ,  H01M4/621 ,  H01M10/052 ,  H01M10/0525 ,  H01M10/0568 ,  Y02E60/122

摘要： A lithium storage cell comprises at least a first electrode comprising an active material wherein Li+ cations can be inserted, a second electrode and an electrolyte. The active material of the first electrode comprises a linear condensed compound comprising at least two tetrahedra, respectively of AO4 and A′O4 type, bonded by a common oxygen atom. A transition metal ion M2+ with a degree of oxidation of +2 selected from the group consisting of Ni2+, Co2+, Mn2+, Fe2+ and Ti2+ is inserted in the linear condensed compound, and the ratio between the number of Li+ cations able to be inserted in the active material and the number of transition metal ions M2+ is strictly greater than 1. A and A′ are selected from the group consisting of P5+, Si4+, Al3+, S6+, Ge4+, B3+.

摘要翻译： 锂蓄电池至少包括第一电极，其包含可以插入Li +阳离子的活性材料，第二电极和电解质。 第一电极的活性材料包括线性缩合化合物，其包含分别由共同的氧原子键合的AO4和A'O4型的至少两个四面体。 将从Ni2 +，Co2 +，Mn2 +，Fe2 +和Ti2 +组成的组中选择的氧化度为+2的过渡金属离子M2 +插入线性缩合化合物中，并且能够插入的Li +阳离子数 活性物质和过渡金属离子数M2 +严格大于1.A和A'选自P5 +，Si4 +，Al3 +，S6 +，Ge4 +，B3 +。