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1.发明授权公开(公告)号：US07529014B2
公开(公告)日：2009-05-05
申请号：US10536178
申请日：2003-12-02
CPC分类号： H01M4/131 , C01B25/26 , H01M4/1315 , H01M4/1391 , H01M4/13915 , H01M4/364 , H01M4/485 , H01M4/582 , H01M4/5825 , H01M10/0525
摘要： Lithium insertion compound having the following formula (I): LiαMβM1vM2wM3xM4yM5zBγ(XO4−εZε)1 (I) M is selected from V2+, Mn2+, Fe2+, Co2+ and Ni2+; M1 is selected from Na+ and K+; M2 is selected from Mg2+, Zn2+, Cu2+, Ti2+, and Ca2+; M3 is selected from Al3+, Ti3+, Cr3+, Fe3+, Mn3+, Ga3+, and V3+; M4 is selected from Ti4+, Ge4+, Sn4+, V4+, and Zr4+; M5 is selected from V5+, Nb5+, and Ta5+; X is an element in oxidation state m, exclusively occupying a tetrahedral site and coordinated by oxygen or a halogen, which is selected from B3+, Al3+, V5+, Si4+, P5+, S6+, Ge4+ and mixtures thereof; Z is a halogen selected from F, Cl, Br and I; the coefficients α, β, v, w, x, y, z, γ and ε are all positive and satisfy the following equations: 0≦α≦2 (1); 1≦β≦2 (2); 0
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2.发明授权Method for preparing insertion compounds of an alkali metal, active materials containing same, and devices comprising said active materials 有权制备碱金属的插入化合物的方法，含有它们的活性材料和包含所述活性材料的装置公开(公告)号：US08496902B2
公开(公告)日：2013-07-30
申请号：US10537947
申请日：2003-12-15
IPC分类号： C01B25/26
CPC分类号： C01B25/45 , C01P2004/03 , C01P2004/61 , C01P2006/40 , H01M4/13 , H01M4/131 , H01M4/136 , H01M4/1397 , H01M4/366 , H01M4/485 , H01M4/525 , H01M4/5825 , H01M10/0525
摘要： Process for the preparation of an insertion compound of an alkali metal in which the following successive stages are carried out: a) an organic complex of a transition metal or of a mixture of transition metals M in an oxidation state of greater than 2 is brought into contact with an alkali metal A in the ionic form and with an entity of formula Hb(XO4), where X is chosen from Si, S, Al, P, Ge, As or Mo and b has a value from 0 to 5, in a liquid medium in a closed chamber; the chamber is brought to a temperature T which makes possible the decomposition of the organic complex in the said liquid medium; the temperature and the pressure in the chamber are brought back to ambient temperature and atmospheric pressure and the insertion compound for an alkali metal of formula AMXO4, in which M is in the +2 oxidation state, is recovered.
摘要翻译： 制备其中进行以下连续阶段的碱金属插入化合物的方法：a）过渡金属或大于2的氧化态的过渡金属M的混合物的有机络合物被引入 与离子形式的碱金属A和式Hb（XO4）的实体接触，其中X选自Si，S，Al，P，Ge，As或Mo，b具有0至5的值，在 封闭室内的液体介质; 使室达到温度T，这使得可能在所述液体介质中分解有机络合物; 将室内的温度和压力恢复到环境温度和大气压，并回收其中M处于+2氧化态的式AMXO4的碱金属的插入化合物。
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3.发明授权Method of modifying a lithium-based oxide comprising at least one transition metal, positive electrode comprising this oxide, and lithium secondary battery 有权包含至少一种过渡金属的锂基氧化物，包含该氧化物的正极和锂二次电池的改性方法公开(公告)号：US08133462B2
公开(公告)日：2012-03-13
申请号：US11883829
申请日：2006-02-10
CPC分类号： H01M4/505 , C01G45/1221 , C01G51/44 , C01G53/44 , C01P2002/52 , C01P2004/61 , C01P2006/12 , C01P2006/40 , H01M4/525 , H01M10/0525
摘要： The present invention relates to a method of chemically modifying a lithium-based oxide comprising at least one transition metal, which comprises, in succession: a step of bringing said oxide into contact with an aqueous solution comprising phosphate ions; a step of separating said oxide from the aqueous solution; and a step of drying said oxide. Use of the modified lithium transition metal oxide as active positive electrode material for a lithium secondary battery.
摘要翻译： 本发明涉及一种化学改性包含至少一种过渡金属的锂基氧化物的方法，该方法包括：使所述氧化物与包含磷酸根离子的水溶液接触的步骤; 从水溶液中分离出氧化物的步骤; 和干燥所述氧化物的步骤。 使用改性锂过渡金属氧化物作为锂二次电池的活性正极材料。
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4.发明授权Process for preparation of a lithiated or overlithiated transition metal oxide, active positive electrode materials containing this oxide, and a battery 有权制备锂化或重叠过渡金属氧化物的方法，包含该氧化物的活性正极材料和电池公开(公告)号：US06652605B1
公开(公告)日：2003-11-25
申请号：US09445400
申请日：1999-12-07
IPC分类号： H01M600
CPC分类号： H01M4/485 , C01G23/005 , C01G31/00 , C01G45/1228 , C01G45/1235 , C01G45/1242 , C01G45/1292 , C01G51/42 , C01G53/42 , C01P2002/72 , C01P2002/76 , C01P2002/77 , C01P2006/40 , H01M4/505 , H01M10/052 , Y02T10/7011 , Y10T29/49108
摘要： This invention relates to a process for manufacturing a lithiated or overlithiated transition metal oxide comprising the following three steps, carried out successively or in a simultaneous manner: preparation of a solution of lithium alkoxide by dissolving lithium metal in an alcohol, the said alcohol being chosen among the alcohols originating from linear or ramified alkanes comprising at least three carbon atoms, the alcohols originating from unsaturated aliphatic hydrocarbides, and mixtures of them; addition of a transition metal oxide powder to the said lithium alkoxide solution to obtain a dispersion; controlled reduction of the said transition metal oxide by the said alkoxide to obtain a lithiated or overlithiated transition metal oxide with a defined Li:Metal stoichiometry; the said process also comprising the following steps: evaporation of the residual alcohol, rinsing of the powder thus obtained, drying of the powder.
摘要翻译： 本发明涉及一种用于制造锂化或重叠过渡金属氧化物的方法，包括以下三个步骤：连续或同时进行：通过将金属锂溶解在醇中制备醇锂溶液，所述醇被选择 在源自包含至少三个碳原子的直链或支链烷烃的醇中，源自不饱和脂族烃的醇，及其混合物;向所述醇锂溶液中加入过渡金属氧化物粉末以获得分散体;控制减少 所述过渡金属氧化物通过所述醇盐获得具有规定的Li:金属化学计量的锂化或重叠的过渡金属氧化物;所述方法还包括以下步骤：蒸发残余醇，冲洗由此获得的粉末，干燥 粉末。
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5.发明授权公开(公告)号：US07754384B2
公开(公告)日：2010-07-13
申请号：US11972263
申请日：2008-01-10
CPC分类号： H01M4/485 , C01G45/1242 , C01G53/54 , C01P2002/32 , C01P2002/72 , C01P2002/76 , C01P2002/77 , C01P2004/52 , C01P2004/61 , C01P2006/40 , H01M4/505 , H01M4/525
摘要： A spinel structure compound of the formula LiNi0.4Mn1.6O4-δ, wherein δ>0, has a lattice parameter of from 8.179 to 8.183 Å. The compound may be prepared by mixing carbonated precursors under stoichiometric conditions to produce a mixture, subjecting the mixture to a first heat treatment at a temperature of from 500 to 700° C., and then subjecting the mixture to one or more annealing treatments at a temperature of from 700 to 950° C., followed by cooling in a medium containing oxygen. The spinel structure compound may be used as an electrochemically active material in an electrode, for example an electrode of a battery.
摘要翻译： 式LiNi0.4Mn1.6O4-δ的尖晶石结构化合物，其中δ> 0具有8.179至8.183的晶格参数。 化合物可以通过在化学计量条件下混合碳酸化前体以制备混合物来制备，使混合物在500-700℃的温度下进行第一次热处理，然后在混合物中进行一次或多次退火处理 温度为700至950℃，然后在含氧的介质中冷却。 尖晶石结构化合物可以用作电极中的电化学活性材料，例如电池的电极。
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公开(公告)号：US08218351B2
公开(公告)日：2012-07-10
申请号：US12393255
申请日：2009-02-26
IPC分类号： G11C13/00
CPC分类号： G11C13/02 , G11C2213/13 , G11C2213/55
摘要： A non-volatile electrochemical memory cell formed of a stack of thin films comprising at least one first active layer, suited to releasing and accepting, in a reversible manner, at least one ion species, at least one second active layer, suited to releasing and accepting said ion species, in a reversible manner, the active layers being based on materials having different compositions and electrochemical potential profiles.
摘要翻译： 一种非易失性电化学存储单元，由一叠薄膜组成，包括至少一个第一活性层，其适于以可逆方式释放和接受至少一种离子种类，至少一种第二活性层，适于释放和 以可逆的方式接受所述离子物质，所述活性层基于具有不同组成和电化学电位分布的材料。
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7.发明授权Titanium and dense lithium mixed oxide powder compound, method for producing said compound and compound-containing electrode 有权钛和致密锂复合氧化物粉末化合物，所述化合物和含化合物的电极的制备方法公开(公告)号：US07682596B2
公开(公告)日：2010-03-23
申请号：US11660163
申请日：2005-08-08
CPC分类号： H01M4/131 , C01G23/002 , C01G23/003 , C01P2002/32 , C01P2004/03 , C01P2004/50 , C01P2004/53 , C01P2004/61 , C01P2004/62 , C01P2006/11 , C01P2006/12 , H01M4/136 , H01M4/485 , H01M4/505 , H01M4/525 , H01M4/5825 , H01M10/052 , H01M2004/021 , Y02E60/122
摘要： A powdery compound selected from the group consisting of Li4Ti5O12 and its derivatives selected from the group consisting of Li4−xMxTi5O12 and Li4Ti5−yNyO12 (x and y between 0 and 0.2, M and N selected from the group consisting of Na, K, Mg, Nb, Al, Ni , Co, Zr, Cr, Mn, Fe, Cu, Zn, Si and Mo), used as active material of an electrode for a lithium storage battery, consists of unitary particles having a diameter not greater than 1 μm and 10-50% volume agglomerated particles having a diameter not greater than 100 μm wherein the agglomerated particles formed by agglomeration of said unitary particles. The method for producing such a compound preferably consists in grinding the synthesized oxide for a duration comprised between 24 hours and 48 hours in a planetary mill and in then performing thermal treatment at a temperature comprised between 450° C. and 600° C.
摘要翻译： 选自Li4Ti5O12及其衍生物的锂化合物的粉末化合物，其选自Li4-xMxTi5O12和Li4Ti5-yNyO12（x和y在0和0.2之间，M和N选自Na，K，Mg， 用作锂蓄电池电极的活性材料的Nb，Al，Ni，Co，Zr，Cr，Mn，Fe，Cu，Zn，Si和Mo）由直径不大于1μm的单一颗粒组成 和10-50％体积的直径不大于100μm的凝聚颗粒，其中通过所述单一颗粒的聚集形成的附聚颗粒。 制造这种化合物的方法优选包括在行星式研磨机中将合成氧化物研磨24小时至48小时，然后在450℃至600℃的温度下进行热处理。
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8.发明申请Method for preparing insertion compounds of an alkali metal, active materials containing same, and device comprising said active materials 有权制备碱金属的插入化合物的方法，含有它们的活性材料和包含所述活性材料的装置公开(公告)号：US20060204848A1
公开(公告)日：2006-09-14
申请号：US10537947
申请日：2003-12-15
CPC分类号： C01B25/45 , C01P2004/03 , C01P2004/61 , C01P2006/40 , H01M4/13 , H01M4/131 , H01M4/136 , H01M4/1397 , H01M4/366 , H01M4/485 , H01M4/525 , H01M4/5825 , H01M10/0525
摘要： Process for the preparation of an insertion compound of an alkali metal in which the following successive stages are carried out: a) an organic complex of a transition metal or of a mixture of transition metals M in an oxidation state of greater than 2 is brought into contact with an alkali metal A in the ionic form and with an entity of formula Hb (XO4), where X is chosen from Si, S, Al, P, Ge, As or Mo and b has a value from 0 to 5, in a liquid medium in a closed chamber; the chamber is brought to a temperature T which makes possible the decomposition of the organic complex in the the said liquid medium; the temperature and the pressure in the chamber are brought back to ambient temperature and atmospheric pressure and the insertion compound for an alkali metal of formula AMXO4, in which M is in the +2 oxidation state, is recovered.
摘要翻译： 制备其中进行以下连续阶段的碱金属插入化合物的方法：a）过渡金属或大于2的氧化态的过渡金属M的混合物的有机络合物被引入 与离子形式的碱金属A和式H b（XO 4 S）的实体接触，其中X选自Si，S，Al，P， Ge，As或Mo和b具有0至5的值，在封闭室中的液体介质中; 使室达到使所述液体介质中的有机络合物分解成温度T; 将室内的温度和压力恢复到环境温度和大气压，并回收其中M处于+2氧化态的式AMXO 4碱金属的插入化合物 。
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9.发明授权Synthesis of a LiMPO4 compound and use as electrode material in a lithium storage battery 有权LiMPO4化合物的合成并用作锂蓄电池中的电极材料公开(公告)号：US08404305B2
公开(公告)日：2013-03-26
申请号：US12449588
申请日：2008-03-12
IPC分类号： B32B5/16
CPC分类号： H01M10/052 , C01B25/37 , C01B25/375 , C01B25/377 , C01B25/45 , H01M4/505 , H01M4/525 , Y02E60/122 , Y10T428/2982
摘要： The LiMPO4 compound is synthesized by reacting a compound of general formula XMPO4, nH2O where X represents a radical selected from —NH4 and —H and M is a transition metal selected from Co, Ni and Mn, with a lithium source such as lithium nitrate, at a temperature lower than or equal to 350° C. The XMPO4, nH2O compound further exhibits a particular morphology in the form of platelets that is preserved during the reaction between the two precursors. The LiMPO4 compound thus synthesized is advantageously used as active material of an electrode for a lithium storage battery.
摘要翻译： 通过使通式XMPO 4，nH 2 O的化合物，其中X表示选自-NH 4和-H的基团，M是选自Co，Ni和Mn的过渡金属，与锂源如硝酸锂反应合成LiMPO 4化合物， 在低于或等于350℃的温度下.XMPO 4，nH 2 O化合物进一步表现出在两种前体之间的反应期间保留的血小板形式的特定形态。 由此合成的LiMPO 4化合物有利地用作锂蓄电池用电极的活性物质。
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10.发明申请公开(公告)号：US20090026413A1
公开(公告)日：2009-01-29
申请号：US12224651
申请日：2007-03-13
申请人： Sebastien Patoux , Carole Bourbon
发明人： Sebastien Patoux , Carole Bourbon
CPC分类号： H01M4/5825 , H01M4/366 , H01M4/587 , H01M4/625 , H01M10/052 , H01M2004/021 , Y02E60/122
摘要： A compound containing titanium diphosphate TiP2O7 and carbon covering at least part of the surface of the TiP2O7 particles presents properties which make it suitable for use as active material of an electrode for a lithium storage battery. A compound of this kind is prepared more particularly by mixing at least one first precursor containing the titanium element with a +4 oxidation state, a phosphorus-based second precursor and an organic precursor containing the carbon element. The mixture then undergoes heat treatment at a temperature of between 500° C. and 800° C. in an inert atmosphere.
摘要翻译： 含有二磷酸钛TiP 2 O 7的化合物和覆盖TiP 2 O 7颗粒表面的至少一部分的碳的化合物具有使其适合用作锂蓄电池用电极的活性物质的性质。 通过将含有钛元素的至少一种第一前体与+4氧化态，磷系第二前体和含有碳元素的有机前体进行混合来制备这种化合物。 然后将混合物在惰性气氛中在500℃至800℃的温度下进行热处理。
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