公开(公告)号：US08597828B2

公开(公告)日：2013-12-03

申请号：US12194715

申请日：2008-08-20

申请人： Sébastien Martinet ,  Hélène Lignier

发明人： Sébastien Martinet ,  Hélène Lignier

IPC分类号： H01M6/18 ,  H01M4/13 ,  H01M10/26 ,  H01M6/04

CPC分类号： H01M10/26 ,  H01M4/485 ,  H01M4/5825 ,  H01M10/36 ,  H01M2300/0014 ,  H01M2300/0085

摘要： The invention relates to a lithium battery including a cell comprising: a positive electrode, a negative electrode, and an electrolyte consisting of an aqueous solution of a lithium salt, characterized in that the electrolyte has a pH of at least 14, the positive electrode has a lithium intercalation potential greater than 3.4 V, and the negative electrode has a lithium intercalation potential less than 2.2 V.

摘要翻译： 本发明涉及包括电池的锂电池，包括：正电极，负电极和由锂盐水溶液组成的电解质，其特征在于电解质的pH至少为14，正电极具有 锂插层电位大于3.4V，负极具有小于2.2V的锂嵌入电位。

公开(公告)号：US20120068129A1

公开(公告)日：2012-03-22

申请号：US13307049

申请日：2011-11-30

申请人： Séverine JOUANNEAU ,  Frédéric LE CRAS ,  Carole BOURBON ,  Hélène LIGNIER

发明人： Séverine JOUANNEAU ,  Frédéric LE CRAS ,  Carole BOURBON ,  Hélène LIGNIER

IPC分类号： H01B1/02

CPC分类号： C01G53/54 ,  C01P2002/32 ,  C01P2002/52 ,  C01P2002/72 ,  C01P2004/61 ,  C01P2006/12 ,  C01P2006/40 ,  H01M4/131 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  H01M10/0525

摘要： A material or compound is provided having a spinel structure and corresponding to the formula LiyNi0.5Mn1.5−xIVMnxIIIAzO4−d, where:0.02≦x≦0.35;d>0;A is selected from the group comprising Na, K, Mg, Nb, Al, Ni, Co, Zr, Cr, Fe, Cu, Ti, Zn, Si and Mo;0.8≦y≦1.2;0≦z≦0.1; and has a mesh parameter of between 8.174 and 8.179 Å.

摘要翻译： 提供了具有尖晶石结构并对应于Li y Ni 0.5 Mn 1.5-x IV Mn x IIa z O 4-d的材料或化合物，其中：0.02＆nlE; x＆nlE; 0.35; d> 0; A选自Na，K，Mg，Nb，Al，Ni，Co，Zr，Cr，Fe，Cu，Ti，Zn，Si和Mo; 0.8＆nlE; y＆nlE; 1.2; 0＆nlE; z＆nlE; 0.1; 并具有介于8.174与8.179之间的网格参数。

公开(公告)号：US20130247334A1

公开(公告)日：2013-09-26

申请号：US13819655

申请日：2011-08-26

申请人： Charles Huguet ,  Emmanuel Flahaut ,  Hélène Lignier

发明人： Charles Huguet ,  Emmanuel Flahaut ,  Hélène Lignier

IPC分类号： B01D9/00

CPC分类号： B01D9/00 ,  C03C17/22 ,  C03C17/225 ,  C04B41/009 ,  C04B41/52 ,  C04B41/87 ,  C04B41/89 ,  C04B2111/00879 ,  C30B11/002 ,  C30B29/06 ,  C04B35/522 ,  C04B41/4531 ,  C04B41/5059 ,  C04B41/4535 ,  C04B41/455 ,  C04B41/5035 ,  C04B41/4554 ,  C04B41/5066

摘要： The present invention relates to a crucible that can be used for solidifying a silicon ingot from molten silicon, characterized in that same is at least partially coated on the inner surface thereof with at least one layer consisting of a material produced by thermal decomposition of polysilizane(s), said layer having a shear strength greater than 1 Pa and no higher than 500 MPa, and being in the form of a stack of adjoining layers of non-contiguous tiles. The invention also relates to a method for preparing such crucibles.

摘要翻译： 本发明涉及可用于从熔融硅固化硅锭的坩埚，其特征在于，其至少部分地在其内表面上涂覆有至少一层由聚硅烷的热分解产生的材料 s），所述层具有大于1Pa且不高于500MPa的剪切强度，并且是相邻层的非连续砖的堆叠形式。 本发明还涉及制备这种坩埚的方法。

公开(公告)号：US20100297480A1

公开(公告)日：2010-11-25

申请号：US12852183

申请日：2010-08-06

申请人： Audrey MARTINENT ,  Sébastien Martinet ,  Hélène Lignier ,  Djamel Mourzagh

发明人： Audrey MARTINENT ,  Sébastien Martinet ,  Hélène Lignier ,  Djamel Mourzagh

IPC分类号： H01M10/42 ,  H01M10/26 ,  H01M6/16

CPC分类号： H01M10/4235 ,  H01M4/485 ,  H01M4/505 ,  H01M4/581 ,  H01M4/5825 ,  H01M6/168 ,  H01M10/0567

摘要： A lithium battery comprises at least a positive electrode containing a material whose lithium insertion and deinsertion potential is lower than or equal to 3.5 Volts in relation to the potential of the Li+/Li couple, a negative electrode and a non-aqueous electrolyte disposed between the positive and negative electrodes. The electrolyte comprises at least a lithium salt dissolved in an aprotic organic solvent wherein a polymerizable additive is added, chosen from carbazol and the derivatives thereof and being used to prevent the battery from operating as soon as the voltage at the terminal connections of the battery reaches a value resulting in polymerization of the additive.

摘要翻译： 锂电池至少包含含锂的插入和去绝缘电位低于或等于3.5伏的材料的正极，相对于Li + / Li族的电位，负极和非水电解质 正极和负极。 电解质至少包含溶于非质子有机溶剂中的锂盐，其中加入可聚合的添加剂，其选自咔唑及其衍生物，并且用于在电池端子连接处的电压达到时防止电池操作 导致添加剂的聚合的值。

公开(公告)号：US07682596B2

公开(公告)日：2010-03-23

申请号：US11660163

申请日：2005-08-08

申请人： Carole Bourbon ,  Séverine Jouanneau ,  Frédéric Le Cras ,  Hélène Lignier

发明人： Carole Bourbon ,  Séverine Jouanneau ,  Frédéric Le Cras ,  Hélène Lignier

IPC分类号： C01G23/00 ,  C01G57/00 ,  H01M4/48 ,  H01M4/00 ,  H01M4/02 ,  H01M4/40 ,  H01M4/58 ,  H01M4/50

CPC分类号： H01M4/131 ,  C01G23/002 ,  C01G23/003 ,  C01P2002/32 ,  C01P2004/03 ,  C01P2004/50 ,  C01P2004/53 ,  C01P2004/61 ,  C01P2004/62 ,  C01P2006/11 ,  C01P2006/12 ,  H01M4/136 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  H01M4/5825 ,  H01M10/052 ,  H01M2004/021 ,  Y02E60/122

摘要： A powdery compound selected from the group consisting of Li4Ti5O12 and its derivatives selected from the group consisting of Li4−xMxTi5O12 and Li4Ti5−yNyO12 (x and y between 0 and 0.2, M and N selected from the group consisting of Na, K, Mg, Nb, Al, Ni , Co, Zr, Cr, Mn, Fe, Cu, Zn, Si and Mo), used as active material of an electrode for a lithium storage battery, consists of unitary particles having a diameter not greater than 1 μm and 10-50% volume agglomerated particles having a diameter not greater than 100 μm wherein the agglomerated particles formed by agglomeration of said unitary particles. The method for producing such a compound preferably consists in grinding the synthesized oxide for a duration comprised between 24 hours and 48 hours in a planetary mill and in then performing thermal treatment at a temperature comprised between 450° C. and 600° C.

摘要翻译： 选自Li4Ti5O12及其衍生物的锂化合物的粉末化合物，其选自Li4-xMxTi5O12和Li4Ti5-yNyO12（x和y在0和0.2之间，M和N选自Na，K，Mg， 用作锂蓄电池电极的活性材料的Nb，Al，Ni，Co，Zr，Cr，Mn，Fe，Cu，Zn，Si和Mo）由直径不大于1μm的单一颗粒组成 和10-50％体积的直径不大于100μm的凝聚颗粒，其中通过所述单一颗粒的聚集形成的附聚颗粒。 制造这种化合物的方法优选包括在行星式研磨机中将合成氧化物研磨24小时至48小时，然后在450℃至600℃的温度下进行热处理。