Catalyst compositions for polymerizing olefins to multimodal molecular weight distribution polymer, processes for production and use of the catalyst
    1.
    发明授权
    Catalyst compositions for polymerizing olefins to multimodal molecular weight distribution polymer, processes for production and use of the catalyst 失效
    用于将烯烃聚合成多峰分子量分布聚合物的催化剂组合物,催化剂的生产和使用方法

    公开(公告)号:US06784263B2

    公开(公告)日:2004-08-31

    申请号:US10052326

    申请日:2002-01-18

    IPC分类号: C08F444

    摘要: A solid catalyst component comprises a transition metal-containing metallocene compound, a non-cyclopentadienyl transition metal compound, a magnesium compound and a polymeric material which acts as a support. The catalyst component is combined with co-catalyst organoaluminum compound or a mixture of organoaluminum compounds to provide a catalyst composition useful for olefin polymerization, e.g., to produce linear low, medium and high density polyethylenes or copolymerization of ethylene with alpha-olefins. Product polyolefin polymers have a varied range of molecular weight distributions. The catalyst composition is prepared by a process comprising combining polymer support particles, magnesium compound, transition metal-containing metallocene compound, and non-cyclopentadienyl transition metal compound to provide a solid catalyst component, and, combining the solid catalyst component with a cocatalyst compound to provide a polyolefin polymerization catalyst composition.

    摘要翻译: 固体催化剂组分包含含过渡金属的茂金属化合物,非环戊二烯基过渡金属化合物,镁化合物和作为载体的聚合物。 将催化剂组分与助催化剂有机铝化合物或有机铝化合物的混合物组合以提供可用于烯烃聚合的催化剂组合物,例如产生线性低,中和高密度聚乙烯或乙烯与α-烯烃的共聚。 产品聚烯烃聚合物具有不同范围的分子量分布。催化剂组合物通过包括将聚合物载体颗粒,镁化合物,含过渡金属的茂金属化合物和非环戊二烯基过渡金属化合物组合以提供固体催化剂组分的方法制备, 并且将固体催化剂组分与助催化剂化合物组合以提供聚烯烃聚合催化剂组合物。