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US07662894B2 Polymer supported metallocene catalyst composition for polymerizing olefins 失效
用于聚合烯烃的聚合物负载金属茂催化剂组合物

Polymer supported metallocene catalyst composition for polymerizing olefins
Abstract:
A catalyst composition for polymerizing olefins to polymers having bimodal molecular weight distribution comprises two transition metal-containing metallocene compounds, a magnesium compound, an alcohol, an aluminum containing co-catalyst and a polymeric support. The transition metal in one of the metallocene compounds is zirconium and the transition metal in the second metallocene compound is selected from the group consisting of titanium, vanadium and hafnium. Polyolefin polymers made using the catalyst composition have broad molecular weight distributions and are useful in film and blow molding applications.
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