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    Process for the preparation of linear alpha-olefins and catalyst used therein
    1.
    发明授权
    Process for the preparation of linear alpha-olefins and catalyst used therein 有权
    用于制备线性α-烯烃和其中使用的催化剂的方法

    公开(公告)号：US08653316B2

    公开(公告)日：2014-02-18

    申请号：US11990173

    申请日：2006-08-10

    申请人： Vugar O. Aliyev ,  Atieh Abu-Raqabah ,  Mohammad Zahoor

    发明人： Vugar O. Aliyev ,  Atieh Abu-Raqabah ,  Mohammad Zahoor

    IPC分类号： C07C2/22 ,  B01J31/04

    CPC分类号： B01J31/2226 ,  B01J31/04 ,  B01J31/143 ,  B01J2231/20 ,  B01J2531/48 ,  C07C2/30 ,  C07C11/02

    摘要： The present invention relates to a process for the preparation of linear low molecular weight alpha-olefins having 4 to 24 carbon atoms, comprising oligomerizing ethylene in an inert solvent in the presence of a catalyst system comprising: (i) zirconium carboxylate of the formula (R1COO)mZrCl4-m, wherein R1 is saturated or unsaturated aliphatic C1-C10 hydrocarbon or aromatic C6-C14 hydrocarbon and m fulfills 1≦m≦4, (ii) at least one aluminum compound selected from organoaluminum compounds of the formula R2nAlX3-n, wherein R2 is C1-C20 alkyl, X is chlorine, bromine or iodine, and n fulfills 1≦n≦2, and/or aluminoxanes, and (iii) at least two different additives selected from the group consisting of hydrogen, esters, ketones, ethers, amines, anhydrides, phosphines and sulfur compounds; as well as to a catalyst used therein.

    摘要翻译： 本发明涉及制备具有4至24个碳原子的线型低分子量α-烯烃的方法，包括在惰性溶剂中在催化剂体系存在下使乙烯低聚，包括：（i）式 R1COO）mZrCl4-m，其中R1是饱和或不饱和脂族C 1 -C 10烃或芳族C 6 -C 14烃，m满足1〜4，（ii）至少一种选自式R 2 n AlX 3-n的有机铝化合物的铝化合物 其中R2是C1-C20烷基，X是氯，溴或碘，n满足1≤n≤2和/或铝氧烷，和（iii）至少两种选自氢，酯， 酮，醚，胺，酸酐，膦和硫化合物; 以及其中使用的催化剂。

    Catalyst composition for polymerization of olefins and method for preparing the same
    9.
    发明授权
    Catalyst composition for polymerization of olefins and method for preparing the same 失效
    用于烯烃聚合的催化剂组合物及其制备方法

    公开(公告)号：US07001862B2

    公开(公告)日：2006-02-21

    申请号：US10470465

    申请日：2002-01-30

    申请人： Akhlaq A. Moman ,  Khalid Al-Bahily ,  Atieh Abu-Raqabah ,  John Ledford ,  Orass M. Hamed

    发明人： Akhlaq A. Moman ,  Khalid Al-Bahily ,  Atieh Abu-Raqabah ,  John Ledford ,  Orass M. Hamed

    IPC分类号： B01J31/00 ,  B01J37/00 ,  C08F4/60 ,  C08F4/02

    CPC分类号： C08F10/00 ,  C08F110/02 ,  C08F210/16 ,  C08F4/027 ,  C08F4/68 ,  C08F4/685 ,  C08F2500/18 ,  C08F210/08 ,  C08F210/14

    摘要： The present invention relates to a catalyst composition for polymerization of olefins comprising: (a) a solid catalyst pre cursor comprising at least one vanadium compound, at least one magnesium compound and a polymeric material or a solid catalyst precursor comprising at least one vanadium compound, at least one further transition metal compound and/or at least one alcohol, at least one magnesium compound and a polymeric material; and (b) a cocatalyst comprising at least one aluminum compound; and to a method for preparing a catalyst composition according to the present invention, comprising the steps of: (a) combining the components of the solid catalyst precursor; and (b) activating the catalyst precursor with aluminum compound.

    摘要翻译： 本发明涉及一种用于烯烃聚合的催化剂组合物，其包括：（a）固体催化剂前体，其包含至少一种钒化合物，至少一种镁化合物和聚合物材料或包含至少一种钒化合物的固体催化剂前体， 至少一种其它过渡金属化合物和/或至少一种醇，至少一种镁化合物和聚合物材料; 和（b）包含至少一种铝化合物的助催化剂; 以及制备根据本发明的催化剂组合物的方法，包括以下步骤：（a）将固体催化剂前体的组分混合; 和（b）用铝化合物活化催化剂前体。