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    Process for the preparation of linear alpha-olefins and catalyst used therein
    1.
    发明授权
    Process for the preparation of linear alpha-olefins and catalyst used therein 有权
    用于制备线性α-烯烃和其中使用的催化剂的方法

    公开(公告)号：US08653316B2

    公开(公告)日：2014-02-18

    申请号：US11990173

    申请日：2006-08-10

    申请人： Vugar O. Aliyev ,  Atieh Abu-Raqabah ,  Mohammad Zahoor

    发明人： Vugar O. Aliyev ,  Atieh Abu-Raqabah ,  Mohammad Zahoor

    IPC分类号： C07C2/22 ,  B01J31/04

    CPC分类号： B01J31/2226 ,  B01J31/04 ,  B01J31/143 ,  B01J2231/20 ,  B01J2531/48 ,  C07C2/30 ,  C07C11/02

    摘要： The present invention relates to a process for the preparation of linear low molecular weight alpha-olefins having 4 to 24 carbon atoms, comprising oligomerizing ethylene in an inert solvent in the presence of a catalyst system comprising: (i) zirconium carboxylate of the formula (R1COO)mZrCl4-m, wherein R1 is saturated or unsaturated aliphatic C1-C10 hydrocarbon or aromatic C6-C14 hydrocarbon and m fulfills 1≦m≦4, (ii) at least one aluminum compound selected from organoaluminum compounds of the formula R2nAlX3-n, wherein R2 is C1-C20 alkyl, X is chlorine, bromine or iodine, and n fulfills 1≦n≦2, and/or aluminoxanes, and (iii) at least two different additives selected from the group consisting of hydrogen, esters, ketones, ethers, amines, anhydrides, phosphines and sulfur compounds; as well as to a catalyst used therein.

    摘要翻译： 本发明涉及制备具有4至24个碳原子的线型低分子量α-烯烃的方法，包括在惰性溶剂中在催化剂体系存在下使乙烯低聚，包括：（i）式 R1COO）mZrCl4-m，其中R1是饱和或不饱和脂族C 1 -C 10烃或芳族C 6 -C 14烃，m满足1〜4，（ii）至少一种选自式R 2 n AlX 3-n的有机铝化合物的铝化合物 其中R2是C1-C20烷基，X是氯，溴或碘，n满足1≤n≤2和/或铝氧烷，和（iii）至少两种选自氢，酯， 酮，醚，胺，酸酐，膦和硫化合物; 以及其中使用的催化剂。

    PROCESS FOR POLYMERISATION OF ETHYLENE
    2.
    发明申请
    PROCESS FOR POLYMERISATION OF ETHYLENE 有权
    乙烯聚合方法

    公开(公告)号：US20130310245A1

    公开(公告)日：2013-11-21

    申请号：US13877558

    申请日：2011-10-04

    申请人： Vugar O. Aliyev ,  Ali Saad Headan ,  Jaiprakash Brijal Sainani

    发明人： Vugar O. Aliyev ,  Ali Saad Headan ,  Jaiprakash Brijal Sainani

    IPC分类号： C08F10/02

    CPC分类号： C08F10/02 ,  C08F110/02 ,  C08F2410/01 ,  C08F4/24 ,  C08F4/69 ,  C08F2500/07 ,  C08F2500/04 ,  C08F2500/18 ,  C08F2500/12

    摘要： The present invention is directed to a process for the production of high density polyethylene by polymerisation of ethylene in the presence of a supported chromium oxide based catalyst which is modified with an organic compound comprising oxygen and a nitrogen atom which is selected from the group consisting of saturated heterocyclic organic compounds with a five or six membered ring, amino esters and amino alcohols. Such organic compounds allow manufacturing of HDPE with increases molecular weight distribution and increased molecular weight.

    摘要翻译： 本发明涉及一种通过在负载的氧化铬基催化剂存在下聚合乙烯生产高密度聚乙烯的方法，该催化剂用包含氧和氮原子的有机化合物进行改性，该有机化合物选自： 具有五或六元环的饱和杂环有机化合物，氨基酯和氨基醇。 这样的有机化合物允许制备具有增加的分子量分布和分子量增加的HDPE。

    Process for the polymerizaion of olefins
    4.
    发明授权
    Process for the polymerizaion of olefins 有权
    烯烃聚合方法

    公开(公告)号：US07919569B2

    公开(公告)日：2011-04-05

    申请号：US11921616

    申请日：2006-05-12

    申请人： Wei Xu ,  Vugar O. Aliyev ,  Sirajudeen Mohamed ,  Atieh Abu-Raqabah

    发明人： Wei Xu ,  Vugar O. Aliyev ,  Sirajudeen Mohamed ,  Atieh Abu-Raqabah

    IPC分类号： C08F4/602 ,  C08F4/609 ,  C08F4/642 ,  C08F4/649 ,  C08F4/6592

    CPC分类号： C08F10/02 ,  C08F110/02 ,  C08F210/16 ,  Y10S526/943 ,  C08F2/002 ,  C08F210/14

    摘要： The present invention relates to a process for the polymerization of olefins, comprising the steps of introducing at least one olefin, at least one polymerization catalyst, at least one cocatalyst and at least one cocatalyst aid, and optionally a scavenger, into a polymerization reactor, and polymerizing the olefin, wherein the cocatalyst aid is a reaction product prepared separately prior to the introduction into the reactor by reacting at least one metal alkyl compound of group IIA or IIIA of the periodic system of elements and at least one compound (A) of the formula RmXR′n, wherein R is a branched, straight, or cyclic, substituted or unsubstituted, hydrocarbon group having 1 to 30 carbon atoms, R′ is hydrogen or any functional group with at least one active hydrogen, X is at least one heteroatom selected from the group of O, N, P or S or a combination thereof, and wherein n and m are each at least 1 and are such that the formula has no net charge.

    摘要翻译： 本发明涉及一种烯烃聚合方法，包括以下步骤：将至少一种烯烃，至少一种聚合催化剂，至少一种助催化剂和至少一种助催化剂助剂以及任选的清除剂引入聚合反应器中， 并且使所述烯烃聚合，其中所述助催化剂是通过使至少一种元素周期系统的IIA族或IIIA族的至少一种金属烷基化合物与至少一种元素周期系统的至少一种化合物（A）反应，在引入反应器之前分别制备的反应产物 式RmXR'n，其中R是具有1至30个碳原子的支链，直链或环状的取代或未取代的烃基，R'是氢或具有至少一个活性氢的任何官能团，X是至少一个 选自O，N，P或S或其组合的杂原子，并且其中n和m各自为至少1并且使得该式不具有净电荷。

    Process for the Preparation of Linear Alpha-Olefins and Catalyst Used Therein
    8.
    发明申请
    Process for the Preparation of Linear Alpha-Olefins and Catalyst Used Therein 有权
    线性α-烯烃及其所用催化剂的制备方法

    公开(公告)号：US20090306449A1

    公开(公告)日：2009-12-10

    申请号：US11990173

    申请日：2006-08-10

    申请人： Vugar O. Aliyev ,  Atieh Abu-Raqabah ,  Mohammad Zahoor

    发明人： Vugar O. Aliyev ,  Atieh Abu-Raqabah ,  Mohammad Zahoor

    IPC分类号： C07C2/26 ,  B01J31/14

    CPC分类号： B01J31/2226 ,  B01J31/04 ,  B01J31/143 ,  B01J2231/20 ,  B01J2531/48 ,  C07C2/30 ,  C07C11/02

    摘要： The present invention relates to a process for the preparation of linear low molecular weight alpha-olefins having 4 to 24 carbon atoms, comprising oligomerizing ethylene in an inert solvent in the presence of a catalyst system comprising: (i) zirconium carboxylate of the formula (R1COO)mZrCl4-m, wherein R1 is saturated or unsaturated aliphatic C1-C10 hydrocarbon or aromatic C6-C14 hydrocarbon and m fulfills 1≦m≦4, (ii) at least one aluminum compound selected from organoaluminum compounds of the formula R2nAlX3-n, wherein R2 is C1-C20 alkyl, X is chlorine, bromine or iodine, and n fulfills 1≦n≦2, and/or aluminoxanes, and (iii) at least two different additives selected from the group consisting of hydrogen, esters, ketones, ethers, amines, anhydrides, phosphines and sulfur compounds; as well as to a catalyst used therein.

    摘要翻译： 本发明涉及制备具有4至24个碳原子的线型低分子量α-烯烃的方法，包括在惰性溶剂中在催化剂体系存在下使乙烯低聚，包括：（i）式 R1COO）mZrCl4-m，其中R1是饱和或不饱和脂族C 1 -C 10烃或芳族C 6 -C 14烃，m满足1≤n≤4，（ii）至少一种铝化合物，其选自式R2nAlX3的有机铝化合物 -n，其中R2是C1-C20烷基，X是氯，溴或碘，n满足1≤n≤2，和/或铝氧烷，和（iii）至少两种不同的添加剂，其选自 氢，酯，酮，醚，胺，酸酐，膦和硫化合物; 以及其中使用的催化剂。

    Process for the polymerizaion of olefins
    10.
    发明申请
    Process for the polymerizaion of olefins 有权
    烯烃聚合方法

    公开(公告)号：US20090203859A1

    公开(公告)日：2009-08-13

    申请号：US11921616

    申请日：2006-05-12

    申请人： Wei Xu ,  Vugar O. Aliyev ,  Sirajudeen Mohamed ,  Atieh Abu-Raqabah

    发明人： Wei Xu ,  Vugar O. Aliyev ,  Sirajudeen Mohamed ,  Atieh Abu-Raqabah

    IPC分类号： C08F4/52

    CPC分类号： C08F10/02 ,  C08F110/02 ,  C08F210/16 ,  Y10S526/943 ,  C08F2/002 ,  C08F210/14

    摘要： The present invention relates to a process for the polymerization of olefins, comprising the steps of introducing at least one olefin, at least one polymerization catalyst, at least one cocatalyst and at least one cocatalyst aid, and optionally a scavenger, into a polymerization reactor, and polymerizing the olefin, wherein the cocatalyst aid is a reaction product prepared separately prior to the introduction into the reactor by reacting at least one metal alkyl compound of group IIA or IIIA of the periodic system of elements and at least one compound (A) of the formula RmXR′n, wherein R is a branched, straight, or cyclic, substituted or unsubstituted, hydrocarbon group having 1 to 30 carbon atoms, R′ is hydrogen or any functional group with at least one active hydrogen, X is at least one heteroatom selected from the group of O, N, P or S or a combination thereof, and wherein n and m are each at least 1 and are such that the formula has no net charge.

    摘要翻译： 本发明涉及一种烯烃聚合方法，包括以下步骤：将至少一种烯烃，至少一种聚合催化剂，至少一种助催化剂和至少一种助催化剂助剂以及任选的清除剂引入聚合反应器中， 并且使所述烯烃聚合，其中所述助催化剂是通过使至少一种元素周期系统的IIA族或IIIA族的至少一种金属烷基化合物与至少一种元素周期系统的至少一种化合物（A）反应，在引入反应器之前分别制备的反应产物 式RmXR'n，其中R是具有1至30个碳原子的支链，直链或环状的取代或未取代的烃基，R'是氢或具有至少一个活性氢的任何官能团，X是至少一个 选自O，N，P或S或其组合的杂原子，并且其中n和m各自为至少1并且使得该式不具有净电荷。