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    Halogenovinyl-substituted tetra-hydrofuran-2-ones
    1.
    发明授权
    Halogenovinyl-substituted tetra-hydrofuran-2-ones 失效
    卤代乙烯基取代的四氢呋喃-2-酮

    公开(公告)号：US4288370A

    公开(公告)日：1981-09-08

    申请号：US89344

    申请日：1979-10-30

    申请人： Hans-Georg Heine ,  Armin Hubner ,  Willy Hartmann

    发明人： Hans-Georg Heine ,  Armin Hubner ,  Willy Hartmann

    IPC分类号： C07C49/687 ,  C07C49/693 ,  C07D307/33 ,  C07D307/94 ,  C07D307/32

    CPC分类号： C07D307/33 ,  C07C49/687 ,  C07C49/693 ,  C07D307/94

    摘要： Halogenovinyl-substituted tetrahydrofuran-2-ones of the formula ##STR1## are prepared by reacting a peracid such as peracetic, perpropionic or m-chloroperbenzoic acid with a halogenvinyl-substituted cyclobutanene of the formula ##STR2## in which R.sup.1 to R.sup.8 can be hydrogen, halogen, cyano or various organic radicals, or in pairs can make up a ring. Products wherein R.sup.3 is not hydrogen or R.sup.1 is not halogen are new. The products are useful as intermediates in making insecticides.

    摘要翻译： 通过使过酸如过乙酸，过丙酸或间氯过苯甲酸与式为“IMAGE”的卤代乙烯基取代的环丁腈反应制备式“IMAGE”的卤代乙烯基取代的四氢呋喃-2-酮，其中R 1至R 8可以是氢 ，卤素，氰基或各种有机基团，或成对可以构成环。 R3不是氢或R1不是卤素的产物是新的。 该产品可用作制造杀虫剂的中间体。

    1,2-Halohydrincarboxylic acid esters and a process for their preparation
    2.
    发明授权
    1,2-Halohydrincarboxylic acid esters and a process for their preparation 失效
    1,2-卤代羧酸羧酸酯及其制备方法

    公开(公告)号：US4252738A

    公开(公告)日：1981-02-24

    申请号：US887900

    申请日：1978-03-17

    申请人： Willy Hartmann ,  Hans-Georg Heine

    发明人： Willy Hartmann ,  Hans-Georg Heine

    IPC分类号： C07C69/013 ,  B01J23/00 ,  B01J31/00 ,  C07B61/00 ,  C07C45/54 ,  C07C67/00 ,  C07C253/00 ,  C07C255/46 ,  C07D317/44 ,  C07C120/00 ,  C07C69/12 ,  C07C69/74 ,  C07C69/78

    CPC分类号： C07D317/44 ,  C07C45/54

    摘要： 1,2-Halohydrincarboxylic acid esters of the formula ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, and R.sup.4 are identical or different and represent hydrogen, cyano and optionally substituted alkyl, alkenyl, aralkyl, aryl, alkoxycarbonyl, acyloxy, alkoxy and aryloxy, and furthermoreR.sup.1 and R.sup.2 and/or R.sup.3 and R.sup.4, or R.sup.1 and R.sup.3 and/or R.sup.2 and R.sup.4 can be linked, forming a ring with the carbon atoms to which they are bonded;R.sup.5 represents hydrogen and optionally substituted alkyl, alkenyl, aralkyl, aryl, alkoxy and alkoxycarbonyl andX represents fluorine, chlorine, bromine and iodine; a process for preparing such 1,2-halohydrincarboxylic acid esters by reacting a cyclobutane-cis-1,2-diol of the formula ##STR2## with an orthoester of the formula ##STR3## wherein R.sup.1 -R.sup.5 have the previously ascribed significance and R.sup.6 -R.sup.8 are identical or different and represent optionally substituted alkyl, alkenyl, aralkyl and aryl, (or a ketene-acetal corresponding thereto) to give a 1,3-dioxolane and reacting the resultant 1,3-dioxolane with a halogenosilane or an acid halide. Also disclosed is a process for preparing compounds of the formula ##STR4## by contacting a 1,2-halohydrin ester of the formula given above with a base suitably at a temperature of 20.degree. to 150.degree. C.

    摘要翻译： 式（I）的其中R 1，R 2，R 3和R 4相同或不同并表示氢，氰基和任选取代的烷基，烯基，芳烷基，芳基，烷氧基羰基，酰氧基，烷氧基的1,2-卤代羧酸羧酸酯 和芳氧基，此外，R 1和R 2和/或R 3和R 4，或R 1和R 3和/或R 2和R 4可以连接，与它们所键合的碳原子形成环; R5表示氢和任选取代的烷基，烯基，芳烷基，芳基，烷氧基和烷氧基羰基，X表示氟，氯，溴和碘; 通过使式（II）的环丁烷 - 顺-1,2-二醇与式（III）的原酸酯反应制备这种1,2-卤代醇羧酸酯的方法，其中R1-R5具有 以前的含义和R6-R8相同或不同，表示任选取代的烷基，烯基，芳烷基和芳基（或与其对应的乙烯酮缩醛），得到1,3-二氧戊环并使所得1,3-二氧戊环 与卤代硅烷或酰卤。 还公开了通过使上述式I的1,2-卤代醇与碱适宜地在20-150℃的温度下接触来制备式（V）的化合物的方法。

    .DELTA.4-Oxazolin-2-ones and process therefor
    3.
    发明授权
    .DELTA.4-Oxazolin-2-ones and process therefor 失效
    {66 4-恶唑啉-2-酮及其制备方法

    公开(公告)号：US4130563A

    公开(公告)日：1978-12-19

    申请号：US770259

    申请日：1977-02-18

    申请人： Karl-Heinz Scholz ,  Willy Hartmann ,  Hans-Georg Heine

    发明人： Karl-Heinz Scholz ,  Willy Hartmann ,  Hans-Georg Heine

    IPC分类号： C07D263/22 ,  C07D263/26 ,  C07D263/38 ,  C07D263/58

    CPC分类号： C07D263/58 ,  C07D263/22 ,  C07D263/26 ,  C07D263/38

    摘要： Compounds having the formula ##STR1## wherein R is hydrogen or an acyl radical are prepared by chlorinating 3-acyl-oxazolidin-2-ones, followed by dehydrochlorination and optionally by saponification and reacylation. The compounds are useful as starting material for substitution and addition reactions and as vinyl monomers in homo- and copolymerizations, whereby oxazolidin-2-one rings containing polymers are formed. These polymers can be used as antistatic agents, dyeing auxiliaries and ion exchangers.

    摘要翻译： 通过氯化3-酰基 - 恶唑烷-2-酮，然后脱氯化氢并任选通过皂化和再酰化来制备具有式“IMAGE”的化合物，其中R是氢或酰基。 该化合物可用作取代和加成反应的起始原料，并且可用作均聚和共聚中的乙烯基单体，由此形成含有恶唑烷-2-酮环的聚合物。 这些聚合物可用作抗静电剂，染色助剂和离子交换剂。

    Process for the preparation of diacylated 4-imidazolin-2-ones
    4.
    发明授权
    Process for the preparation of diacylated 4-imidazolin-2-ones 失效
    二酰化4-咪唑啉-2-酮的制备方法

    公开(公告)号：US4238618A

    公开(公告)日：1980-12-09

    申请号：US884520

    申请日：1978-03-08

    申请人： Karl-Heinz Scholz ,  Willy Hartmann ,  Hans-Georg Heine

    发明人： Karl-Heinz Scholz ,  Willy Hartmann ,  Hans-Georg Heine

    IPC分类号： C07D233/70 ,  C07D235/02 ,  C07D235/26

    CPC分类号： C07D235/02 ,  C07D233/70 ,  C07D235/26

    摘要： A process for the preparation of a diacylated 4-imidazolin-2-one of the formula ##STR1## wherein R.sup.1 and R.sup.2 independently represent hydrogen, optionally substituted alkyl, cycloalkyl, aryl and alkoxy, which comprises contacting a compound of the formula of II ##STR2## wherein R.sup.1 and R.sup.2 of the previously assigned significance with a source of chlorine at a temperature from 20.degree. to 150.degree. C. in the presence of a radical forming agent or under ultra-violet light and thereafter dehydrohalogenating or dehalogenating the resultant chlorinated product the diacylated 4-imidazolin-2-ones prepared by the process are useful for photochemical cycloadditions and as intermediates for the preparation of compounds in the biotin series.

    摘要翻译： 制备式（I）的二酰化4-咪唑啉-2-酮的方法，其中R 1和R 2独立地表示氢，任选取代的烷基，环烷基，芳基和烷氧基，其包括使式 的II（II）化合物，其中在自由基形成剂存在下或在紫外光下，在20至150℃的温度下，将具有氯源的先前指定的含义的R 1和R 2在脱卤化氢 或脱卤化所得氯化产物，通过该方法制备的二酰化4-咪唑啉-2-酮可用于光化学环加成和作为制备生物素系列中化合物的中间体。

    Preparation of halogenovinyl-substituted tetra-hydrofuran-2-ones
    5.
    发明授权
    Preparation of halogenovinyl-substituted tetra-hydrofuran-2-ones 失效
    卤代乙烯基取代的四氢呋喃-2-酮的制备

    公开(公告)号：US4225704A

    公开(公告)日：1980-09-30

    申请号：US936988

    申请日：1978-08-25

    申请人： Hans-Georg Heine ,  Armin Hubner ,  Willy Hartmann

    发明人： Hans-Georg Heine ,  Armin Hubner ,  Willy Hartmann

    IPC分类号： C07C49/687 ,  C07C49/693 ,  C07D307/33 ,  C07D307/94 ,  C07D307/20

    CPC分类号： C07D307/33 ,  C07C49/687 ,  C07C49/693 ,  C07D307/94

    摘要： Halogenovinyl-substituted tetrahydrofuran-2-ones of the formula ##STR1## are prepared by reacting a peracid such as peracetic, perpropionic or m-chloroperbenzoic acid with a halogenvinyl-substituted cyclobutanone of the formula ##STR2## in which R.sup.1 to R.sup.8 can be hydrogen, halogen, cyano or various organic radicals, or in pairs can make up a ring.Products wherein R.sup.3 is not hydrogen or R.sup.1 is not halogen are new. The products are useful as intermediates in making insecticides.

    摘要翻译： 通过使过酸如过乙酸，过丙酸或间氯过苯甲酸与式（IMAGE）的卤素乙烯基取代的环丁酮反应制备式IMAMA的卤代乙烯基取代的四氢呋喃-2-酮，其中R 1至R 8可以是氢 ，卤素，氰基或各种有机基团，或成对可以构成环。 R3不是氢或R1不是卤素的产物是新的。 该产品可用作制造杀虫剂的中间体。

    Preparation of cyclobutanones
    7.
    发明授权
    Preparation of cyclobutanones 失效
    环丁酮的制备

    公开(公告)号：US4216172A

    公开(公告)日：1980-08-05

    申请号：US886229

    申请日：1978-03-13

    申请人： Hans-Georg Heine ,  Willy Hartmann

    发明人： Hans-Georg Heine ,  Willy Hartmann

    IPC分类号： C07C49/385 ,  C07C45/00 ,  C07C45/51 ,  C07C49/587 ,  C07C67/00 ,  C07C69/757 ,  C07C231/00 ,  C07C231/12 ,  C07C235/82 ,  C07C253/00 ,  C07C255/46 ,  C07C255/56 ,  C07F9/38 ,  C07F9/40 ,  C07C45/02

    CPC分类号： C07C45/516

    摘要： A process for the preparation of a cyclobutanone of the formula ##STR1## in which R.sup.1 to R.sup.6 each independently is a hydrogen, halogen, cyano, alkoxy, alkoxycarbonyl, carboxamido, dialkylphosphono, alkyl, cycloalkyl, aryl, aralkyl or alkenyl radical, or two of them together with the carbon atom to which each is linked form a ring,comprising reacting an N,N-disubstituted carboxylic acid amide of the formula ##STR2## in which R.sup.7 and R.sup.8 each independently is an alkyl, cycloalkyl, alkenyl, aryl or aralkyl radical or together form a ring, with an inorganic acid halide, and then reacting the product with a tertiary amine, an olefin of the formula ##STR3## and a Lewis acid, and subsequently hydrolyzing the mass. Preferably isobutyric acid dimethylamide is employed as the carboxylic acid amide, phosgene is employed as the inorganic acid halide, triethylamine is employed as the tertiary amine and zinc chloride or titanium tetrachloride is employed as the Lewis acid. The products are known intermediates for insecticides.

    摘要翻译： 制备式“IMAGE”的环丁酮的方法，其中R 1至R 6各自独立地为氢，卤素，氰基，烷氧基，烷氧基羰基，甲酰氨基，二烷基膦酰基，烷基，环烷基，芳基，芳烷基或烯基，或两个 它们与各自连接的碳原子一起形成环，包括使式“IMAGE”的N，N-二取代的羧酸酰胺与其中R 7和R 8各自独立地为烷基，环烷基，烯基，芳基或 芳烷基或与无机酰卤一起形成环，然后使产物与叔胺，式“IMAGE”的烯烃和路易斯酸反应，随后水解该物质。 优选使用异丁酸二甲基酰胺作为羧酸酰胺，光气用作无机酰卤，三乙胺用作叔胺，氯化锌或四氯化钛用作路易斯酸。 该产品是已知的杀虫剂中间体。

    Process for the preparation of diacylated 4-imidazolin-2-ones
    9.
    发明授权
    Process for the preparation of diacylated 4-imidazolin-2-ones 失效
    二酰化4-咪唑啉-2-酮的制备方法

    公开(公告)号：US4294973A

    公开(公告)日：1981-10-13

    申请号：US101610

    申请日：1979-12-10

    申请人： Karl-Heinz Scholz ,  Willy Hartmann ,  Hans-Georg Heine

    发明人： Karl-Heinz Scholz ,  Willy Hartmann ,  Hans-Georg Heine

    IPC分类号： C07D233/70 ,  C07D235/02 ,  C07D235/26

    CPC分类号： C07D235/02 ,  C07D233/70 ,  C07D235/26

    摘要： A process for the preparation of a diacylated 4-imidazolin-2-one of the formula ##STR1## wherein R.sup.1 and R.sup.2 independently represent hydrogen, optionally substituted alkyl, cycloalkyl, aryl and alkoxy, which comprises contacting a compound of the formula ##STR2## wherein R.sup.1 and R.sup.2 have the previously assigned significance with a source of chlorine at a temperature from 20.degree. to 150.degree. C. in the presence of a radical forming agent or under ultra-violet light and thereafter dehydrohalogenating or dehalogenating the resultant chlorinated product.The diacylated 4-imidazolin-2-ones prepared by the process are useful for photochemical cycloadditions and as intermediates for the preparation of compounds in the biotin series.

    摘要翻译： 制备式（I）的二酰化4-咪唑啉-2-酮的方法，其中R 1和R 2独立地表示氢，任选取代的烷基，环烷基，芳基和烷氧基，其包括使式 （II）其中R1和R2在自由基形成剂存在下或在紫外光下在20℃至150℃的温度下具有预先给出的氯源，然后脱卤化氢或脱卤 得到的氯化产物。 通过该方法制备的二酰化4-咪唑啉-2-酮可用于光化学环加成和作为制备生物素系列中化合物的中间体。