公开(公告)号：US08470959B2

公开(公告)日：2013-06-25

申请号：US12790100

申请日：2010-05-28

申请人： Tomoyuki Hirayama ,  Junichi Fujisawa

发明人： Tomoyuki Hirayama ,  Junichi Fujisawa

IPC分类号： C08G73/10

CPC分类号： C08G73/0273 ,  C08G73/1075 ,  C08L79/02 ,  C08L79/08 ,  G02B6/12

摘要： A novel polyimide compound which has a low linear expansion coefficient and permits film formation by a spin coating method or the like, a preparation method for the polyimide compound, and an optical film and an optical waveguide produced by employing the compound. The polyimide compound has a structural unit represented by the following general formula (1): wherein X is a covalent single bond, —CH2—, —C(CF3)2— or —CR(R′)— (wherein R and R′, which may be the same or different, are each a C1 to C6 alkyl group or an aryl group); A and B, which may be the same or different, are substituents each selected from a hydroxyl group, a halogen group and a C1 to C4 alkyl group; a and b, which are the numbers of the substituents A and B, respectively, are each an integer of 0 to 2; and o, p and q are each an integer of 1 to 5.

摘要翻译： 具有低线性膨胀系数并允许通过旋涂法等成膜的新型聚酰亚胺化合物，聚酰亚胺化合物的制备方法以及使用该化合物制备的光学膜和光波导。 聚酰亚胺化合物具有由以下通式（1）表示的结构单元：其中X是共价单键，-CH 2 - ， - C（CF 3）2 - 或-CR（R'） - （其中R和R' 可以相同或不同，分别为C1〜C6烷基或芳基）; A和B可以相同或不同，为选自羟基，卤素基和C1-C4烷基的取代基; a和b分别为取代基A和B的数，分别为0〜2的整数。 和o，p和q各自为1〜5的整数。

公开(公告)号：US20110064930A1

公开(公告)日：2011-03-17

申请号：US12516036

申请日：2008-11-06

申请人： Tomoyuki Hirayama ,  Toshiyuki Iida ,  Yutaka Ohmori ,  Miyuki Kurogi ,  Hisae Shimizu

发明人： Tomoyuki Hirayama ,  Toshiyuki Iida ,  Yutaka Ohmori ,  Miyuki Kurogi ,  Hisae Shimizu

IPC分类号： B32B27/36 ,  C08G63/00 ,  B05D5/06 ,  B44C1/17

CPC分类号： B32B27/36 ,  B32B7/12 ,  B32B23/08 ,  B32B27/08 ,  B32B27/28 ,  B32B27/302 ,  B32B27/304 ,  B32B27/306 ,  B32B27/308 ,  B32B27/32 ,  B32B27/34 ,  B32B27/365 ,  B32B27/38 ,  B32B2250/24 ,  B32B2255/10 ,  B32B2255/26 ,  B32B2270/00 ,  B32B2307/306 ,  B32B2307/412 ,  B32B2307/418 ,  B32B2307/42 ,  B32B2457/20 ,  B32B2457/202 ,  B32B2457/204 ,  C08J5/18 ,  C08J2367/03 ,  G02B5/305 ,  G02F1/133528 ,  G02F1/13363 ,  G02F2001/133635 ,  G02F2201/50 ,  G02F2202/28 ,  Y10T428/21 ,  Y10T428/31786

摘要： The invention relates to an optical film containing aromatic polymer which shows high solubility to solvents, and methods for production thereof. Further, the invention also relates to an optical laminate, a polarizing plate, and an image display device each using the optical film. The optical film may be attained by using polyester with a specific structure. The polyester with a specific structure may be obtained by condensation polymerization of bisphenol compound(s) and dicarboxylic acid compound(s) with biphenyl structure, and preferably has no halogen atom in its chemical structure. The optical film of the invention advantageously has not only high solubility in solvents but also a high level of heat resistance and birefringence producing capability. When the content of the biphenyl structure is high, the optical film of the invention can also have large wavelength dispersion of birefringence.

摘要翻译： 本发明涉及一种含有对溶剂的溶解度高的芳香族聚合物的光学膜及其制造方法。 此外，本发明还涉及各自使用光学膜的光学层叠体，偏振片和图像显示装置。 光学膜可以通过使用具有特定结构的聚酯来实现。 具有特定结构的聚酯可以通过双酚化合物和二羧酸化合物与联苯结构的缩聚获得，并且优选在其化学结构中不具有卤素原子。 本发明的光学膜有利地不仅在溶剂中的溶解度高，而且具有高水平的耐热性和双折射产生能力。 当联苯结构的含量高时，本发明的光学膜也可以具有双折射的大的波长色散。

公开(公告)号：US20100058871A1

公开(公告)日：2010-03-11

申请号：US12517234

申请日：2008-01-24

申请人： Masayuki Takeishi ,  Masanori Shimazaki ,  Masahiro Yui ,  Tomoyuki Hirayama

发明人： Masayuki Takeishi ,  Masanori Shimazaki ,  Masahiro Yui ,  Tomoyuki Hirayama

IPC分类号： G01N29/00

CPC分类号： G01N29/2418 ,  G01N29/34 ,  G01N2291/2634 ,  G10K9/12 ,  G10K15/046

摘要： An ultrasonic inspection apparatus is provided in which the size of the apparatus can be made compact by using laser light, the degradation and deformation of the inspected object is prevented, and a broad range of inspections can be carried out. An ultrasonic inspection apparatus (1) is provided with a laser apparatus (5) that irradiates laser light and a volumetric inspection ultrasonic wave transmitter (17) having a transmitting diaphragm (39) that is irradiated by the laser light emitted by the laser apparatus (5) and that generates ultrasonic waves (C); and the ultrasonic inspection apparatus (1) carries out volumetric inspections by irradiating the ultrasonic waves (C) that are generated by the transmitting diaphragm (39) of the ultrasonic wave transmitting portion (17) to the inspected object. In addition, the ultrasonic inspection apparatus (1) is further provided with a surface inspection ultrasonic wave transmitting portion (19), and enables the carrying out of inspections having the characteristics of volumetric inspections and surface inspections, that is, hybrid inspections.

摘要翻译： 提供一种超声波检查装置，通过使用激光可以使装置的尺寸变小，可以防止检查对象的劣化和变形，能够进行宽范围的检查。 超声波检查装置（1）设置有照射激光的激光装置（5）和具有由激光装置发射的激光照射的发射光圈（39）的体积检查用超声波发射器（17） 5），并产生超声波（C）; 超声波检查装置（1）通过将由超声波发送部（17）的发送用振动板（39）生成的超声波（C）照射到被检查体来进行体积检查。 此外，超声波检查装置（1）还具备表面检查用超声波透过部（19），能够进行具有体积检查和表面检查特性的检查，即混合检查。

公开(公告)号：US10041154B2

公开(公告)日：2018-08-07

申请号：US14234770

申请日：2012-07-10

申请人： Tomoyuki Hirayama ,  Pizhi Zhao ,  Takeshi Handa ,  Toshiya Anami ,  Yusuke Nagaishi ,  Koji Itakura ,  Hirokazu Miyagawa ,  Tsutomu Hattori ,  Shigenori Yoshizawa ,  Akio Yoshizawa

发明人： Tomoyuki Hirayama ,  Pizhi Zhao ,  Takeshi Handa ,  Toshiya Anami ,  Yusuke Nagaishi ,  Koji Itakura ,  Hirokazu Miyagawa ,  Tsutomu Hattori ,  Shigenori Yoshizawa ,  Akio Yoshizawa

IPC分类号： C22C21/06 ,  C22F1/047 ,  C22C21/08 ,  C22F1/00 ,  B22D11/00 ,  B21B3/00

摘要： An aluminum alloy sheet includes an aluminum alloy substrate having a composition containing, by mass percentage, 3.0 to 4.0% of magnesium, 0.2 to 0.4% of manganese, 0.1 to 0.5% of iron, not less than 0.03% but less than 0.10% of copper, and less than 0.20% of silicon, with the remainder being aluminum and unavoidable impurities. A peak concentration of a copper concentration distribution in a thickness direction in a region at a depth of 15 nm to 200 nm from the surface of the aluminum alloy substrate is equal to or more than 0.15%, and the aluminum alloy substrate has a recrystallized structure with an average grain size of 15 μm or less.

公开(公告)号：US08901196B2

公开(公告)日：2014-12-02

申请号：US12985711

申请日：2011-01-06

申请人： Tomoyuki Hirayama

发明人： Tomoyuki Hirayama

IPC分类号： C09D4/06 ,  C08F265/06 ,  G02B1/04 ,  G02B6/122 ,  G02B6/138 ,  G03F7/027 ,  C08K5/37

CPC分类号： C09D4/06 ,  C08F265/06 ,  C08K5/37 ,  G02B1/045 ,  G02B6/1221 ,  G02B6/138 ,  G03F7/0275 ,  C08L33/06

摘要： A liquid resin composition is provided which satisfies both a tackiness-free requirement and a curing sensitivity requirement for production of an optical waveguide by a roll-to-roll process. An optical waveguide produced by using the liquid resin composition and a production method of the optical waveguide are also provided. The liquid resin composition for the production of the optical waveguide comprises: (A) a (meth)acrylate polymer, as a major component, having a plurality of (meth)acryl groups in its molecule; (B) a liquid thiol monomer having a plurality of thiol groups in its molecule; and (C) a photopolymerization initiator.

摘要翻译： 提供一种液体树脂组合物，其通过卷对卷方法满足生产光波导的无粘性要求和固化敏感性要求。 还提供了通过使用液体树脂组合物制造的光波导和光波导的制造方法。 用于生产光波导的液体树脂组合物包括：（A）在其分子中具有多个（甲基）丙烯酰基的主要组分的（甲基）丙烯酸酯聚合物; （B）在其分子中具有多个硫醇基团的液体硫醇单体; 和（C）光聚合引发剂。

公开(公告)号：US20120155819A1

公开(公告)日：2012-06-21

申请号：US13296577

申请日：2011-11-15

申请人： Tomoyuki Hirayama ,  Junichi Fujisawa

发明人： Tomoyuki Hirayama ,  Junichi Fujisawa

IPC分类号： G02B6/02 ,  C08F2/50 ,  G03F7/038

CPC分类号： G03F7/038 ,  G02B6/122 ,  G02B6/1221 ,  G02B6/138 ,  G03F7/0385 ,  G03F7/0388

摘要： A resin composition for an optical waveguide is provided, which has excellent adhesiveness to a cladding layer of the optical waveguide and excellent patternability for formation of a core portion of the optical waveguide and reduces the optical waveguide loss. An optical waveguide produced by using the resin composition is also provided. The resin composition comprises: (A) a multifunctional partially-acrylated epoxy resin, as a major component, having an epoxy group and a (meth)acrylate group in the same main chain thereof; and (B) a photopolymerization initiator as a curing component. The optical waveguide includes: a substrate; a cladding layer provided on the substrate; and a core portion provided on the cladding layer for transmission of an optical signal; wherein the core portion is formed from the resin composition.

摘要翻译： 提供了一种用于光波导的树脂组合物，其对于光波导的包层具有优异的粘合性，并且具有优异的用于形成光波导的芯部的图案性，并且减小了光波导损耗。 还提供了使用该树脂组合物制造的光波导。 树脂组合物包含：（A）作为主要成分的多官能部分丙烯酸酯化环氧树脂，在其主链中具有环氧基和（甲基）丙烯酸酯基; 和（B）作为固化成分的光聚合引发剂。 光波导包括：基板; 设置在基板上的包覆层; 以及芯部，设置在所述包层上，用于传输光信号; 其中芯部由树脂组合物形成。

公开(公告)号：US20120114294A1

公开(公告)日：2012-05-10

申请号：US13286830

申请日：2011-11-01

申请人： Junichi Fujisawa ,  Tomoyuki Hirayama

发明人： Junichi Fujisawa ,  Tomoyuki Hirayama

IPC分类号： G02B6/10 ,  G03F7/004

CPC分类号： G02B6/138 ,  G03F7/038 ,  G03F7/0388

摘要： A resin composition for an optical waveguide is provided, which permits easy formation of a core pattern using an alkali developing liquid and suppresses degradation of the alkali developing liquid. An optical waveguide produced by using the resin composition is provided. The resin composition comprises: (A) an alkali soluble resin, as a major component, having a structural unit represented by formula (1): wherein R1, R2 and R3, which may be the same or different, are each a hydrogen atom or a methyl group; R5 and R6, which may be the same or different, are each a hydrogen atom or a methyl group; R4 is and m+n+p=1, m>0, n>0 and p>0; and (B) a photopolymerization initiator. The optical waveguide includes a substrate, a cladding layer provided thereon, and a core portion provided in the cladding layer for transmitting an optical signal.

摘要翻译： 提供了一种用于光波导的树脂组合物，其允许使用碱性显影液容易地形成芯图案并抑制碱性显影液的劣化。 提供了使用该树脂组合物制造的光波导。 树脂组合物包含：（A）具有由式（1）表示的结构单元作为主要成分的碱溶性树脂：其中可以相同或不同的R 1，R 2和R 3各自为氢原子或 甲基; R5和R6可以相同或不同，分别为氢原子或甲基; R4是和m + n + p = 1，m> 0，n> 0和p> 0; 和（B）光聚合引发剂。 光波导包括衬底，设置在其上的覆层，以及设置在包层中的用于发送光信号的芯部。

公开(公告)号：US20110280531A1

公开(公告)日：2011-11-17

申请号：US13098699

申请日：2011-05-02

申请人： Tomoyuki Hirayama

发明人： Tomoyuki Hirayama

IPC分类号： G02B6/02 ,  G03F7/004

CPC分类号： G02B1/045 ,  G03F7/0005 ,  G03F7/038 ,  C08L63/00

摘要： A resin composition is provided, which satisfies both an uncured layer flexibility requirement and a patterning resolution requirement for production of an optical waveguide by a roll-to-roll process. An optical waveguide produced by using the resin composition is also provided. The resin composition comprises: (A) an aromatic multifunctional epoxy polymer having a weight average molecular weight (Mw) of 500 to 5000; (B) an aromatic multifunctional epoxy polymer having a weight average molecular weight (Mw) of 10000 to 50000; (C) at least one of monofunctional, difunctional and trifunctional liquid aromatic epoxy monomers; and (D) a photoacid generator; wherein the components (A), (B) and (C) are present in proportions of 80 to 90 parts by weight, 5 to 15 parts by weight, and 1 to 10 parts by weight, respectively, based on a total of 100 parts by weight of the components (A), (B) and (C).

摘要翻译： 提供一种树脂组合物，其通过卷对卷方法满足未固化层柔性要求和用于生产光波导的图案分辨率要求。 还提供了使用该树脂组合物制造的光波导。 树脂组合物包含：（A）重均分子量（Mw）为500〜5000的芳族多官能环氧聚合物; （B）重均分子量（Mw）为10000〜50000的芳香族多官能环氧聚合物; （C）单官能，二官能和三官能的液体芳族环氧单体中的至少一种; 和（D）光致酸产生剂; 其中组分（A），（B）和（C）分别以80至90重量份，5至15重量份和1至10重量份的比例存在，基于总计100份 的组分（A），（B）和（C）。

公开(公告)号：US20110013278A1

公开(公告)日：2011-01-20

申请号：US12920528

申请日：2009-03-25

申请人： Tomoyuki Hirayama ,  Toshiyuki Iida ,  Yutaka Ohmori ,  Satoru Suzuki ,  Miyuki Kurogi ,  Hisae Shimizu

发明人： Tomoyuki Hirayama ,  Toshiyuki Iida ,  Yutaka Ohmori ,  Satoru Suzuki ,  Miyuki Kurogi ,  Hisae Shimizu

IPC分类号： G02B5/30 ,  C08G63/181

CPC分类号： C08G63/197 ,  C08G63/195 ,  C08J5/18 ,  C08J2367/03 ,  G02B5/3083

摘要： The birefringent film of the present invention contains an aromatic polyester having a repeating unit represented by the following general formula (1).In the general formula (1), A(s), B(s), C(s), and D(s) are each independently represent a group selected from a halogeno group, an alkyl group which has 1 to 6 carbon atoms, and an aryl group. Also, a and b each represent an integer of 0 to 4, and c and d each represent an integer of 0 to 3. R1 represents a hydrogen atom, or an alkyl group which has 1 to 10 carbon atoms. R2 represents an alkyl group which has 2 to 10 carbon atoms. R3 to R6 each independently represent a group or atom selected from a hydrogen atom, a halogeno group, an alkyl group which has 1 to 6 carbon atoms, and an aryl group. Furthermore, l and m each represent an integer of 2 or more.

摘要翻译： 本发明的双折射膜含有具有下述通式（1）表示的重复单元的芳香族聚酯。 在通式（1）中，A（s），B（s），C（s）和D（s）各自独立地表示选自卤代基，具有1至6个碳原子的烷基 ，和芳基。 此外，a和b各自表示0〜4的整数，c和d表示0〜3的整数.R1表示氢原子或碳原子数1〜10的烷基。 R2表示碳原子数为2〜10的烷基。 R3至R6各自独立地表示选自氢原子，卤代基，具有1至6个碳原子的烷基和芳基的基团或原子。 此外，l和m分别表示2以上的整数。

公开(公告)号：US20100265579A1

公开(公告)日：2010-10-21

申请号：US12721901

申请日：2010-03-11

申请人： Toshiyuki Iida ,  Tomoyuki Hirayama ,  Yutaka Ohmori ,  Miyuki Kurogi ,  Hisae Shimizu ,  Junichi Nagase

发明人： Toshiyuki Iida ,  Tomoyuki Hirayama ,  Yutaka Ohmori ,  Miyuki Kurogi ,  Hisae Shimizu ,  Junichi Nagase

IPC分类号： G02B27/28 ,  C08L67/00 ,  B32B5/00 ,  B05D5/06

CPC分类号： C08L67/03 ,  C08J5/18 ,  C08J2367/03 ,  C08J2367/06 ,  C08L67/06 ,  G02B5/3083 ,  G02F1/133634 ,  G02F2001/133637 ,  Y10T428/1041 ,  Y10T428/105 ,  Y10T428/26 ,  Y10T428/269 ,  Y10T428/31786 ,  C08L2666/18

摘要： The invention relates to an optical film containing polymers having different repeating units, and methods for production thereof. Further, the invention also relates to an optical laminate, a polarizing plate, and an image display device each using the optical film.The optical film of the invention advantageously has not only high solubility in solvents but also a high level of transparency since the polymers used in the optical film are compatible with each other. Further, wavelength dispersion of the birefringence of the optical film can be controlled by merely changing a ratio of polymers.

摘要翻译： 本发明涉及含有不同重复单元的聚合物的光学膜及其制备方法。 此外，本发明还涉及各自使用光学膜的光学层叠体，偏振片和图像显示装置。 本发明的光学膜有利地在溶剂中的溶解度高，而且由于光学膜中使用的聚合物彼此相容，所以具有高的透明度。 此外，光学膜的双折射的波长色散可以通过仅改变聚合物的比例来控制。