公开(公告)号：US07722958B2

公开(公告)日：2010-05-25

申请号：US11754694

申请日：2007-05-29

Applicant: Charles M. Kania ,  Roxalana L. Martin ,  Carolyn A. K. Novak ,  Thomas R. Hockswender ,  Mark A. Tucker ,  Mary Beth Grolemund ,  Deirdre Ragan ,  Alicia Williams

Inventor： Charles M. Kania ,  Roxalana L. Martin ,  Carolyn A. K. Novak ,  Thomas R. Hockswender ,  Mark A. Tucker ,  Mary Beth Grolemund ,  Deirdre Ragan ,  Alicia Williams

IPC: B32B5/16 ,  B32B9/04

CPC classification number: C08F212/08 ,  C08F212/14 ,  Y10T428/25 ,  Y10T428/256 ,  Y10T428/257 ,  Y10T428/259 ,  Y10T428/26 ,  Y10T428/31663

Abstract: Provided is a film-forming composition substantially free of organic solvent which includes an aqueous dispersion of polymeric microparticles prepared by emulsion polymerization of a monomeric composition containing (1) at least 10 percent by weight of one or more vinyl aromatic compounds; (2) 0.1 to 10 percent by weight of one or more carboxylic acid functional polymerizable, ethylenically unsaturated monomers; (3) 0 to 10 percent by weight of one or more polymerizable monomers having one or more functional groups capable of reacting to form crosslinks; and (4) one or more polymerizable ethylenically unsaturated monomers. Each of (1), (2), (3) and (4) are different one from the other and at least one of (3) and (4) is present in the monomeric composition. Multi-layer composite coatings and coated substrates also are provided.

Abstract translation: 本发明提供一种基本上不含有机溶剂的成膜组合物，其包括通过含有（1）至少10重量％的一种或多种乙烯基芳族化合物的单体组合物的乳液聚合制备的聚合物微粒的水性分散体; （2）0.1至10重量％的一种或多种羧酸官能可聚合的烯属不饱和单体; （3）0〜10重量％的一种或多种具有一个或多个能够反应形成交联的官能团的可聚合单体; 和（4）一种或多种可聚合的烯属不饱和单体。 （1），（2），（3）和（4）中的每一个彼此不同，并且（3）和（4）中的至少一个存在于单体组合物中。 还提供多层复合涂层和涂覆的基底。

公开(公告)号：US07183355B2

公开(公告)日：2007-02-27

申请号：US10928803

申请日：2004-08-27

Applicant: Roxalana L. Martin ,  Edward R. Coleridge ,  Mark A. Tucker ,  Mary E. Grolemund

Inventor： Roxalana L. Martin ,  Edward R. Coleridge ,  Mark A. Tucker ,  Mary E. Grolemund

IPC: C08F8/30

CPC classification number: B05D7/57 ,  B05D1/007 ,  B05D3/0209 ,  B05D3/067 ,  B05D7/53 ,  C08F8/00 ,  C08F210/10 ,  C08F220/10 ,  C08F290/046 ,  C08G18/6229 ,  C08G18/792 ,  C08G18/798 ,  C08G18/8025 ,  C08G18/807 ,  C08G18/8074 ,  C08G2150/20 ,  C09D123/22 ,  C09D133/062 ,  C09D133/14 ,  Y10T428/31938 ,  C08F210/00 ,  C08F220/12 ,  C08L2666/28 ,  C08L2666/02 ,  C08L2666/14 ,  C08F212/00 ,  C08F220/00 ,  C08F2500/26 ,  C08F214/18 ,  C08F2500/03 ,  C08F2500/02 ,  C08F222/00

Abstract: A curable, aqueous film-forming composition is provided, comprising: (a) a copolymer containing reactive functional groups and comprising at least 30 mol % of residues having alternating structural units: -[DM-AM]- wherein DM represents a residue from a donor monomer, and AM represents a residue from an acceptor monomer, at least 15 mol % of the copolymer comprising a donor monomer having the structure (I): wherein R1 is linear or branched C1 to C4 alkyl, R2 is selected from methyl, linear, cyclic or branched C1 to C20 alkyl, alkenyl, aryl, alkaryl and aralkyl; and (b) a curing agent having functional groups reactive with the reactive functional groups of (a). The invention is also directed to a multi-component composite coating composition including a base coat deposited from a pigmented film-forming composition and a transparent topcoat applied over the base coat. At least one-coat is the film-forming composition described above.

Abstract translation: 提供了一种可固化的水性成膜组合物，其包含：（a）含有反应性官能团并且包含至少30mol％具有交替结构单元的残基的共聚物：<？in-line-formula description =“In-Line Formulas “end =”lead“？> - [DM-AM] - <？in-line-formula description =”In-line Formulas“end =”tail“？>其中DM表示来自供体单体的残基，AM表示 来自受主单体的残余物，至少15mol％的共聚物包含具有结构（I）的供体单体：其中R 1是直链或支链C 1至 C 4烷基，R 2选自甲基，直链，环状或支链C 1至C 20烷基 ，烯基，芳基，烷芳基和芳烷基; 和（b）具有与（a）的反应性官能团反应的官能团的固化剂。 本发明还涉及一种多组分复合涂料组合物，其包括从着色成膜组合物沉积的底涂层和涂覆在底涂层上的透明面漆。 至少一层是上述成膜组合物。

公开(公告)号：US06265489B1

公开(公告)日：2001-07-24

申请号：US09375017

申请日：1999-08-16

Applicant: Karen A. Barkac ,  Simion Coca ,  James R. Franks ,  Kurt A. Humbert ,  Paul H. Lamers ,  Roxalana L. Martin ,  James B. O'Dwyer ,  Kurt G. Olson ,  Daniela White

Inventor： Karen A. Barkac ,  Simion Coca ,  James R. Franks ,  Kurt A. Humbert ,  Paul H. Lamers ,  Roxalana L. Martin ,  James B. O'Dwyer ,  Kurt G. Olson ,  Daniela White

IPC: C08L3302

CPC classification number: C09D133/02 ,  C08L63/00 ,  C09D133/064 ,  C08L2666/14

Abstract: A thermosetting composition comprising a co-reactable solid, particulate mixture of (a) polycarboxylic acid functional polymer, and (b) epoxide functional crosslinking agent having at least two epoxide groups, e.g., triglycidyl isocyanurate (TGIC), is described. The polycarboxylic acid functional polymer is prepared by atom transfer radical polymerization and has well defined polymer chain architecture and polydispersity index of less than 2.0. The thermosetting compositions of the present invention have utility as powder coatings compositions.

Abstract translation: 描述了包含（a）多元羧酸官能聚合物和（b）具有至少两个环氧基团的环氧官能交联剂例如三缩水甘油基异氰脲酸酯（TGIC）的共反应固体，颗粒混合物的热固性组合物。 聚羧酸官能聚合物通过原子转移自由基聚合制备，并且具有良好的聚合物链结构和小于2.0的多分散指数。 本发明的热固性组合物可用作粉末涂料组合物。

公开(公告)号：US5684072A

公开(公告)日：1997-11-04

申请号：US408672

申请日：1995-03-22

Applicant: Daniel E. Rardon ,  Roxalana L. Martin ,  Dennis L. Faler ,  James E. Poole

Inventor： Daniel E. Rardon ,  Roxalana L. Martin ,  Dennis L. Faler ,  James E. Poole

IPC: C08G18/28 ,  C08G18/71 ,  C09D5/02 ,  C09D7/47 ,  C09D167/00 ,  C09D175/04 ,  C08J5/10 ,  C08K5/16 ,  C08L33/04

CPC classification number: C09D167/00 ,  C08G18/283 ,  C08G18/71 ,  C09D175/04 ,  C09D5/024 ,  C09D7/06

Abstract: A waterborne coating composition having improved smoothness is provided which contains a polymeric film-forming resin in aqueous medium and from about 0.1 percent to about 10 percent by weight based on total weight of resin solids of at least one material having the following structure: ##STR1## where n is an integer that is at least 1, R.sup.1 is hydrogen or lower alkyl having 1 to 10 carbon atoms, R.sup.2 is a divalent organic radical, and R.sup.3 is an alkyl, aryl, or alkylaryl group having 1 to 20 carbon atoms.

Abstract translation: 提供了具有改善的平滑度的水性涂料组合物，其含有在水性介质中的聚合物成膜树脂和占树脂固体总重量的约0.1％至约10％重量的至少一种具有以下结构的材料：其中n是至少为1的整数，R 1是氢或具有1至10个碳原子的低级烷基，R 2是二价有机基团，R 3是具有1至20个碳原子的烷基，芳基或烷芳基。

公开(公告)号：US5401790A

公开(公告)日：1995-03-28

申请号：US220658

申请日：1994-03-31

Applicant: James E. Poole ,  Roxalana L. Martin

Inventor： James E. Poole ,  Roxalana L. Martin

IPC: C08L75/04 ,  C09D5/02 ,  C09D167/00 ,  C09D175/00 ,  C09D177/00 ,  C09D201/00 ,  C08K5/16 ,  C08K5/20 ,  C08K5/21 ,  C08L75/00

CPC classification number: C09D167/00 ,  C09D201/00 ,  C09D5/024 ,  C08L75/04

Abstract: Waterborne coating compositions comprising polymeric film-forming resins and about 0.1 to 5 percent by weight based on weight of resin solids of an oligomer containing from about two to four urethane, urea, or amide moieties per molecule and two or more moieties selected from the group consisting of hydroxyl and tertiary amine. The oligomer improves the smoothness of the resulting coating.

Abstract translation: 包含聚合物成膜树脂的水性涂料组合物和基于树脂固体重量的约0.1至5重量％的每分子含有约2-4个氨基甲酸酯，脲或酰胺部分的低聚物和两个或更多个选自下组的部分 由羟基和叔胺组成。 低聚物改善了所得涂层的光滑度。

公开(公告)号：US20090098386A1

公开(公告)日：2009-04-16

申请号：US12338160

申请日：2008-12-18

Applicant: Roxalana L. Martin ,  Mark A. Tucker ,  George Yakulis, JR. ,  Thomas R. Hockswender

Inventor： Roxalana L. Martin ,  Mark A. Tucker ,  George Yakulis, JR. ,  Thomas R. Hockswender

IPC: B32B27/30 ,  C09D133/02 ,  B32B27/36

CPC classification number: C08F212/08 ,  C08F212/14 ,  C08K5/19 ,  C08L2666/04 ,  C09D133/14 ,  C09D167/00 ,  Y10T428/31551 ,  Y10T428/31786 ,  Y10T428/31855 ,  C08F220/06 ,  C08F220/20 ,  C08F2220/1858 ,  C08F220/14 ,  C08F2220/325

Abstract: The present invention is directed to waterborne curable film-forming compositions comprising a film-forming resin, a crosslinking agent, and an additive comprising isostearic acid neutralized with dimethylethanolamine. The compositions are essentially free of additives derived from reaction products of isocyanate functional materials and alkoxypolyalkylene compounds.The present invention further provides multi-component composite coating compositions comprising a first film-forming composition applied to a substrate to form a primer or base coat, and a second film-forming composition applied on top of the primer or base coat to form a top coat, the top coat comprising the composition described above.Coating compositions prepared from the curable compositions of the present invention demonstrate superior pop resistance properties, making them ideally suited for automotive applications.

Abstract translation: 本发明涉及包含成膜树脂，交联剂和包含用二甲基乙醇胺中和的异硬脂酸的添加剂的水性固化成膜组合物。 该组合物基本上不含有衍生自异氰酸酯官能材料和烷氧基聚亚烷基化合物的反应产物的添加剂。 本发明还提供了多组分复合涂料组合物，其包含施加到基材上以形成底漆或底漆的第一成膜组合物，以及施涂在底漆或底涂层顶部上形成顶部的第二成膜组合物 涂层，包括上述组合物的面漆。 由本发明的可固化组合物制备的涂料组合物表现出优异的弹性阻燃性能，使其非常适用于汽车应用。

公开(公告)号：US06472085B2

公开(公告)日：2002-10-29

申请号：US09864904

申请日：2001-05-24

Applicant: Karen A. Barkac ,  Simion Coca ,  James R. Franks ,  Kurt A. Humbert ,  Paul H. Lamers ,  Roxalana L. Martin ,  James B. O'Dwyer ,  Kurt G. Olson ,  Daniela White

Inventor： Karen A. Barkac ,  Simion Coca ,  James R. Franks ,  Kurt A. Humbert ,  Paul H. Lamers ,  Roxalana L. Martin ,  James B. O'Dwyer ,  Kurt G. Olson ,  Daniela White

IPC: B32B1508

CPC classification number: C08G59/3209 ,  C08G59/4207 ,  Y10T428/31699 ,  Y10T428/31928

Abstract: A multi-component composite coating composition comprising a base coat deposited from a pigmented film-forming composition and a transparent top coat applied over the base coat in which the base coat is a thermosetting composition comprising a co-reactable solid, particulate mixture of (i) an epoxy functional polymer containing at least one of the polymer chain structures -[(M)p-(G)q]x- or -[(G)q-(M)p]x- wherein M is an oxirane-free residue of at least one ethylenically unsaturated monomer, G is a glycidyl-functional ethylenically unsaturated monomer, p and q each independently has a value of 0 to typically less than 100, and x has a value of at least 1 to typically less than 100, the total value of p, q and x selected such that said epoxy functional polymer has a number average molecular weight of at least 250, and (ii) a co-reactant having functional groups reactive with the epoxy groups of (i). The epoxy functional polymer is prepared by atom transfer radical polymerization and has a polydispersity index of less than 2.5.

Abstract translation: 一种多组分复合涂料组合物，其包含从着色成膜组合物沉积的底涂层和涂覆在底涂层上的透明顶涂层，其中底涂层为热固性组合物，其包含可共反应的固体，（i ）包含至少一种聚合物链结构的环氧官能聚合物 - [（M）p-（G）q] x-或 - [（G）q-（M）p] x-，其中M是无环氧乙烷 至少一种烯属不饱和单体的残基，G是缩水甘油基官能的烯属不饱和单体，p和q各自独立地具有0至典型地小于100的值，x具有至少1至通常小于100的值， 所选择的p，q和x的总值使得所述环氧官能聚合物的数均分子量至少为250，和（ii）具有与（i）的环氧基反应的官能团的共反应物。 环氧官能聚合物通过原子转移自由基聚合制备，多分散指数小于2.5。

公开(公告)号：US06339126B1

公开(公告)日：2002-01-15

申请号：US09375014

申请日：1999-08-16

Applicant: Karen A. Barkac ,  Simion Coca ,  James R. Franks ,  Kurt A. Humbert ,  Paul H. Lamers ,  Roxalana L. Martin ,  James B. O'Dwyer ,  Kurt G. Olson ,  Daniela White

Inventor： Karen A. Barkac ,  Simion Coca ,  James R. Franks ,  Kurt A. Humbert ,  Paul H. Lamers ,  Roxalana L. Martin ,  James B. O'Dwyer ,  Kurt G. Olson ,  Daniela White

IPC: C08L5100

CPC classification number: C09D133/02 ,  C09D133/064 ,  Y10T428/31551 ,  Y10T428/31725 ,  Y10T428/31786 ,  Y10T428/31855 ,  C08L2666/36

Abstract: A thermosetting composition comprising a co-reactable solid, particulate mixture of (a) beta-hydroxyalkylamide crosslinking agent, e.g., bis(N,N-di-2-hydroxyethyl)adipamide, and (b) polycarboxylic acid functional polymer, is described. The polycarboxylic acid functional polymer is prepared by atom transfer radical polymerization and has well defined polymer chain architecture and polydispersity index of less than 2.5. The thermosetting compositions of the present invention have utility as powder coatings compositions.

公开(公告)号：US06268433B1

公开(公告)日：2001-07-31

申请号：US09375013

申请日：1999-08-16

Applicant: Karen A. Barkac ,  Simion Coca ,  James R. Franks ,  Kurt A. Humbert ,  Paul H. Lamers ,  Roxalana L. Martin ,  James B. O'Dwyer ,  Kurt G. Olson ,  Daniela White

Inventor： Karen A. Barkac ,  Simion Coca ,  James R. Franks ,  Kurt A. Humbert ,  Paul H. Lamers ,  Roxalana L. Martin ,  James B. O'Dwyer ,  Kurt G. Olson ,  Daniela White

IPC: C08L3314

CPC classification number: C08G59/3209 ,  C08G59/4207 ,  Y10T428/31699 ,  Y10T428/31928

Abstract: A thermosetting composition useful as a powder coating comprises a co-reactable solid, particulate mixture of (a) an epoxy functional polymer containing at least one of the polymer chain structures -[(M)p-(G)q]x- or -[(G)q-(M)p]x- wherein M is an oxirane-free residue of at least one ethylenically unsaturated monomer, G is a glycidyl-functional ethylenically unsaturated monomer, p and q each independently has a value of 0 to typically less than 100, and x has a value of at least 1 to typically less than 100, the total value of p, q and x selected such that said epoxy functional polymer has a number average molecular weight of at least 250, and (b) a co-reactant having functional groups reactive with the epoxy groups of (a), e.g., dodecanedioic acid. The epoxy functional polymer is prepared by atom transfer radical polymerization and a polydispersity index of less than 2.5.

Abstract translation: 可用作粉末涂料的热固性组合物包含（a）包含至少一种聚合物链结构 - [（M）p-（G）q] x - 或 - 的聚环氧官能聚合物的可共反应的固体颗粒混合物， [（G）q-（M）p] x-其中M是至少一种烯键式不饱和单体的不含环氧乙烷的残基，G是缩水甘油基官能的烯属不饱和单体，p和q各自独立地为0至 通常小于100，并且x具有至少1至通常小于100的值，选择p，q和x的总值使得所述环氧官能聚合物的数均分子量为至少250，并且（b ）具有与（a）的环氧基反应的官能团的共反应物，例如十二烷二酸。 环氧官能聚合物通过原子转移自由基聚合和小于2.5的多分散指数制备。

公开(公告)号：US5830928A

公开(公告)日：1998-11-03

申请号：US735989

申请日：1996-10-25

Applicant: Dennis L. Faler ,  James R. Franks ,  Roxalana L. Martin

Inventor： Dennis L. Faler ,  James R. Franks ,  Roxalana L. Martin

IPC: C08F283/01 ,  C09D151/08 ,  C09D167/06 ,  D06M15/507 ,  D06M15/51 ,  D06M23/08 ,  D06N3/12 ,  D06P1/44 ,  D06P1/52 ,  C08L51/08

CPC classification number: D06P1/5271 ,  C08F283/01 ,  C09D151/08 ,  C09D167/06 ,  D06M15/507 ,  D06M15/51 ,  D06M23/08 ,  D06N3/121 ,  D06P1/44 ,  Y10T442/2361

Abstract: The present invention provides a waterborne coating composition which includes a polymeric film-forming resin. The polymeric film-forming resin includes a dispersion of polymeric microparticles prepared by forming, in aqueous medium, a mixture of: (a) an unsaturated, substantially hydrophobic polyester component, and (b) an ethylenically unsaturated monomer component. With various hydrophobic polyesters, the ethylenically unsaturated monomer component of the polymeric film-forming resin includes: (a) an acrylamide or methacrylamide with N-methylol or N-alkoxymethyl functionality, (b) an alpha-beta ethylenically unsaturated compound with carboxyl functionality, and (c) an alpha-beta ethylenically unsaturated compound with no additional reactive functionality. Such a waterborne coating composition has a low V.O.C., provides added stiffness, does not block, and can be applied in such a manner that it does not substantially mask the texture of the nonwoven fabrics and/or textiles over which it is applied. When the hydrophobic polyester is prepared with polycarboxylic acid and about 45 to 75 percent by weight 2,2,4-trimethyl-1,3-pentanediol, and about 0 to 23 percent by weight 2-ethyl-2-(hydroxymethyl)-1,3-propanediol, various mixtures of ethylenically unsaturated monomer(s) can be used. The percents by weight are based on total weight of the substantially hydrophobic polyester mixtures of ethylenically unsaturated monomer(s). These are particularized into microparticles by high-stress techniques followed by polymerizing the polymerizable species to form the polymeric microparticles which are stably dispersed in the aqueous medium.