公开(公告)号：US07101930B2

公开(公告)日：2006-09-05

申请号：US10887626

申请日：2004-07-09

Applicant: Roxalana L. Martin ,  Edward R. Coleridge ,  Mark A. Tucker ,  Mary E. Grolemund

Inventor： Roxalana L. Martin ,  Edward R. Coleridge ,  Mark A. Tucker ,  Mary E. Grolemund

IPC: C08J3/00

CPC classification number: C09D201/02 ,  C08F8/00 ,  Y10T428/31504 ,  Y10T428/31855 ,  C08F10/00 ,  C08F20/00

Abstract: A curable, aqueous film-forming composition is provided that includes a polymeric binder comprising reactive functional groups, a crosslinking agent having at least two functional groups that are reactive with the functional groups of the polymeric binder, and a copolymer flow control agent comprising at least 30 mol % of residues containing alternating residues from a donor monomer and from an acceptor monomer. The copolymer contains at least 15 mol % of an isobutylene type donor monomer. Components (a) and (b) are substantially hydrophobic and are prepared as an aqueous dispersion comprising polymeric microparticles, prepared by mixing components (a) and (b) together under high shear conditions.A multi-component composite coating composition is also provided, comprising a base coat deposited from a pigmented film-forming composition and a transparent topcoat applied over the base coat. The topcoat is deposited from the film-forming composition described above.

Abstract translation: 提供了一种可固化的水性成膜组合物，其包括含有反应性官能团的聚合物粘合剂，具有至少两个与聚合物粘合剂的官能团反应的官能团的交联剂，以及至少包含共聚物流动控制剂 30mol％的残余物含有来自供体单体和受体单体的交替残基。 共聚物含有至少15摩尔％的异丁烯型供体单体。 组分（a）和（b）基本上是疏水性的，并且被制备成包含通过在高剪切条件下将组分（a）和（b）混合在一起而制备的聚合物微粒的水分散体。 还提供了一种多组分复合涂料组合物，其包含由着色成膜组合物沉积的底涂层和涂覆在底涂层上的透明面漆。 面漆从上述成膜组合物沉积。

公开(公告)号：US07183355B2

公开(公告)日：2007-02-27

申请号：US10928803

申请日：2004-08-27

Applicant: Roxalana L. Martin ,  Edward R. Coleridge ,  Mark A. Tucker ,  Mary E. Grolemund

Inventor： Roxalana L. Martin ,  Edward R. Coleridge ,  Mark A. Tucker ,  Mary E. Grolemund

IPC: C08F8/30

CPC classification number: B05D7/57 ,  B05D1/007 ,  B05D3/0209 ,  B05D3/067 ,  B05D7/53 ,  C08F8/00 ,  C08F210/10 ,  C08F220/10 ,  C08F290/046 ,  C08G18/6229 ,  C08G18/792 ,  C08G18/798 ,  C08G18/8025 ,  C08G18/807 ,  C08G18/8074 ,  C08G2150/20 ,  C09D123/22 ,  C09D133/062 ,  C09D133/14 ,  Y10T428/31938 ,  C08F210/00 ,  C08F220/12 ,  C08L2666/28 ,  C08L2666/02 ,  C08L2666/14 ,  C08F212/00 ,  C08F220/00 ,  C08F2500/26 ,  C08F214/18 ,  C08F2500/03 ,  C08F2500/02 ,  C08F222/00

Abstract: A curable, aqueous film-forming composition is provided, comprising: (a) a copolymer containing reactive functional groups and comprising at least 30 mol % of residues having alternating structural units: -[DM-AM]- wherein DM represents a residue from a donor monomer, and AM represents a residue from an acceptor monomer, at least 15 mol % of the copolymer comprising a donor monomer having the structure (I): wherein R1 is linear or branched C1 to C4 alkyl, R2 is selected from methyl, linear, cyclic or branched C1 to C20 alkyl, alkenyl, aryl, alkaryl and aralkyl; and (b) a curing agent having functional groups reactive with the reactive functional groups of (a). The invention is also directed to a multi-component composite coating composition including a base coat deposited from a pigmented film-forming composition and a transparent topcoat applied over the base coat. At least one-coat is the film-forming composition described above.

Abstract translation: 提供了一种可固化的水性成膜组合物，其包含：（a）含有反应性官能团并且包含至少30mol％具有交替结构单元的残基的共聚物：<？in-line-formula description =“In-Line Formulas “end =”lead“？> - [DM-AM] - <？in-line-formula description =”In-line Formulas“end =”tail“？>其中DM表示来自供体单体的残基，AM表示 来自受主单体的残余物，至少15mol％的共聚物包含具有结构（I）的供体单体：其中R 1是直链或支链C 1至 C 4烷基，R 2选自甲基，直链，环状或支链C 1至C 20烷基 ，烯基，芳基，烷芳基和芳烷基; 和（b）具有与（a）的反应性官能团反应的官能团的固化剂。 本发明还涉及一种多组分复合涂料组合物，其包括从着色成膜组合物沉积的底涂层和涂覆在底涂层上的透明面漆。 至少一层是上述成膜组合物。

公开(公告)号：US06387997B1

公开(公告)日：2002-05-14

申请号：US09437617

申请日：1999-11-10

Applicant: Mary E. Grolemund ,  Masayuki Nakajima ,  Thomas R. Hockswender ,  Kurt G. Olson

Inventor： Mary E. Grolemund ,  Masayuki Nakajima ,  Thomas R. Hockswender ,  Kurt G. Olson

IPC: C08F28312

CPC classification number: C09D183/10 ,  C08F283/12 ,  C08G77/442 ,  C09D151/08

Abstract: An aqueous dispersion including polymeric microparticles which are prepared in a medium substantially free of organic solvent from a mixture of one or more reaction products of polymerizable, ethylenically unsaturated monomers, and one or more reactive organopolysiloxanes is provided. Pigmented film-forming compositions, curable compositions and topcoats of multi-component composite coating composition containing the above-described dispersions also are provided. The substantially solvent-free film-forming compositions of the invention are storage stable at room temperature and provide coatings with excellent application properties such as sag resistance and tack-free overspray, and excellent performance properties such as hardness and scratch resistance. The film-forming compositions are suitable for wet-on-wet application over a base coat with little or no mudcracking.

Abstract translation: 提供了包含聚合物微粒的水分散体，其在基本上不含有机溶剂的介质中由可聚合的烯属不饱和单体和一种或多种反应性有机聚硅氧烷的一种或多种反应产物的混合物制备。 还提供了含有上述分散体的着色成膜组合物，可固化组合物和多组分复合涂料组合物的面漆。 本发明的基本上无溶剂的成膜组合物在室温下保存稳定，并提供具有优异应用性能的涂料，例如耐下落性和无粘性的过喷，以及优异的性能如硬度和耐刮擦性。 成膜组合物适用于湿法湿法施涂于基底涂层上，很少或没有泥浆破裂。

公开(公告)号：US06329060B1

公开(公告)日：2001-12-11

申请号：US09437796

申请日：1999-11-10

Applicant: Karen A. Barkac ,  Dennis Leroy Faler ,  Mary E. Grolemund ,  Debra Lynn Singer

Inventor： Karen A. Barkac ,  Dennis Leroy Faler ,  Mary E. Grolemund ,  Debra Lynn Singer

IPC: B32B2708

CPC classification number: C09D167/07 ,  C08G18/4615 ,  C08G18/6254 ,  C08G18/631 ,  C08G18/672 ,  C08G18/8077 ,  C09D4/06 ,  C09D175/04 ,  Y10T428/31551 ,  Y10T428/31554 ,  Y10T428/31786 ,  Y10T428/31855 ,  Y10T428/31909 ,  C08G18/42 ,  C08F283/02 ,  C08L2666/02 ,  C08L2666/16

Abstract: A multi-component composite coating composition is provided which includes a pigmented base coat and a transparent topcoat composition applied over the base coat. The transparent topcoat is deposited from a substantially solvent free film-forming composition which includes a thermosettable dispersion of polymeric microparticles having functionality adapted to react with a crosslinking agent and a hydrophilic crosslinking agent reactive with the functionality of the microparticles. The microparticles are prepared from one or more reaction products of ethylenically unsaturated monomers, one or more hydrophobic polymers and one or more hydrophobic crosslinking agents. Pigmented film-forming compositions as well as curable compositions containing the above-described dispersions also are provided. A method of forming the dispersion of polymeric microparticles is provided. The substantially solvent-free film-forming compositions of the invention are storage stable at room temperature and provide coatings with excellent application properties such as sag resistance and tack-free overspray, and excellent performance properties such as chip resistance and adhesion. The film-forming compositions are suitable for wet-on-wet application over a base coat with little or no mudcracking.

Abstract translation: 提供了一种多组分复合涂料组合物，其包括着色底涂层和涂覆在底涂层上的透明面漆组合物。 透明面漆由基本上无溶剂的成膜组合物沉积，该组合物包括具有适于与交联剂反应的官能团的聚合物微粒的可热分散分散体和与微粒官能度反应的亲水性交联剂。 微粒由烯属不饱和单体，一种或多种疏水性聚合物和一种或多种疏水性交联剂的一种或多种反应产物制备。 还提供了着色成膜组合物以及含有上述分散体的可固化组合物。 提供了形成聚合物微粒分散体的方法。 本发明的基本上无溶剂的成膜组合物在室温下保存稳定，并提供具有优异应用性能的涂层，例如抗流挂性和无粘性过喷，以及优异的性能特性如耐芯片性和粘合性。 成膜组合物适用于湿法湿法施涂于基底涂层上，很少或没有泥浆破裂。

公开(公告)号：US06803413B2

公开(公告)日：2004-10-12

申请号：US10358041

申请日：2003-02-04

Applicant: Roxalana L. Martin ,  Edward R. Coleridge ,  Mark A. Tucker ,  Mary E. Grolemund

Inventor： Roxalana L. Martin ,  Edward R. Coleridge ,  Mark A. Tucker ,  Mary E. Grolemund

IPC: C08L6300

CPC classification number: B05D7/57 ,  B05D1/007 ,  B05D3/0209 ,  B05D3/067 ,  B05D7/53 ,  C08F8/00 ,  C08F210/10 ,  C08F220/10 ,  C08F290/046 ,  C08G18/6229 ,  C08G18/792 ,  C08G18/798 ,  C08G18/8025 ,  C08G18/807 ,  C08G18/8074 ,  C08G2150/20 ,  C08L33/068 ,  C09D123/22 ,  C09D133/062 ,  C09D133/08 ,  Y10T428/31504 ,  Y10T428/31511 ,  C08F220/00 ,  C08F220/12 ,  C08F210/00 ,  C08L2666/28 ,  C08L2666/02 ,  C08F214/18 ,  C08F2500/03 ,  C08F2500/02 ,  C08F212/00 ,  C08F222/00 ,  C08F2500/26 ,  C08L2666/04

Abstract: A curable, aqueous film-forming composition is provided, comprising: (a) a copolymer containing reactive functional groups and comprising at least 30 mol % of residues having alternating structural units: —[DM—AM]— wherein DM represents a residue from a donor monomer, and AM represents a residue from an acceptor monomer, at least 15 mol % of the copolymer comprising a donor monomer having the structure (I): wherein R1 is linear or branched C1 to C4 alkyl, R2 is selected from methyl, linear, cyclic or branched C1 to C20 alkyl, alkenyl, aryl, alkaryl and aralkyl; and (b) a curing agent having functional groups reactive with the reactive functional groups of (a). The invention is also directed to a multi-component composite coating composition including a base coat deposited from a pigmented film-forming composition and a transparent topcoat applied over the base coat. At least one coat is the film-forming composition described above.

Abstract translation: 提供了一种可固化的水性成膜组合物，其包含：（a）含有反应性官能团并含有至少30mol％具有交替结构单元的残基的共聚物：其中DM表示来自供体单体的残基，AM表示 来自受主单体的残基，至少15mol％的共聚物包含具有结构（I）的供体单体：其中R 1是直链或支链C1至C4烷基，R 2选自甲基，直链， 环状或支链C 1至C 20烷基，烯基，芳基，烷芳基和芳烷基; 和（b）具有与（a）的反应性官能团反应的官能团的固化剂。本发明还涉及一种多组分复合涂料组合物，其包括由着色成膜组合物沉积的底漆和透明面漆 涂在底漆上。 至少一层是上述成膜组合物。

公开(公告)号：US06787597B1

公开(公告)日：2004-09-07

申请号：US10357797

申请日：2003-02-04

Applicant: Roxalana L. Martin ,  Edward R. Coleridge ,  Mark A. Tucker ,  Mary E. Grolemund

Inventor： Roxalana L. Martin ,  Edward R. Coleridge ,  Mark A. Tucker ,  Mary E. Grolemund

IPC: C08J300

CPC classification number: C09D201/02 ,  C08F8/00 ,  C08F10/00 ,  C08F20/00

Abstract: A curable, aqueous film-forming composition is provided that includes a polymeric binder comprising reactive functional groups, a crosslinking agent having at least two functional groups that are reactive with the functional groups of the polymeric binder, and a copolymer flow control agent comprising at least 30 mol % of residues containing alternating residues from a donor monomer and from an acceptor monomer. The copolymer contains at least 15 mol % of an isobutylene type donor monomer. A multi-component composite coating composition is also provided, comprising a base coat deposited from a pigmented film-forming composition and a transparent topcoat applied over the base coat. The topcoat is deposited from the film-forming composition described above.

Abstract translation: 提供了一种可固化的水性成膜组合物，其包括含有反应性官能团的聚合物粘合剂，具有至少两个与聚合物粘合剂的官能团反应的官能团的交联剂，以及至少包含共聚物流动控制剂 30mol％的残余物含有来自供体单体和受体单体的交替残基。 共聚物含有至少15摩尔％的异丁烯型供体单体。还提供了一种多组分复合涂料组合物，其包含从着色成膜组合物沉积的底涂层和涂覆在底涂层上的透明面漆。 面漆从上述成膜组合物沉积。