Functionalized polymers, articles prepared therefrom, and methods for making the same
    1.
    发明授权
    Functionalized polymers, articles prepared therefrom, and methods for making the same 有权
    官能化聚合物,由其制备的制品及其制备方法

    公开(公告)号:US09000099B2

    公开(公告)日:2015-04-07

    申请号:US12669194

    申请日:2008-07-10

    摘要: The invention provides compositions comprising at least one propylene-based polymer, at least one peroxide and at least one coagent. In a preferred example, a composition comprising at least one propylene-based polymer, at least one peroxide, at least one grafting agent, and at least one coagent, and wherein the at least one coagent has a substituted carbon-carbon double bond structure selected from the group consisting of structures (I), (II), (III), (IV) and (V) as follows, including cis and trans isomers wherein D1, D2, D3 and D4 are each, independently, one of the following: (a) a hydrocarbon substituent containing a heteroatom with a nonbonding pair of electrons, and where the heteroatom with the nonbonding pair is directly attached to the carbon-carbon double bond, or (b) a hydrocarbon substituent containing a carbon-carbon pi bonding pair, and where the first carbon of the carbon-carbon pi bonding pair is directly bonded to the carbon-carbon double bond; and wherein the R1, R2 and R3 are each, independently, H, a hydrocarbon substituent, or a substituted hydrocarbon substituent; and wherein R1, R2 and R3, each, independently, does not have the same chemical structure as D1, D2, D3 or D4; and wherein the molar ratio of the “coagent(s)” to “free radicals formed from the peroxide(s)” is from 0.5:1 to 5:1; and wherein the coagent selected from structures (I)-(V) does not contain only one phenyl group, or does not contain only one furyl group.

    摘要翻译: 本发明提供了包含至少一种基于丙烯的聚合物,至少一种过氧化物和至少一种助剂的组合物。 在优选实例中,包含至少一种基于丙烯的聚合物,至少一种过氧化物,至少一种接枝剂和至少一种助剂的组合物,并且其中所述至少一种助剂具有取代的碳 - 碳双键结构 包括由以下结构(I),(II),(III),(IV)和(V)组成的组,包括顺式和反式异构体,其中D1,D2,D3和D4各自独立地为以下之一 (a)含有具有非键合电子对的杂原子的烃取代基,其中与非键合对的杂原子直接连接到碳 - 碳双键上,或(b)含有碳 - 碳键的烃取代基 并且其中碳 - 碳π键合对的第一个碳直接键合到碳 - 碳双键上; 并且其中R 1,R 2和R 3各自独立地为H,烃取代基或取代的烃取代基; 并且其中R1,R2和R3各自独立地不具有与D1,D2,D3或D4相同的化学结构; 并且其中“助剂”与“由过氧化物形成的自由基”的摩尔比为0.5:1至5:1; 并且其中选自结构(I) - (V)的助剂不仅含有一个苯基,或不含有一个呋喃基。

    CROSSLINKED FIBERS OR OTHER ARTICLES MADE FROM POLYOLEFIN ELASTOMERS
    2.
    发明申请
    CROSSLINKED FIBERS OR OTHER ARTICLES MADE FROM POLYOLEFIN ELASTOMERS 审中-公开
    交联纤维或其他文章从聚烯烃弹性体制造

    公开(公告)号:US20110187018A1

    公开(公告)日:2011-08-04

    申请号:US12946579

    申请日:2010-11-15

    IPC分类号: D01D5/00 C08L51/06 C08L53/00

    CPC分类号: C08L51/06 C08L53/00 D01D5/00

    摘要: The invention relates to an improved process for controlling the amount of crosslinking in polyolefin based articles such as fibers or films. The invention relates to mixing silane grafted material together with ungrafted material prior to crosslinking. The article can then be formed and cured, optionally with a curing catalyst which can preferably be applied to the surface of a shaped article. The amount of crosslinking will be controlled in part by the level of silane grafting on the grafted silane material as well as the amount of the grafted material in the blend.

    摘要翻译: 本发明涉及用于控制聚烯烃基制品如纤维或薄膜中的交联量的改进方法。 本发明涉及在交联之前将硅烷接枝材料与未接枝的材料混合。 然后可以任选地使用固化催化剂来形成和固化该制品,该固化催化剂可以优选地施加到成型制品的表面上。 交联量将部分地由接枝硅烷材料上的硅烷接枝水平以及共混物中接枝材料的量来控制。

    SILANE MOISTURE CURED HEAT RESISTANT FIBERS MADE FROM POLYOLEFIN ELASTOMERS
    4.
    发明申请
    SILANE MOISTURE CURED HEAT RESISTANT FIBERS MADE FROM POLYOLEFIN ELASTOMERS 审中-公开
    来自聚烯烃弹性体的硅烷水溶固化耐热纤维

    公开(公告)号:US20090264584A1

    公开(公告)日:2009-10-22

    申请号:US12481895

    申请日:2009-06-10

    IPC分类号: C08K5/14 C08F255/00

    摘要: An improved process for crosslinking a polyolefin polymer is described. The process involves grafting a silane material onto the polyolefin based polymer in the presence of a free radical generating initiator material and then hydrolyzing the silane material to form crosslinks. By using an effective molar ratio of silane material to free radical of 40 or greater in the grafting reaction, premature crosslinking is controlled and the grafted polymer can be shaped first and then crosslinked. In another aspect of the invention, the crosslinking process is improved by adding a catalyst for the hydrolysis catalyst to the surface of a shaped article made from the grafted polymer. Grafted polymer and articles made from the grafted polymer, particularly fibers, are also disclosed.

    摘要翻译: 描述了一种交联聚烯烃聚合物的改进方法。 该方法包括在产生自由基的引发剂材料的存在下将硅烷材料接枝到聚烯烃基聚合物上,然后水解硅烷材料以形成交联。 通过在接枝反应中使用硅烷材料与自由基的自由基的有效摩尔比为40以上,控制过早交联,接枝聚合物首先被成型然后交联。 在本发明的另一方面,通过向由接枝聚合物制成的成型制品的表面添加用于水解催化剂的催化剂来改善交联过程。 接枝聚合物和由接枝聚合物,特别是纤维制成的制品也被公开。

    Optical sensor system and method for monitoring consumables
    5.
    发明授权
    Optical sensor system and method for monitoring consumables 失效
    光学传感器系统和消耗品监控方法

    公开(公告)号:US06271523B1

    公开(公告)日:2001-08-07

    申请号:US09520708

    申请日:2000-03-07

    IPC分类号: G08S2300

    摘要: An optical sensor for monitoring a utility meter having a sweep hand indicator that moves over a meter surface of the utility meter. The optical sensor has a single infrared light emitter and two photo diodes detectors. The infrared light emitter is positioned at an angle with respect the meter surface and the sweep hand indicator of the utility meter so that the sweep hand indicator is illuminated from an angle to provide a shadow of the sweep hand indicator. The photo detectors detect changes in the intensity of light reflected on the sweep hand indicator and the background surface as well as the shadow of the sweep hand indicator. The two photo diode detectors are electrically coupled in series but in opposite directions relative to an output node, so as to cancel each other at the output node in normal operation. The passing of the sweep hand indicator changes the signal produced of each of the photo diode detectors at the output node, independently but in opposite directions.

    摘要翻译: 一种光学传感器,用于监测具有在公用事业仪表的仪表表面上移动的扫掠指示器的公用事业仪表。 光学传感器具有单个红外光发射器和两个光电二极管检测器。 红外光发射器相对于仪表表面和效用表的扫掠指示器定位成一角度,使得扫掠指示器从一角度照亮以提供扫掠指示器的阴影。 光检测器检测扫描指示器和背景表面上反射的光强度以及扫描指示器的阴影的变化。 两个光电二极管检测器相对于输出节点串联电耦合在相反的方向上,以便在正常操作中在输出节点彼此抵消。 扫掠指示器的通过将输出节点上的每个光电二极管检测器产生的信号独立地但相反地改变。

    Ion-exchange polymers having an expanded microstructure
    6.
    发明授权
    Ion-exchange polymers having an expanded microstructure 失效
    具有扩展微结构的离子交换聚合物

    公开(公告)号:US6011074A

    公开(公告)日:2000-01-04

    申请号:US17444

    申请日:1998-02-02

    IPC分类号: C08F8/44 C08J5/22 C02F1/44

    摘要: Novel organic ion-exchange polymers and membranes formed from these polymers provide improved performance in electrolytic cells. The membranes exhibit an expanded micro-structure as the result of the removal of organic groups previously reacted with the ion-exchange groups of the polymer. The polymers are also useful in finely divided form as catalysts or deposited on a catalyst support. When formed into sheets, the polymers are useful as membranes in the separation of miscible liquids and in the separation of gases.

    摘要翻译: 由这些聚合物形成的新型有机离子交换聚合物和膜在电解槽中提供了改进的性能。 作为除去预先与聚合物的离子交换基团反应的有机基团的结果,膜表现出膨胀的微结构。 聚合物也可以细分形式用作催化剂或沉积在催化剂载体上。 当形成片材时,聚合物可用作分离可混溶液体和分离气体中的膜。

    X-ray generator cooling system
    8.
    发明授权
    X-ray generator cooling system 失效
    X射线发生器冷却系统

    公开(公告)号:US4767961A

    公开(公告)日:1988-08-30

    申请号:US537546

    申请日:1983-10-03

    CPC分类号: H01J35/12 H05G1/025 H05G1/04

    摘要: An X-ray generator system comprising a pressurized fluid source disposed for directing dielectric coolant fluid through a housing wherein an X-ray source may be electrically connected for generating X-rays, the system including a venturi device having a restricted passage through which the fluid flows and which is disposed in communication with portions of the housing where gas bubbles may accumulate in the fluid. Thus, the fluid flowing through the restricted passage of the venturi device produces a reduction in pressure which draws fluid from said portions of the housing so that any gas bubbles accumulated therein may be purged from the system.

    摘要翻译: 一种X射线发生器系统,包括被设置用于引导电介质冷却剂流体通过壳体的加压流体源,其中X射线源可以电连接以产生X射线,该系统包括具有限制通道的文氏管装置,流体 流动并且与壳体的其中气泡可能积聚在流体中的部分相连通。 因此,流过文氏管装置的限制通道的流体产生压力的降低,其从壳体的所述部分抽吸流体,使得积聚在其中的任何气泡可以从系统中清除。