公开(公告)号：US08188153B2

公开(公告)日：2012-05-29

申请号：US12718356

申请日：2010-03-05

申请人： Yong Wang ,  Anna Lee Tonkovich ,  Terry Mazanec ,  Francis P. Daly ,  Dave VanderWiel ,  Jianli Hu ,  Chunshe Cao ,  Charles Kibby ,  Xiaohong Shari Li ,  Michael D. Briscoe ,  Nathan Gano ,  Ya-Huei Chin

发明人： Yong Wang ,  Anna Lee Tonkovich ,  Terry Mazanec ,  Francis P. Daly ,  Dave VanderWiel ,  Jianli Hu ,  Chunshe Cao ,  Charles Kibby ,  Xiaohong Shari Li ,  Michael D. Briscoe ,  Nathan Gano ,  Ya-Huei Chin

IPC分类号： C07C27/00 ,  B01J8/00

CPC分类号： C10G2/332 ,  B01J19/0093 ,  B01J21/04 ,  B01J23/75 ,  B01J23/8896 ,  B01J23/8913 ,  B01J35/0066 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J37/0205 ,  B01J2219/00783 ,  B01J2219/00822 ,  B01J2219/00824 ,  B01J2219/00826 ,  B01J2219/00831 ,  B01J2219/00835 ,  B01J2219/00844 ,  B01J2219/0086 ,  B01J2219/00873 ,  C10G2/341 ,  C10G2300/301 ,  C10G2300/4018 ,  C10G2300/4025 ,  C10G2300/70 ,  C10G2400/04 ,  C10G2400/10 ,  Y02P20/582

摘要： The disclosed invention relates to a process for converting a reactant composition comprising H2 and CO to a product comprising at least one aliphatic hydrocarbon having at least about 5 carbon atoms, the process comprising: flowing the reactant composition through a microchannel reactor in contact with a Fischer-Tropsch catalyst to convert the reactant composition to the product, the microchannel reactor comprising a plurality of process microchannels containing the catalyst; transferring heat from the process microchannels to a heat exchanger; and removing the product from the microchannel reactor; the process producing at least about 0.5 gram of aliphatic hydrocarbon having at least about 5 carbon atoms per gram of catalyst per hour; the selectivity to methane in the product being less than about 25%. The disclosed invention also relates to a supported catalyst comprising Co, and a microchannel reactor comprising at least one process microchannel and at least one adjacent heat exchange zone.

摘要翻译： 所公开的发明涉及将包含H 2和CO的反应物组合物转化为包含至少一种具有至少约5个碳原子的脂族烃的产物的方法，该方法包括：使反应物组合物流过与Fischer接触的微通道反应器 - 催化剂将反应物组合物转化成产物，微通道反应器包含多个含有催化剂的工艺微通道; 将热量从工艺微通道传递到热交换器; 并从微通道反应器中除去产物; 该方法每小时产生至少约0.5克具有至少约5个碳原子的每克催化剂的脂族烃; 产品中甲烷的选择性小于约25％。 所公开的发明还涉及包含Co的载体催化剂和包含至少一个工艺微通道和至少一个相邻的热交换区的微通道反应器。

公开(公告)号：US08062623B2

公开(公告)日：2011-11-22

申请号：US10966162

申请日：2004-10-15

申请人： Francis P. Daly ,  Junko M. Watson ,  Yong Wang ,  Jianli Hu ,  Chunshe Cao ,  Richard Long

发明人： Francis P. Daly ,  Junko M. Watson ,  Yong Wang ,  Jianli Hu ,  Chunshe Cao ,  Richard Long

IPC分类号： C01B3/26

CPC分类号： B01J19/0093 ,  B01J23/42 ,  B01J23/6567 ,  B01J35/0006 ,  B01J35/04 ,  B01J35/06 ,  B01J37/0225 ,  B01J37/0226 ,  B01J37/0238 ,  B01J2219/00783 ,  B01J2219/00822 ,  B01J2219/00835 ,  B01J2219/0086 ,  B01J2219/00873 ,  B01J2219/00889 ,  B01J2219/00891 ,  C01B3/384 ,  C01B3/386 ,  C01B2203/0233 ,  C01B2203/0261 ,  C01B2203/0811 ,  C01B2203/0822 ,  C01B2203/0827 ,  C01B2203/0844 ,  C01B2203/1041 ,  C01B2203/107 ,  C01B2203/1241 ,  C01B2203/141 ,  C01B2203/82 ,  F23C13/00 ,  F23C2900/03001 ,  Y02P20/128 ,  Y02P20/52

摘要： Catalysts containing 30 weight percent or more platinum have surprisingly been discovered to possess superior stability and activity for catalyzing combustion reactions. The addition of rhenium improves catalyst performance in fuel lean conditions but has undesirable effects in fuel rich conditions. The invention provides integrated combustion microreactors, chemical systems utilizing these integrated combustion microreactors, methods of combustion, and methods of providing heat to endothermic reactions in integrated combustion microreactors.

摘要翻译： 令人惊奇地发现含有30重量％或更多的铂的催化剂具有优异的催化燃烧反应的稳定性和活性。 添加铼提高了燃料贫乏条件下的催化剂性能，但在富燃料条件下具有不良影响。 本发明提供了综合燃烧微反应器，利用这些综合燃烧微反应器的化学系统，燃烧方法和向集成燃烧微反应器中的吸热反应提供热量的方法。

公开(公告)号：US20100160463A1

公开(公告)日：2010-06-24

申请号：US12718356

申请日：2010-03-05

申请人： Yong Wang ,  Anna Lee Tonkovich ,  Terry Mazanec ,  Francis P. Daly ,  Dave VanderWiel ,  Jianli Hu ,  Chunshe Cao ,  Charles Kibby ,  Xiaohong Shari Li ,  Michael D. Briscoe ,  Nathan Gano ,  Ya-Huei Chin

发明人： Yong Wang ,  Anna Lee Tonkovich ,  Terry Mazanec ,  Francis P. Daly ,  Dave VanderWiel ,  Jianli Hu ,  Chunshe Cao ,  Charles Kibby ,  Xiaohong Shari Li ,  Michael D. Briscoe ,  Nathan Gano ,  Ya-Huei Chin

IPC分类号： C07C1/04 ,  B01J8/02

CPC分类号： C10G2/332 ,  B01J19/0093 ,  B01J21/04 ,  B01J23/75 ,  B01J23/8896 ,  B01J23/8913 ,  B01J35/0066 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J37/0205 ,  B01J2219/00783 ,  B01J2219/00822 ,  B01J2219/00824 ,  B01J2219/00826 ,  B01J2219/00831 ,  B01J2219/00835 ,  B01J2219/00844 ,  B01J2219/0086 ,  B01J2219/00873 ,  C10G2/341 ,  C10G2300/301 ,  C10G2300/4018 ,  C10G2300/4025 ,  C10G2300/70 ,  C10G2400/04 ,  C10G2400/10 ,  Y02P20/582

摘要： The disclosed invention relates to a process for converting a reactant composition comprising H2 and CO to a product comprising at least one aliphatic hydrocarbon having at least about 5 carbon atoms, the process comprising: flowing the reactant composition through a microchannel reactor in contact with a Fischer-Tropsch catalyst to convert the reactant composition to the product, the microchannel reactor comprising a plurality of process microchannels containing the catalyst; transferring heat from the process microchannels to a heat exchanger; and removing the product from the microchannel reactor; the process producing at least about 0.5 gram of aliphatic hydrocarbon having at least about 5 carbon atoms per gram of catalyst per hour; the selectivity to methane in the product being less than about 25%. The disclosed invention also relates to a supported catalyst comprising Co, and a microchannel reactor comprising at least one process microchannel and at least one adjacent heat exchange zone.

摘要翻译： 所公开的发明涉及将包含H 2和CO的反应物组合物转化为包含至少一种具有至少约5个碳原子的脂族烃的产物的方法，该方法包括：使反应物组合物流过与Fischer接触的微通道反应器 - 催化剂将反应物组合物转化成产物，微通道反应器包含多个含有催化剂的工艺微通道; 将热量从工艺微通道传递到热交换器; 并从微通道反应器中除去产物; 该方法每小时产生至少约0.5克具有至少约5个碳原子的每克催化剂的脂族烃; 产品中甲烷的选择性小于约25％。 所公开的发明还涉及包含Co的载体催化剂和包含至少一个工艺微通道和至少一个相邻的热交换区的微通道反应器。

公开(公告)号：US07425657B1

公开(公告)日：2008-09-16

申请号：US11759075

申请日：2007-06-06

申请人： Douglas C. Elliott ,  Jianli Hu ,  Todd R. Hart ,  Gary G. Neuenschwander

发明人： Douglas C. Elliott ,  Jianli Hu ,  Todd R. Hart ,  Gary G. Neuenschwander

IPC分类号： C07C41/48 ,  C07C41/50 ,  C07C33/03 ,  C07C31/18

CPC分类号： C07C29/172 ,  B01J21/18 ,  B01J23/44 ,  B01J23/462 ,  B01J37/0201 ,  C07C29/149 ,  C07C2601/08 ,  C07C2601/14 ,  C07D307/06 ,  C10G1/00 ,  C10G1/06 ,  C10G1/086 ,  C10G3/47 ,  C10G3/48 ,  C10G3/50 ,  C10G2300/1014 ,  C10G2300/4018 ,  Y02E50/14 ,  Y02E50/32 ,  Y02P20/52 ,  Y02P30/20 ,  C07C35/14 ,  C07C35/08 ,  C07C31/04 ,  C07C31/08 ,  C07C31/20 ,  C07C31/125 ,  C07C35/06

摘要： The invention provides palladium-catalyzed hydrogenations of bio-oils and certain organic compounds. Experimental results have shown unexpected and superior results for palladium-catalyzed hydrogenations of organic compounds typically found in bio-oils.

摘要翻译： 本发明提供钯催化的生物油和某些有机化合物的氢化。 实验结果已经显示出对于通常在生物油中发现的有机化合物的钯催化氢化的意想不到的和优异的结果。

公开(公告)号：US20080103318A1

公开(公告)日：2008-05-01

申请号：US11932436

申请日：2007-10-31

申请人： Michael Lilga ,  Richard Hallen ,  Jianli Hu ,  James White ,  Michel Gray

发明人： Michael Lilga ,  Richard Hallen ,  Jianli Hu ,  James White ,  Michel Gray

IPC分类号： C07D307/68 ,  B01J21/06 ,  B01J23/42 ,  C07D307/46

CPC分类号： C07D307/48 ,  C07D307/44

摘要： A method of oxidizing hydroxymethylfurfural (HMF) includes providing a starting material which includes HMF in a solvent comprising water into a reactor. At least one of air and O2 is provided into the reactor. The starting material is contacted with the catalyst comprising Pt on a support material where the contacting is conducted at a reactor temperature of from about 50° C. to about 200° C. A method of producing an oxidation catalyst where ZrO2 is provided and is calcined. The ZrO2 is mixed with platinum (II) acetylacetonate to form a mixture. The mixture is subjected to rotary evaporation to form a product. The product is calcined and reduced under hydrogen to form an activated product. The activated product is passivated under a flow of 2% O2.

摘要翻译： 氧化羟甲基糠醛（HMF）的方法包括在包含水的溶剂中将包含HMF的原料提供到反应器中。 将空气和O 2 2中的至少一个提供到反应器中。 使起始材料与包含Pt的催化剂在载体材料上接触，其中在约50℃至约200℃的反应器温度下进行接触。一种制备氧化催化剂的方法，其中ZrO 2 / SUB>并被煅烧。 将ZrO 2 2与乙酰丙酮酸铂（II）混合以形成混合物。 将混合物进行旋转蒸发以形成产物。 将产物在氢气下煅烧和还原以形成活化产物。 活化产物在2％O 2 2的流下被钝化。

公开(公告)号：US07208136B2

公开(公告)日：2007-04-24

申请号：US10440448

申请日：2003-05-16

申请人： Jamelyn D. Holladay ,  Yong Wang ,  Jianli Hu ,  Ya-Huei Chin ,  Robert A. Dagle ,  Guanguang Xia ,  Eddie G. Baker ,  Daniel R. Palo ,  Max R. Phelps ,  Heon Jung

发明人： Jamelyn D. Holladay ,  Yong Wang ,  Jianli Hu ,  Ya-Huei Chin ,  Robert A. Dagle ,  Guanguang Xia ,  Eddie G. Baker ,  Daniel R. Palo ,  Max R. Phelps ,  Heon Jung

IPC分类号： C01B3/26 ,  B01J23/60 ,  B01J23/44 ,  B01J23/42 ,  B01J23/00

CPC分类号： C01B3/326 ,  B01J19/0093 ,  B01J21/04 ,  B01J23/60 ,  B01J35/002 ,  B01J37/0201 ,  B01J2219/00783 ,  B01J2219/00788 ,  B01J2219/00822 ,  B01J2219/00824 ,  B01J2219/00835 ,  B01J2219/00862 ,  B01J2219/00873 ,  B01J2219/00891 ,  B01J2219/00961 ,  B01J2219/00997 ,  C01B3/586 ,  C01B2203/0233 ,  C01B2203/0445 ,  C01B2203/047 ,  C01B2203/1041 ,  C01B2203/1064 ,  C01B2203/1223 ,  Y02P20/52

摘要： The present invention provides steam reforming catalyst compositions containing Pd and Zn, and methods of steam reforming alcohols over a catalyst. Surprisingly superior results and properties of the present invention, including low temperature activity and/or low carbon monoxide output, are also described. Methods of making a steam reforming catalyst are also provided.

摘要翻译： 本发明提供含有Pd和Zn的蒸汽重整催化剂组合物，以及在催化剂上蒸汽重整醇的方法。 还描述了包括低温活性和/或低一氧化碳输出的本发明的令人惊奇的优异结果和性质。 还提供了制备蒸汽重整催化剂的方法。

公开(公告)号：US20060083675A1

公开(公告)日：2006-04-20

申请号：US10966162

申请日：2004-10-15

申请人： Francis Daly ,  Junko Watson ,  Yong Wang ,  Jianli Hu ,  Chunshe Cao ,  Richard Long

发明人： Francis Daly ,  Junko Watson ,  Yong Wang ,  Jianli Hu ,  Chunshe Cao ,  Richard Long

IPC分类号： C01B3/26 ,  B01J8/02

CPC分类号： B01J19/0093 ,  B01J23/42 ,  B01J23/6567 ,  B01J35/0006 ,  B01J35/04 ,  B01J35/06 ,  B01J37/0225 ,  B01J37/0226 ,  B01J37/0238 ,  B01J2219/00783 ,  B01J2219/00822 ,  B01J2219/00835 ,  B01J2219/0086 ,  B01J2219/00873 ,  B01J2219/00889 ,  B01J2219/00891 ,  C01B3/384 ,  C01B3/386 ,  C01B2203/0233 ,  C01B2203/0261 ,  C01B2203/0811 ,  C01B2203/0822 ,  C01B2203/0827 ,  C01B2203/0844 ,  C01B2203/1041 ,  C01B2203/107 ,  C01B2203/1241 ,  C01B2203/141 ,  C01B2203/82 ,  F23C13/00 ,  F23C2900/03001 ,  Y02P20/128 ,  Y02P20/52

摘要： Catalysts containing 30 weight percent or more platinum have surprisingly been discovered to possess superior stability and activity for catalyzing combustion reactions. The addition of rhenium improves catalyst performance in fuel lean conditions but has undesirable effects in fuel rich conditions. The invention provides integrated combustion microreactors, chemical systems utilizing these integrated combustion microreactors, methods of combustion, and methods of providing heat to endothermic reactions in integrated combustion microreactors.

摘要翻译： 令人惊奇地发现含有30重量％或更多的铂的催化剂具有优异的催化燃烧反应的稳定性和活性。 添加铼提高了燃料贫乏条件下的催化剂性能，但在富燃料条件下具有不良影响。 本发明提供了综合燃烧微反应器，利用这些综合燃烧微反应器的化学系统，燃烧方法和向集成燃烧微反应器中的吸热反应提供热量的方法。

公开(公告)号：US20050165121A1

公开(公告)日：2005-07-28

申请号：US10766297

申请日：2004-01-28

申请人： Yong Wang ,  Anna Tonkovich ,  Terry Mazanec ,  Francis Daly ,  Dave VanderWiel ,  Jianli Hu ,  Chunshe Cao ,  Charles Kibby ,  Xiaohong Li ,  Michael Briscoe ,  Nathan Gano ,  Ya-Huei Chin

发明人： Yong Wang ,  Anna Tonkovich ,  Terry Mazanec ,  Francis Daly ,  Dave VanderWiel ,  Jianli Hu ,  Chunshe Cao ,  Charles Kibby ,  Xiaohong Li ,  Michael Briscoe ,  Nathan Gano ,  Ya-Huei Chin

IPC分类号： B01J19/00 ,  B01J19/24 ,  B01J21/04 ,  B01J23/75 ,  B01J23/889 ,  B01J23/89 ,  B01J35/10 ,  B01J37/02 ,  C10G2/00 ,  C07C27/26

CPC分类号： C10G2/332 ,  B01J19/0093 ,  B01J21/04 ,  B01J23/75 ,  B01J23/8896 ,  B01J23/8913 ,  B01J35/0066 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J37/0205 ,  B01J2219/00783 ,  B01J2219/00822 ,  B01J2219/00824 ,  B01J2219/00826 ,  B01J2219/00831 ,  B01J2219/00835 ,  B01J2219/00844 ,  B01J2219/0086 ,  B01J2219/00873 ,  C10G2/341 ,  C10G2300/301 ,  C10G2300/4018 ,  C10G2300/4025 ,  C10G2300/70 ,  C10G2400/04 ,  C10G2400/10 ,  Y02P20/582

摘要： The disclosed invention relates to a process for converting a reactant composition comprising H2 and CO to a product comprising at least one aliphatic hydrocarbon having at least about 5 carbon atoms, the process comprising: flowing the reactant composition through a microchannel reactor in contact with a Fischer-Tropsch catalyst to convert the reactant composition to the product, the microchannel reactor comprising a plurality of process microchannels containing the catalyst; transferring heat from the process microchannels to a heat exchanger; and removing the product from the microchannel reactor; the process producing at least about 0.5 gram of aliphatic hydrocarbon having at least about 5 carbon atoms per gram of catalyst per hour; the selectivity to methane in the product being less than about 25%. The disclosed invention also relates to a supported catalyst comprising Co, and a microchannel reactor comprising at least one process microchannel and at least one adjacent heat exchange zone.

摘要翻译： 所公开的发明涉及将包含H 2 CO和CO的反应物组合物转化成包含至少一种具有至少约5个碳原子的脂族烃的产物的方法，该方法包括：使反应物组合物通过 与费 - 托催化剂接触以将反应物组合物转化成产物的微通道反应器，该微通道反应器包含多个含有该催化剂的工艺微通道; 将热量从工艺微通道传递到热交换器; 并从微通道反应器中除去产物; 该方法每小时产生至少约0.5克具有至少约5个碳原子的每克催化剂的脂族烃; 产品中甲烷的选择性小于约25％。 所公开的发明还涉及包含Co的载体催化剂和包含至少一个工艺微通道和至少一个相邻的热交换区的微通道反应器。

公开(公告)号：US20100152470A1

公开(公告)日：2010-06-17

申请号：US12712100

申请日：2010-02-24

申请人： Michael A. Lilga ,  Richard T. Hallen ,  Jianli Hu ,  James F. White ,  Michel J. Gray

发明人： Michael A. Lilga ,  Richard T. Hallen ,  Jianli Hu ,  James F. White ,  Michel J. Gray

IPC分类号： C07D307/46

CPC分类号： C07D307/48 ,  C07D307/44

摘要： A method of oxidizing hydroxymethylfurfural (HMF) includes providing a starting material which includes HMF in a solvent comprising water into a reactor. At least one of air and O2 is provided into the reactor. The starting material is contacted with the catalyst comprising Pt on a support material where the contacting is conducted at a reactor temperature of from about 50° C. to about 200° C. A method of producing an oxidation catalyst where ZrO2 is provided and is calcined. The ZrO2 is mixed with platinum (II) acetylacetonate to form a mixture. The mixture is subjected to rotary evaporation to form a product. The product is calcined and reduced under hydrogen to form an activated product. The activated product is passivated under a flow of 2% O2.

公开(公告)号：US07585472B2

公开(公告)日：2009-09-08

申请号：US10434443

申请日：2003-05-07

申请人： Jamelyn D. Holladay ,  Yong Wang ,  Jianli Hu ,  Ya-Huei Chin ,  Robert A. Dagle ,  Guanguang Xia ,  Eddie G. Baker ,  Daniel R. Palo ,  Max Phelps ,  Heon Jung

发明人： Jamelyn D. Holladay ,  Yong Wang ,  Jianli Hu ,  Ya-Huei Chin ,  Robert A. Dagle ,  Guanguang Xia ,  Eddie G. Baker ,  Daniel R. Palo ,  Max Phelps ,  Heon Jung

IPC分类号： B01J8/04

CPC分类号： F23C13/00 ,  B01J19/0093 ,  B01J21/04 ,  B01J21/066 ,  B01J23/60 ,  B01J23/63 ,  B01J37/03 ,  B01J2219/00783 ,  B01J2219/00833 ,  B01J2219/00835 ,  B01J2219/00873 ,  B01J2219/00891 ,  C01B3/323 ,  C01B3/384 ,  C01B2203/00 ,  C01B2203/0233 ,  C01B2203/04 ,  C01B2203/0445 ,  C01B2203/047 ,  C01B2203/066 ,  C01B2203/0811 ,  C01B2203/0816 ,  C01B2203/0822 ,  C01B2203/0827 ,  C01B2203/1011 ,  C01B2203/1052 ,  C01B2203/1064 ,  C01B2203/1076 ,  C01B2203/1082 ,  C01B2203/1217 ,  C01B2203/1223 ,  C01B2203/1288 ,  C01B2203/1619 ,  F23C2900/03001 ,  Y02P20/128 ,  Y02P20/52

摘要： The invention describes combustors and steam reformers and methods of combustion and steam reforming. For example, integrated combustion reactors are described in which heat from combustion is transferred to an endothermic reaction. Thermally efficient reactors and methods of alcohol steam reforming are also described. Also described is an integrated combustor/reformer containing a methanation catalyst.

摘要翻译： 本发明描述了燃烧器和蒸汽重整器以及燃烧和蒸汽重整的方法。 例如，描述了将来自燃烧的热转移到吸热反应的综合燃烧反应器。 还描述了热效率的反应器和醇蒸汽重整的方法。 还描述了含有甲烷化催化剂的一体化燃烧器/重整器。