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    Bis-carbalkoxy compounds and their preparation
    1.
    发明授权
    Bis-carbalkoxy compounds and their preparation 失效
    双 - 烷氧基化合物及其制备方法

    公开(公告)号：US4288607A

    公开(公告)日：1981-09-08

    申请号：US19944

    申请日：1979-03-12

    Applicant: Gerhard Bier ,  Dagmar Kottek ,  Egon N. Petersen ,  Hermann Richtzenhain ,  Norbert Vollkommer

    Inventor： Gerhard Bier ,  Dagmar Kottek ,  Egon N. Petersen ,  Hermann Richtzenhain ,  Norbert Vollkommer

    IPC: C08L67/00 ,  C07C67/00 ,  C07C69/80 ,  C07C69/92 ,  C07C313/00 ,  C07C315/04 ,  C07C317/22 ,  C08G63/00 ,  C08G63/676 ,  C08G63/68 ,  C08G63/682 ,  C08K5/00 ,  C08L67/06 ,  C07C147/107

    CPC classification number: C08K5/0066 ,  C07C317/22 ,  C07C69/92 ,  C08G63/676 ,  C08G63/6826 ,  C08G63/6828

    Abstract: The invention relates to halogenous polyesters with the recurrent general formula ##STR1## in which at least part of the R's, e.g. 1 to 100 mole-%, preferably 100 mole-%, or 2 to 10 mole-%, are of the general formulas ##STR2## and 0 to 99 mole-%, preferably 0 or 90 to 98 mole-%, of the R's correspond to a phenylene radical and/or a naphthylene radical and/or an alkylene radical of 3 to 10 carbon atoms and/or a cycloalkylene radical, and the R's represent an organic moiety which is contained in bivalent saturated alcohols and corresponds to a branched or unbranched saturated alkylene radical of 2 to 10 carbon atoms and/or to a cycloalkylene radical and/or which is derived from an alkyleneterephthalate containing hydroxyl groups, preferably an oligomeric ethyleneterephthalate and/or an oligomeric propyleneterephthalate and/or an oligomeric butyleneterephthalate, wherein Z represents the groups ##STR3## and X represents hydrogen, bromine or chlorine, wherein at least some of the X's are bromine or chlorine, and in which polyesters, in some cases, a portion of the R's are residues of unsaturated dicarboxylic acid derivatives which, together with ethylenically unsaturated comonomers, preferably styrene, are capable of forming peroxide-curable unsaturated polyester resin (UP resin) solutions, and their preparation as well as their use as fire-retardant molding compositions or articles, and also dicarboxylic acid esters some of which can be used in the preparation of the polyesters as well as the preparation of these dicarboxylic acid esters. Preferably the xylene nucleus in (2) is substituted by Br.sub.4.0 to 2.8 and Cl.sub.0 to 1.2.

    Abstract translation: 本发明涉及具有复发性通式“IMAGE”的卤代聚酯，其中R的至少一部分，例如， 1至100摩尔％，优选100摩尔％或2至10摩尔％的通式为通式（1）和/或（IMAGE）（2）和0至99摩尔％ 0或90至98摩尔％的R对应于亚苯基和/或亚萘基和/或具有3至10个碳原子的亚烷基和/或亚环烷基，并且R代表有机部分，其中 包含在二价饱和醇中，并且对应于具有2-10个碳原子的支链或非支链的饱和亚烷基和/或环亚烷基和/或衍生自含有羟基的亚烷基对苯二甲酸酯，优选低聚对苯二甲酸乙二醇酯和/或 低聚对苯二甲酸丙二酯和/或低聚对苯二甲酸丁二醇酯，其中Z表示基团，X表示氢，溴或氯，其中至少一些X是溴或氯，并且其中聚酯在一些情况下， R是不饱和d的残基 与烯键式不饱和共聚单体，优选苯乙烯一起形成过氧化物可固化的不饱和聚酯树脂（UP树脂）溶液及其制备以及它们作为阻燃成型组合物或制品的用途的二羧酸衍生物，以及二羧酸 酸酯，其中一些可用于制备聚酯以及这些二羧酸酯的制备。 优选（2）中的二甲苯核被Br4.0至2.8和Cl0至1.2取代。

    Process for the preparation of 2,2-bis-(4-hydroxy-3-chlorophenyl)-propane
    4.
    发明授权
    Process for the preparation of 2,2-bis-(4-hydroxy-3-chlorophenyl)-propane 失效
    制备2,2-双 - （4-羟基-3-氯苯基） - 丙烷的方法

    公开(公告)号：US3932535A

    公开(公告)日：1976-01-13

    申请号：US442939

    申请日：1974-02-15

    Applicant: Gunter Zoche ,  Hermann Richtzenhain ,  Roshdy Ismail

    Inventor： Gunter Zoche ,  Hermann Richtzenhain ,  Roshdy Ismail

    IPC: C07C37/62 ,  C07C39/367 ,  C08G63/682 ,  C07C37/22

    CPC classification number: C07C37/62 ,  C07C37/84 ,  C08G63/6826

    Abstract: Process for the preparation of especially pure 2,2-bis-(4-hydroxy-3-chlorophenyl)-propane (dichlordiane, DCD) by the chlorination of 2,2-bis-(4-hydroxyphenyl)-propane in the presence of solvents that are substantially indifferent to chlorine by prior-art methods; then, for purification, the chlorinated bis-phenol is dissolved in halogenated hydrocarbons and/or halogenated hydrocarbon in which are liquid at 20.degree.C which they are readily soluble in the absence of an aqueous phase but in which they are at most only slightly soluble after the addition of water thereto; and the 2,2-bis-(4-hydroxy-3-chlorophenyl)-propane, is thereby precipitated from this aqueous solution.

    Abstract translation: 通过2,2-双 - （4-羟基苯基） - 丙烷的氯化，在存在下制备特别纯的2,2-双 - （4-羟基-3-氯苯基） - 丙烷（二氯代，DCD）的方法 通过现有技术方法基本上对氯无关的溶剂; 然后，为了净化，氯化双酚溶解在20℃下为液态的卤代烃和/或卤代烃中，它们在不存在水相的情况下易于溶解，但其中它们最多仅仅是微溶的 加水后; 和2,2-双 - （4-羟基-3-氯苯基） - 丙烷，由此从该水溶液中沉淀出来。

    Method and apparatus for performing carbonylation reactions
    5.
    发明授权
    Method and apparatus for performing carbonylation reactions 失效
    用于进行羰基化反应的方法和装置

    公开(公告)号：US4424375A

    公开(公告)日：1984-01-03

    申请号：US274108

    申请日：1981-06-16

    Applicant: Moustafa El-Chahawi ,  Uwe Prange ,  Hermann Richtzenhain ,  Wilhelm Vogt

    Inventor： Moustafa El-Chahawi ,  Uwe Prange ,  Hermann Richtzenhain ,  Wilhelm Vogt

    IPC: C07C67/36 ,  B01F5/10 ,  B01J10/00 ,  C02F1/00 ,  C07C27/00 ,  C07C51/00 ,  C07C51/10 ,  C07C51/12 ,  C07C67/00 ,  C07C69/00 ,  C07C69/76

    CPC classification number: C07C51/10

    Abstract: Improvement in the process of producing carboxylic acid esters or salts involving contacting a halogen alkyl compound with carbon monoxide and a basic substance in the presence of a carbonylation catalyst for carbonylation of the halogen alkyl and production of the corresponding ester or salt of the basic substance. The improvement involves performing the contacting in a reaction vessel, circulating a liquid mass of the halogen alkyl, basic substance and carbonylation catalyst through the vessel and maintaining a carbon monoxide atmosphere in the vessel, injecting the circulating liquid mass into the vessel with a nozzle to spray the liquid mass into the vessel and intimately mixing the liquid mass with carbon monoxide in the nozzle for injection of carbon monoxide into the vessel with the sprayed liquid mass.

    Abstract translation: 包括在羰基化羰基化催化剂存在下将卤代烷基化合物与一氧化碳和碱性物质接触的羧酸酯或盐的改进，用于羰基化卤代烷基和生成碱性物质的相应酯或盐。 改进包括在反应容器中进行接触，使卤素烷基，碱性物质和羰基化催化剂的液体物质通过容器循环并保持容器中的一氧化碳气氛，将循环液体物质用喷嘴注入容器 将液体物质喷射到容器中，并将液体物质与喷嘴中的一氧化碳充分混合，用喷射的液体物质将一氧化碳注射到容器中。

    Method of preparing .alpha.,.beta.-unsaturated carboxylic acid esters
    7.
    发明授权
    Method of preparing .alpha.,.beta.-unsaturated carboxylic acid esters 失效
    制备{60，{62-不饱和羧酸酯

    公开(公告)号：US4156785A

    公开(公告)日：1979-05-29

    申请号：US599913

    申请日：1975-07-28

    Applicant: Uwe Prange ,  Hermann Richtzenhain ,  Wilhelm Vogt

    Inventor： Uwe Prange ,  Hermann Richtzenhain ,  Wilhelm Vogt

    IPC: C07C69/533 ,  B01J31/00 ,  C07B61/00 ,  C07C69/52 ,  C07C69/708

    CPC classification number: C07C69/52

    Abstract: Process of preparing an .alpha.,.beta.-unsaturated carboxylic acid ester, comprising contacting an .alpha.,.beta.-unsaturated halogen compound with carbon monoxide, an alkali alcoholate in the presence of a metal carbonyl as catalyst, in an alcohol that is the basis of the alkali alcoholate, at a pH of 8.5-11.5. Thereby, for example, crotonic acid methyl ester can be produced from allyl chloride.

    Abstract translation: 制备α，β-不饱和羧酸酯的方法，包括在作为催化剂的金属羰基存在下，在作为碱的基础的醇中使α，β-不饱和卤素化合物与一氧化碳接触，碱金属醇化物 醇化物，pH为8.5-11.5。 因此，例如可以由烯丙基氯制造巴豆酸甲酯。

    Method of preparing carboxylic acid chlorides of the benzene series
    8.
    发明授权
    Method of preparing carboxylic acid chlorides of the benzene series 失效
    苯系列羧酸氯化物的制备方法

    公开(公告)号：US4104300A

    公开(公告)日：1978-08-01

    申请号：US813595

    申请日：1977-07-07

    Applicant: Gunter Zoche ,  Hermann Richtzenhain ,  Wilhelm Vogt

    Inventor： Gunter Zoche ,  Hermann Richtzenhain ,  Wilhelm Vogt

    IPC: C07C51/60 ,  C07C51/58

    CPC classification number: C07C51/60

    Abstract: In a process for preparing substituted or unsubstituted carboxylic acid chlorides of the benzene series by contacting the corresponding carboxylic acid ester with an aromatic compound containing at least one nuclearly bound trichlormethyl group in the presence of a molybdenum catalyst, the improvement which comprises introducing into the reaction mixture prior to distillation of the carboxylic acid chloride a complexing agent which complexes with the molybdenum catalyst.

    Abstract translation: 在通过在钼催化剂的存在下使相应的羧酸酯与含有至少一个核结合的三氯甲基的芳族化合物接触来制备苯系列的取代或未取代的羧酸氯化物的方法，其包括引入反应 在蒸馏羧酸氯化物之前的混合物是与钼催化剂复合的络合剂。

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