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1.发明授权Homopolymers and copolymers of acrylamide N-substituted acrylamide or N-substituted methacrylamide solid state cross-linked with polyamines or polyols 失效丙烯酰胺N-取代丙烯酰胺或N-取代甲基丙烯酰胺固态与多胺或多元醇交联的均聚物和共聚物
公开(公告)号：US5280078A
公开(公告)日：1994-01-18
申请号：US764986
申请日：1991-09-23
IPC分类号： B01D67/00 , B01D71/40 , C08F8/00 , D21H17/37 , D21H17/39 , D21H17/42 , D21H17/45 , C08F8/30 , C08F8/14
CPC分类号： B01D67/0093 , B01D71/40 , C08F8/00 , C08F8/34 , D21H17/37 , D21H17/39 , D21H17/42 , D21H17/45 , B01D2323/30 , C08F2800/10 , C08F2810/20
摘要： Cross-linked polymeric gels or films are prepared by dissolving in a suitable solvent a linear polymer or polymers at least one of which is predominantly (at least 80%) made from monomers containing pendant amidocarbonyl or oxycarbonyl groups. For the cross-linking reaction are present either hydroxyl groups, present as either pendant groups from the polymer, or as low molecular weight polyols; or amino groups, present as either pendant groups from the polymer, or as low molecular weight diamines or polyamines. Either no catalyst is present or a strongly acidic catalyst (which may also be a pendant group on a polymer) is used. The solvent is removed by coagulation and/or drying and the dry material is heat-cured, thus cross-linking and insolubilizing the polymer or polymers.
摘要翻译： 通过将合适的溶剂中溶解线性聚合物或聚合物来制备交联聚合物凝胶或膜，所述线性聚合物或聚合物中至少一种主要由含有酰氨基羰基或氧羰基侧链的单体制成（至少80％）。 由于交联反应存在于作为聚合物的侧基存在的羟基或作为低分子量多元醇的羟基; 或氨基，作为聚合物的侧基存在，或作为低分子量二胺或多胺存在。 不使用催化剂，也可以使用强酸性催化剂（也可以是聚合物上的侧基）。 通过凝结和/或干燥除去溶剂，干燥的材料被热固化，从而使聚合物或聚合物交联和不溶解。
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2.发明授权Membrane processes for metal recovery and pollution control in metal process industries 失效金属加工工业中金属回收和污染控制的膜工艺
公开(公告)号：US4655928A
公开(公告)日：1987-04-07
申请号：US543191
申请日：1983-10-18
申请人： Everett C. Milton , Harry P. Gregor
发明人： Everett C. Milton , Harry P. Gregor
IPC分类号： C02F1/44 , B01D61/44 , C02F1/469 , C02F1/62 , C02F9/00 , C22B7/00 , C22B13/00 , C22B15/00 , C22B17/00 , C22B23/00 , C22B26/10 , C23F1/46 , H01M10/54 , B01D13/00
CPC分类号： H01M10/54 , B01D61/58 , C02F9/00 , C22B13/04 , C22B15/0086 , C22B17/04 , C22B23/0453 , C22B26/10 , C22B7/006 , B01D2311/2642 , B01D61/025 , B01D61/445 , C02F2101/20 , Y02P10/234 , Y02P10/236 , Y02W30/84
摘要： A process for the treatment of an aqueous stream containing an acid or base and typically a precipitatable material such as a metal ion comprises:(a) subjecting the aqueous stream to (i) a treatment to produce a relatively pure stream of water and a concentrated aqueous stream, and (ii) water splitting to produce a stream of base, a stream of acid and a dilute aqueous stream of a concentration lower than the concentrated aqueous stream, the treatments (i) and (ii) being effected in either order,(b) recycling at least part of the pure water stream produced in (a)(i) to an earlier stream either in the production leading to said aqueous stream or to step (i) or (ii),(c) recycling at least part of the acid and/or base streams produced in (a)(ii) to an earlier stream either in the production leading to said aqueous stream or to an earlier step in the process, and(d) recycling at least part of the lower concentration stream produced in (a)(ii) to either (a)(i) or to another step in the process, whereby, when present, only the precipitatable material is removed from the aqueous stream, thereby obviating toxic waste disposal problems.
摘要翻译： 用于处理含有酸或碱和典型的可沉淀物质如金属离子的含水流的方法包括：（a）使水流经受（i）处理以产生相对纯的水流和浓缩的 水流，和（ii）水分解以产生碱流，酸流和浓度低于浓缩水流的稀水流，处理（i）和（ii）以任何顺序进行， （b）将（a）（i）中生产的纯水流中的至少一部分再循环到生产过程中的较早的流中，或者在步骤（i）或（ii）中，（c）至少再循环 （a）（ii）中生产的一部分酸和/或碱性物流在生产过程中，或者在生产过程中的较早阶段，或（d）回收至少一部分较低的 （a）（ii）中产生的（a）（i）或（p）中的另一步骤产生的浓缩物流 由此，当存在时，只有可沉淀物质从水流中除去，从而避免有毒废物处理问题。
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公开(公告)号：US4012324A
公开(公告)日：1977-03-15
申请号：US433930
申请日：1974-01-15
申请人： Harry P. Gregor
发明人： Harry P. Gregor
CPC分类号： C08J5/2268 , B01D67/0011 , B01D67/0013 , B01D69/02 , B29D7/01 , B01D2323/30
摘要： Interpolymer fixed-charge membranes of macroscopic homogeneity are prepared by providing a solution containing a matrix polymer, a polyelectrolyte and a crosslinking agent, evaporating the solvent until substantially the desired pore size and other physical properties are obtained in a film cast from the solution, the thereafter chemically crosslinking the film to insolubilize the membrane.
摘要翻译： 通过提供含有基质聚合物，聚电解质和交联剂的溶液，蒸发溶剂直至从溶液中形成的薄膜中获得基本上所需的孔径和其它物理性质来制备宏观均匀性的互聚物固定电荷膜， 然后使膜化学交联以使膜不溶化。
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公开(公告)号：US5312873A
公开(公告)日：1994-05-17
申请号：US711673
申请日：1991-06-06
CPC分类号： B01D67/0093 , B01D69/125 , B01D71/42 , C08F8/00 , C08J7/12 , B01D2323/30
摘要： Water insoluble polymers are treated to place on their exposed surfaces the pendant alkyl imidocarbonyl (amide) groups to impart a high degree of hydrophilicity to that surface. Nitrile-containing polymers or copolymers in the form of insoluble films, filters or membranes are treated to convert a substantial fraction of the surface nitrile groups into the corresponding amide by the use of hydrogen peroxide or concentrated acids. The surface is rendered hydrophilic and resistant to fouling to the extent that even proteins are not denatured thereupon. The surface may also be converted to substituted amides by subsequent reactions to impart to it other functionalities or to serve as the basis for coupling reactions. Other polymers capable of surface treatment to produce pendant amidocarbonyl groups include ones containing pendant esters which on cleavage of the oxygen-carbon bond give pendant alcohol groups. These are converted by cyanoethylation to form the pendant nitrile groups which can be converted to the amide. Other polymers which on hydrolysis give pendant carboxylic acids can be treated with ammonia to also produce pendant amide groups.
摘要翻译： 处理水不溶性聚合物以在其暴露的表面上放置亚酰氨基羰基（酰胺）基团，以赋予该表面高度亲水性。 处理不溶性膜，过滤器或膜形式的含腈聚合物或共聚物，通过使用过氧化氢或浓缩酸将大部分表面腈基转化为相应的酰胺。 表面被赋予亲水性并且抗结垢至甚至蛋白质不变性的程度。 该表面也可以通过后续反应转化为取代的酰胺，以赋予其它功能或用作偶联反应的基础。 能够进行表面处理以产生酰亚胺基羰基的其它聚合物包括含有侧链酯的聚合物，其在氧 - 碳键裂解时产生侧链醇基。 这些通过氰乙基化反应形成可以转化成酰胺的侧基腈基。 可以用氨处理水解产生侧羧酸的其它聚合物，也可产生酰胺基。
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公开(公告)号：US5059659A
公开(公告)日：1991-10-22
申请号：US635421
申请日：1991-01-03
CPC分类号： B01D67/0093 , B01D69/125 , B01D71/42 , C08F8/00 , C08J7/12 , B01D2323/30
摘要： Water insoluble polymers are treated to place on their exposed surfaces the pendant alkyl imidocarbonyl (amide) groups to impart a high degree of hydrophilicity to that surface. Nitrile-containing polymers or copolymers in the form of insoluble films, filters or membranes are treated to convert a substantial fraction of the surface nitrile groups into the corresponding amide by the use of hydrogen peroxide or concentrated acids. The surface is rendered hydrophilic and resistant to fouling to the extent that even proteins are not denatured thereupon. The surface may also be converted to substituted amides by subsequent reactions to impart to it other functionalities or to serve as the basis for coupling reactions. Other polymers capable of surface treatment to produce pendant amidocarbonyl groups include ones containing pendant esters which on cleavage of the oxygen-carbon bond give pendant alcohol groups. These are converted by cyanoethylation to form the pendant nitrile groups which can be converted to the amide. Other polymers which on hydrolysis give pendant carboxylic acids can be treated with ammonia to also produce pendant amide groups.
摘要翻译： 处理水不溶性聚合物以在其暴露的表面上放置亚酰氨基羰基（酰胺）基团，以赋予该表面高度亲水性。 处理不溶性膜，过滤器或膜形式的含腈聚合物或共聚物，通过使用过氧化氢或浓缩酸将大部分表面腈基转化为相应的酰胺。 表面被赋予亲水性并且抗结垢至甚至蛋白质不变性的程度。 该表面也可以通过后续反应转化为取代的酰胺，以赋予其它功能或用作偶联反应的基础。 能够进行表面处理以产生酰亚胺基羰基的其它聚合物包括含有侧链酯的聚合物，其在氧 - 碳键裂解时产生侧链醇基。 这些通过氰乙基化反应形成可以转化成酰胺的侧基腈基。 可以用氨处理水解产生侧羧酸的其它聚合物，也可产生酰胺基。
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公开(公告)号：US4596858A
公开(公告)日：1986-06-24
申请号：US622417
申请日：1984-06-20
CPC分类号： B01D67/0093 , B01D71/40 , C08F8/00 , C08F8/34 , D21H17/37 , D21H17/39 , D21H17/42 , D21H17/45 , B01D2323/30 , C08F2800/10 , C08F2810/20
摘要： Cross-linked polymeric gels or films are prepared by dissolving in a suitable solvent a linear polymer or polymers containing pendant amidocarbonyl or oxycarbonyl groups, hydroxyl groups present as either pendant groups from the polymer or as a low molecular weight polyol, and a strongly acidic catalyst (which may also be a pendant group on a polymer). The solvent is removed by coagulation and/or drying and the dry material is heat-cured, thus cross-linking and insolubilizing the polymer or polymers.
摘要翻译： 通过在合适的溶剂中溶解线性聚合物或含有酰亚胺羰基或氧羰基侧链的聚合物，以聚合物或低分子量多元醇作为侧基存在的羟基和强酸性催化剂制备交联聚合物凝胶或膜 （其也可以是聚合物上的侧基）。 通过凝结和/或干燥除去溶剂，干燥的材料被热固化，从而使聚合物或聚合物交联和不溶解。
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公开(公告)号：US4163714A
公开(公告)日：1979-08-07
申请号：US629939
申请日：1975-11-07
申请人： Harry P. Gregor
发明人： Harry P. Gregor
IPC分类号： B01D61/14 , B01D15/08 , B01D39/00 , B01D71/62 , B01J20/28 , B01J20/32 , C07K1/34 , C07K14/81 , C07K16/06 , C07K17/08 , C08J5/18 , C12N9/00 , C12N11/00 , C12N11/02 , C25B13/04 , B01D13/00 , C07G7/00
CPC分类号： B01D61/145 , B01D15/08 , B01J20/28014 , B01J20/28033 , B01J20/3242 , C07K1/34 , C07K14/811 , C07K16/06 , C12N11/02 , C12N9/00 , B01D2323/24 , Y10S435/815
摘要： Pressure-driven affinity sorption membranes are prepared from a membrane filter composed of an insoluble matrix polymer or an interpolymer composite and used for separation and purification by passing therethrough solutions containing mixtures, one or more of which forms a specific complex with the ligand on the pore surface of the membrane, washing out the uncoupled solutes, then employing an appropriate displacing or eluting agent to recover the desired component in a pure and concentrated state, all under pressure-driven conditions.
摘要翻译： 压力驱动的亲和吸附膜由由不溶性基质聚合物或互聚物复合物组成的膜过滤器制备，用于通过含有混合物的溶液进行分离和纯化，其中一种或多种与孔的配体形成特异性络合物 洗涤出未偶联的溶质，然后使用适当的置换或洗脱剂以纯的和浓缩的状态回收所有的组分，全部在压力驱动条件下。
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公开(公告)号：US4705753A
公开(公告)日：1987-11-10
申请号：US618652
申请日：1984-06-08
申请人： Harry P. Gregor , Paul I. Dalven , James R. Hildebrandt , Leonard T. Hodgins , Anthony J. Laccetti , Abraham Shamir
发明人： Harry P. Gregor , Paul I. Dalven , James R. Hildebrandt , Leonard T. Hodgins , Anthony J. Laccetti , Abraham Shamir
IPC分类号： A61K38/00 , B01D67/00 , B01D69/14 , B01D71/42 , B01J20/28 , C07K1/22 , C07K14/78 , C12N11/08 , C12N11/00 , C12N11/06 , G01N33/545
CPC分类号： B01D67/0093 , A61K38/005 , B01D69/141 , B01D71/42 , B01J20/28033 , C07K1/22 , C07K14/78 , C12N11/08 , Y10S530/815 , Y10S530/816
摘要： A membrane is produced by dissolving, in a water-miscible solvent, a water insoluble copolymer of acrylontrile with at least one monomer selected from the group consisting of an aminostyrene, a vinyl pyridine and an N-hydroxy-containing-substituent-acrylamide, casting said solution to form a thin layer of solution, contacting said solution with water thereby to coagulate the copolymer into a film, and washing away from the copolymer film the solution of solvent and water. The amine or hydroxy group of the copolymer is then activated and coupled with a ligand such as glucose isomerase, chymotrypsin or Protein A. The coupled membranes can then be used for biological separations and reactions.
摘要翻译： 通过将水性不溶性丙烯腈共聚物与选自氨基苯乙烯，乙烯基吡啶和N-羟基的取代基 - 丙烯酰胺中的至少一种单体溶解在水混溶性溶剂中来制造膜， 所述溶液形成薄层溶液，使所述溶液与水接触，从而将共聚物凝结成膜，并从共聚物膜上洗去溶剂和水的溶液。 然后将共聚物的胺或羟基活化并与配体如葡萄糖异构酶，胰凝乳蛋白酶或蛋白A偶联。然后可以将偶联的膜用于生物分离和反应。
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9.发明授权
公开(公告)号：US4584057A
公开(公告)日：1986-04-22
申请号：US725720
申请日：1985-04-22
申请人： John W. Rowe , Harry P. Gregor
发明人： John W. Rowe , Harry P. Gregor
CPC分类号： B01D61/58 , C07C51/42 , D21C11/0007 , B01D2311/18 , B01D2311/2642 , B01D2311/2669 , B01D61/025 , B01D61/145 , B01D61/445 , C02F2103/28 , Y10S210/928
摘要： An aliphatic organic acid fraction is separated from the kraft black liquor by subjecting the liquor to ultrafiltration, treating the resulting permeate by electrodialysis, acidifying the resultant deionate to about pH 4-5, separating the lignin solids which precipitate following this acidification, raising the pH of the separated solution to about 7-8 and finally subjecting the neutralized solution to electrodialytic water-splitting.
摘要翻译： 通过对液体进行超滤，通过电渗析处理所得到的渗透物，将所得酸性酸酸化至约pH 4-5，分离出酸化后沉淀的木质素固体，提高pH值，从而将牛脂黑色液体与硫酸盐黑液分离 的分离溶液为约7-8，最后使中和的溶液进行电渗析水分解。
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10.发明授权Membrane processes for treatment of and recovery of components from kraft black liquors 失效用于处理和回收硫酸盐黑液的组分的膜方法
公开(公告)号：US4775480A
公开(公告)日：1988-10-04
申请号：US8176
申请日：1987-01-29
申请人： Everett C. Milton , Harry P. Gregor
发明人： Everett C. Milton , Harry P. Gregor
CPC分类号： H01M10/54 , B01D61/58 , C02F1/4693 , C02F9/00 , C22B13/04 , C22B15/0086 , C22B17/04 , C22B23/0453 , C22B26/10 , C22B7/006 , B01D2311/2642 , B01D61/025 , B01D61/145 , B01D61/147 , B01D61/445 , C02F2001/46128 , C02F2101/20 , Y02P10/234 , Y02P10/236 , Y02W30/84
摘要： A process for the treatment of an aqueous stream containing an acid or base and typically a precipitatable material such as a metal ion comprises:(a) subjecting the aqueous stream to (i) a treatment to produce a relatively pure stream of water and a concentrated aqueous stream, and (ii) water splitting to produce a stream of base, a stream of acid and a dilute aqueous stream of a concentration lower than the concentrated aqueous stream, the treatments (i) and (ii) being effected in either order,(b) recycling at least part of the pure water stream produced in (a) (i) to an earlier stream either in the production leading to said aqueous stream or to step (i) or (ii),(c) recycling at least part of the acid and/or base streams produced in (a) (ii) to an earlier stream either in the production leading to said aqueous stream or to an earlier step in the process, and(d) recycling at least part of the lower concentration stream produced in (a) (ii) to either (a) (i) or to another step in the process, whereby, when present, only the precipitatable material is removed from the aqueous stream, thereby obviating toxic waste disposal problems.
摘要翻译： 用于处理含有酸或碱和典型的可沉淀物质如金属离子的含水流的方法包括：（a）使水流经受（i）处理以产生相对纯的水流和浓缩的 水流，和（ii）水分解以产生碱流，酸流和浓度低于浓缩水流的稀水流，处理（i）和（ii）以任何顺序进行， （b）将（a）（i）中生产的纯水流中的至少一部分再循环到生产过程中的较早的流中，或者在步骤（i）或（ii）中，（c）至少再循环 （a）（ii）中生产的一部分酸和/或碱性物流在生产过程中，或者在生产过程中的较早阶段，或（d）回收至少一部分较低的 （a）（ii）中产生的（a）（i）或（t）中的另一步骤产生的浓缩物流 因此，当存在时，只有可沉淀物质从水流中除去，从而避免有毒废物处理问题。
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