Penta-2,4-dienamides and use as pesticides
    1.
    发明授权
    Penta-2,4-dienamides and use as pesticides 失效
    五 - 2,4-二烯酰胺,用作农药

    公开(公告)号:US5459149A

    公开(公告)日:1995-10-17

    申请号:US309430

    申请日:1994-09-20

    摘要: The present Application discloses pesticidally active compounds of formula (I):Q(CH.sub.2).sub.a (O).sub.b Q.sup.1 CR.sup.2 =CR.sup.3 CR.sup.4 =CR.sup.5 CXNR.sup.1 R.sup.xor a salt or propesticide thereof, wherein Q is an optionally substituted aromatic monocyclic or fused bicyclic ring system in which at least one ring is aromatic, or Q is a dihalovinyl group or a group R.sup.6 --C=C--where R.sup.6 is C.sub.1-4 alkyl, tri C.sub.1-4 alkylsilyl, halo or hydrogen; Q.sup.1 is a 1,2-cyclopropyl ring optionally substituted by one or more groups selected from C.sub.1-3 alkyl, halo, C.sub.1-3 haloalkyl, C.sub.2-3 alkynyl, or cyano; or Q.sup.1 is (CH.sub.2).sub.7 ; a=0 or 1; b=0 or 1; R.sup.2, R.sup.3, R.sup.4 and R.sup.5 are the same or different with at least one being hydrogen and the others being independently selected from hydrogen, halo, C.sub.1-4 alkyl or C.sub.1-4 haloalkyl; X is oxygen or sulphur;R.sup.1 is phenyl optionally substituted by 1-5 substituents chosen from: a) C.sub.1-4 alkyl, C.sub.1-4 alkoxy, phenoxy and methylenedioxy, each optionally substituted by 1 to 5 halo; b) halo, cyano, nitro, formyl, C.sub.1-5 acyl; c) C.sub.2-3 alkynyl, C.sub.2-3 alkenyl, each optionally substituted by 1 to 5 halo; d) a group S(O).sub.n R.sup.7 wherein n=0, 1, 2 and R.sup.7 is C.sub.1-4 alkyl, halo or NR.sup.8 R.sup.9 wherein R.sup.8 and R.sup.9 are independently selected from hydrogen, C.sub.1-4 alkyl and C.sub.1-4 acyl; and a group e) NR.sup.8 R.sup.9 where R.sup.8 and R.sup.9 are as defined above; R.sup.X is hydrogen or an optionally substituted C.sub.1-8 alkyl or benzyl group, their preparation, pesticidal compositions containing them and their use against pests.

    摘要翻译: 本申请公开了式(I)的杀虫活性化合物:Q(CH2)a(O)bQ1 CR2 = CR3 CR4 = CR5 CXNR1Rx或其盐或农药,其中Q是任选取代的芳族单环或稠合双环体系 其中至少一个环是芳族的,或Q是二卤代乙烯基或基团R6-C = C-,其中R6是C1-4烷基,三C1-4烷基甲硅烷基,卤素或氢; Q1是任选被一个或多个选自C 1-3烷基,卤素,C 1-3卤代烷基,C 2-3炔基或氰基的基团取代的1,2-环丙基环; 或Q 1为(CH 2)7; a = 0或1; b = 0或1; R 2,R 3,R 4和R 5相同或不同,至少一个为氢,其余独立地选自氢,卤素,C 1-4烷基或C 1-4卤代烷基; X是氧或硫; R1是任选被1-5个选自下列的取代基取代的苯基:a)C 1-4烷基,C 1-4烷氧基,苯氧基和亚甲二氧基,各自任选被1至5个卤素取代; b)卤素,氰基,硝基,甲酰基,C 1-5酰基; c)C2-3炔基,C2-3烯基,各自任选被1至5个卤素取代; d)基团S(O)n R 7,其中n = 0,1,2且R 7是C 1-4烷基,卤素或NR 8 R 9,其中R 8和R 9独立地选自氢,C 1-4烷基和C 1-4酰基; 和基团e)NR 8 R 9,其中R 8和R 9如上所定义; RX是氢或任选取代的C 1-8烷基或苄基,它们的制备方法,含有它们的杀虫组合物及其对害虫的用途。

    Certain 2,4-pentadienamide pestacides
    2.
    发明授权
    Certain 2,4-pentadienamide pestacides 失效
    某些2,4-戊二烯酰胺类杀虫剂

    公开(公告)号:US5326755A

    公开(公告)日:1994-07-05

    申请号:US923970

    申请日:1992-09-10

    摘要: The present application discloses pesticidally active compounds of formula I:QQ.sup.1 CR.sup.1 .dbd.CR.sup.2 CR.sup.3 .dbd.CR.sup.4 C(.dbd.X.sup.1)NR.sup.5 R.sup.6or a salt thereof, wherein Q is an monocyclic aromatic ring, or Q is a dihalovinyl group or a group R.sup.7 --C.dbd.C-- where R.sup.7 is C.sub.1-4 alkyl, tri C.sub.1-4 alkylsilyl, halogen or hydrogen; Q.sup.1 is a 1,2-cyclopropyl ring optionally substituted by one or more groups selected from C.sub.1-3 alkyl, halo, C.sub.1-3 haloalkyl, alkynyl, or cyano; R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are the same or different with at least one being hydrogen and the others being independently selected from hydrogen, halo, C.sub.1-4 alkyl or C.sub.1-4 haloalkyl; X.sup.1 is oxygen or sulphur; R.sup.5 is C.sub.1-8 hydrocarbyl optionally substituted, halo, cyano, trifluoromethyl, trifluoromethylthio or C.sub.1-6 alkoxy; and R.sup.6 is selected from:(A) --Y.dbd.X.sup.2 --(R.sup.8).sub.a where X.sup.2 is O or S, Y is carbon, R.sup.8 is hydrogen, C.sub.1-4 alkyl, C.sub.1-4 alkoxy, C.sub.1-5 alkylcarbonyl or aryl or CO.sub.2 R.sup.9 where R.sup.9 is an C.sub.1-4 alkyl or aryl, and a is 1 or 2;(B) --CR.sup.15 R.sup.16 X.sup.3 R.sup.17 where R.sup.15 and R.sup.16 are hydrogen or C.sub.1-4 alkyl, X.sup.3 is oxygen or sulphur and R.sup.17 is C.sub.1-4 alkyl, C.sub.1-5 alkylcarbonyl or aralkylcarbonyl R.sup.17,R.sup.15 X.sup.3, their preparation, pesticidal compositions containing them and their use against pests.

    摘要翻译: PCT No.PCT / GB91 / 00539 Sec。 371日期:1992年9月10日 102(e)日期1992年9月10日PCT 1991年4月8日PCT PCT。 WO91 / 16301 PCT出版物 1991年10月31日。本申请公开了式I的杀虫活性化合物:QQ1CR1 = CR2CR3 = CR4C(= X1)NR5R6或其盐,其中Q为单环芳环,或Q为二卤代乙烯基或基团 R7-C = C-,其中R7是C1-4烷基,三C1-4烷基甲硅烷基,卤素或氢; Q1是任选被一个或多个选自C 1-3烷基,卤素,C 1-3卤代烷基,炔基或氰基的基团取代的1,2-环丙基环; R 1,R 2,R 3和R 4相同或不同,至少一个为氢,其余独立地选自氢,卤素,C 1-4烷基或C 1-4卤代烷基; X1是氧或硫; R 5为任选取代的C 1-8烃基,卤素,氰基,三氟甲基,三氟甲硫基或C 1-6烷氧基; 并且R 6选自:(A)-Y = X 2 - (R 8)a,其中X 2为O或S,Y为碳,R 8为氢,C 1-4烷基,C 1-4烷氧基,C 1-5烷基羰基或芳基或 CO 2 R 9,其中R 9为C 1-4烷基或芳基,a为1或2; (B)-CR15R16X3R17其中R15和R16为氢或C1-4烷基,X3为氧或硫,R17为C1-4烷基,C1-5烷基羰基或芳烷基羰基R17,R15X3,其制备方法,含有它们的杀虫组合物及其用途 反对有害生物

    Penta-2,4-dienamides and use as pesticides
    4.
    发明授权
    Penta-2,4-dienamides and use as pesticides 失效
    五 - 2,4-二烯酰胺,用作农药

    公开(公告)号:US5270343A

    公开(公告)日:1993-12-14

    申请号:US898135

    申请日:1992-06-15

    摘要: The present Application discloses pesticidally active compounds of formula (I):Q(CH.sub.2).sub.a (O).sub.b Q.sup.1 CR.sup.2 .dbd.CR.sup.2 .dbd.CR.sup.3 CR.sup.4 .dbd.CR.sup.5 CXNR.sup.1 R.sup.xor a salt or propesticide thereof, wherein Q is an optionally substituted aromatic monocyclic or fused bicyclic ring system in which at least one ring is aromatic, or Q is a dihalovinyl group or a group R.sup.6 --C.tbd.C-- where R.sup.6 is C.sub.1-4 alkyl, tri C.sub.1-4 alkylsilyl, halo or hydrogen; Q.sup.1 is a 1,2-cyclopropyl ring optionally substituted by one or more groups selected from C.sub.1-3 alkyl, halo, C.sub.1-3 haloalkyl, C.sub.2-3 alkynyl, or cyano; or is (CH.sub.2).sub.7 ;a=0 or 1; b= 0 or 1;R.sup.2, R.sup.3, R.sup.4 and R.sup.5 are the same or different with at least one being hydrogen and the others being independently selected from hydrogen, halo, C.sub.1-4 alkyl or C.sub.1-4 haloalkyl;X is oxygen or sulphur;R.sup.1 is phenyl optionally substituted by 1-5 substituents chosen from:a) C.sub.1-4 alkyl, C.sub.1-4 alkoxy, phenoxy and methylenedioxy, each optionally substituted by 1 to 5 halo;b) halo, cyano, nitro, formyl, C.sub.1-5 acyl;c) C.sub.2-3 alkynyl, C.sub.2-3 alkenyl, each optionally substituted by 1 to 5 halo;d) a group S(O).sub.n R.sup.7 wherein n=0,1,2 and R.sup.7 is C.sub.1-4 alkyl, halo or NR.sup.8 R.sup.9 wherein R.sup.8 and R.sup.9 are independently selected from hydrogen, C.sub.1-4 alkyl and C.sub.1-4 acyl;and a group e) NR.sup.8 R.sup.9 where R.sup.8 and R.sup.9 are as defined above;R.sup.X is hydrogen or an optionally substituted C.sub.1-8 alkyl or benzyl group, their preparation, pesticidal compositions containing them and their use against pests.

    摘要翻译: 本申请公开了式(I)的杀虫活性化合物:Q(CH2)a(O)bQ1CR2 = CR2 = CR3CR4 = CR5 CXNR1Rx或其盐或杀虫剂,其中Q是任选取代的芳族单环或稠合双环体系 其中至少一个环是芳族的,或Q是二卤代乙烯基或R6-C 3BONDC,其中R6是C1-4烷基,三C1-4烷基甲硅烷基,卤素或氢; Q1是任选被一个或多个选自C 1-3烷基,卤素,C 1-3卤代烷基,C 2-3炔基或氰基的基团取代的1,2-环丙基环; 或为(CH 2)7; a = 0或1; b = 0或1; R 2,R 3,R 4和R 5相同或不同,至少一个为氢,其余独立地选自氢,卤素,C 1-4烷基或C 1-4卤代烷基; X是氧或硫; R1是任选被1-5个选自下列的取代基取代的苯基:a)C 1-4烷基,C 1-4烷氧基,苯氧基和亚甲二氧基,各自任选被1至5个卤素取代; b)卤素,氰基,硝基,甲酰基,C 1-5酰基; c)C2-3炔基,C2-3烯基,各自任选被1至5个卤素取代; d)基团S(O)n R 7,其中n = 0,1,2,R 7为C 1-4烷基,卤素或NR 8 R 9,其中R 8和R 9独立地选自氢,C 1-4烷基和C 1-4酰基; 和基团e)NR 8 R 9,其中R 8和R 9如上所定义; RX是氢或任选取代的C 1-8烷基或苄基,它们的制备方法,含有它们的杀虫组合物及其对害虫的用途。