HALOGEN-CONTAINING PERYLENETETRACARBOXYLIC ACID DERIVATIVES AND THE USE THEREOF
    2.
    发明申请
    HALOGEN-CONTAINING PERYLENETETRACARBOXYLIC ACID DERIVATIVES AND THE USE THEREOF 有权
    含有α-烯丙基羧酸的衍生物及其用途

    公开(公告)号:US20130123495A1

    公开(公告)日:2013-05-16

    申请号:US13734460

    申请日:2013-01-04

    Abstract: The invention relates to compounds of the formula (I) in which Y1 and Y2 are each O or, respectively, NRa or NRb, where Ra and Rb are each H or organyl; Z1 to Z4 are each O or S; R11 to R14, R21 to R24 are each Cl, F; where 1 or 2 of the R11 to R14, R21 to R24 radicals may also be CN and/or 1 R11 to R14, R21 to R24 radical may be H; and where, when Y1 is NRa, Z1 or Z2 may also be NRc, where Ra and Rc together are a bridging X group having from 2 to 5 atoms; and where, when Y2 is NRb, Z3 or Z4 may also be NRd, where Rb and Rd together are a bridging X group having from 2 to 5 atoms; to a process for preparation thereof, and to their use as emitter materials, charge transport materials or exciton transport materials.

    Abstract translation: 本发明涉及式(I)化合物,其中Y 1和Y 2各自为O或分别为NR a或NR b,其中R a和R b各自为H或有机基; Z1至Z4各自为O或S; R11〜R14,R21〜R24各自为Cl,F; 其中R11至R14,R21至R24基团中的1或2个也可以是CN和/或1个R11至R14,R21至R24基团可以是H; 并且当Y1是NRa时,Z1或Z2也可以是NRc,其中Ra和Rc一起是具有2至5个原子的桥连X基团; 并且当Y2是NRb时,Z3或Z4也可以是NRd,其中Rb和Rd一起是具有2至5个原子的桥连X基团; 其制备方法,以及它们作为发射体材料,电荷传输材料或激子传输材料的用途。

    TERRYLENE COMPOUNDS, PREPARATION THEREOF AND USE THEREOF IN ORGANIC SOLAR CELLS
    3.
    发明申请
    TERRYLENE COMPOUNDS, PREPARATION THEREOF AND USE THEREOF IN ORGANIC SOLAR CELLS 审中-公开
    叔丁基化合物,其制备及其在有机太阳能电池中的应用

    公开(公告)号:US20120234380A1

    公开(公告)日:2012-09-20

    申请号:US13418989

    申请日:2012-03-13

    Abstract: A terrylene compound of formula I: wherein R1 to R4 are each independently an unsubstituted or substituted alkyl, aryl, thiophenyl or oligothiophenyl group, or a hydrogen atom. Two adjacent radicals selected from R1 to R4, together with the carbon atoms of the benzene ring to which they are bonded, may also form a fused ring system having 1 to 8 additional rings. With the carbon atoms to which it is bonded, A forms a fused monocyclic, dicyclic, tricyclic, tetracyclic, pentacyclic or hexacyclic ring system which optionally contains one or more independently selected substituents. A process for preparing the terrylene compound. An organic solar cell with a photoactive region including at least one organic donor material in contact with at least one organic acceptor material, the donor material and the acceptor material forming a donor-acceptor heterojunction, and the photoactive region including at least one such terrylene compound.

    Abstract translation: 式I的环戊二烯化合物:其中R 1至R 4各自独立地为未取代或取代的烷基,芳基,噻吩基或低聚噻吩基或氢原子。 选自R 1至R 4的两个相邻基团与它们所键合的苯环的碳原子一起也可以形成具有1至8个附加环的稠环体系。 与其键合的碳原子一起形成稠合的单环,二环,三环,四环,五环或六环环系,任选含有一个或多个独立选择的取代基。 一种制备环氧化合物的方法。 一种具有光活性区域的有机太阳能电池,其包括与至少一种有机受体材料接触的至少一种有机供体材料,所述供体材料和受主材料形成供体 - 受体异质结,所述光活性区域包括至少一种这样的亚苄基化合物 。

    Substituted rylene derivatives
    6.
    发明授权
    Substituted rylene derivatives 有权
    取代的二烯衍生物

    公开(公告)号:US08071775B2

    公开(公告)日:2011-12-06

    申请号:US11994719

    申请日:2006-07-06

    CPC classification number: C07D493/06 C07D471/06 C08K5/0041 C08K5/3437

    Abstract: Rylene derivatives of the general formula I in which the variables are each defined as follows: Rylene is a polycyclic conjugated ring system which comprises at least one perylene unit may comprise heteroatoms as ring atoms, may be functionalized by moieties comprising —CO— groups and/or may bear further substituents other than the A radicals; A is a radical of the formula X is oxygen or sulfur; R are identical or different radicals: optionally substituted alkyl, cycloalkyl, aryl, hetaryl, —U-aryl where U is an —O—, —S—, —NR2—, —CO—, —SO— or —SO2— moiety, or C1-C12-alkoxy, C1-C6-alkylthio, —C≡CR2, —CR2═CR22, hydroxy, mercapto, halogen, cyano, nitro, —NR3R4, —NR3COR4, —CONR3R4, —SO2NR3R4, —COOR3 or —SO3R3; R′ are identical or different radicals: hydrogen or one of the R radicals; R2 is hydrogen or alkyl, where the R2 radicals may be the same or different when they occur more than once; R3, R4 are each independently hydrogen; optionally substituted alkyl, aryl or hetaryl; n is from 1 to 8.

    Abstract translation: 通式I的亚芳基衍生物各自定义如下:Rylene是多环共轭环系,其包含至少一个苝单元可以包含杂原子作为环原子,可以由包含-CO-基团和/ 或者可以承担除了A基团之外的其它取代基; A是式X的基团是氧或硫; R是相同或不同的基团:任选取代的烷基,环烷基,芳基,杂芳基,-U-芳基,其中U是-O - , - S - , - NR 2 - , - CO - , - SO-或-SO 2 - 或C 1 -C 12 - 烷氧基,C 1 -C 6烷硫基,-C≡CR2,-CR 2 = CR 22,羟基,巯基,卤素,氰基,硝基,-NR 3 R 4,-NR 3 COR 4,-CONR 3 R 4,-SO 2 NR 3 R 4,-COOR 3或-SO 3 R 3 ; R'是相同或不同的基团:氢或R基团之一; R2是氢或烷基,其中R2基团当它们不止一次出现时可以相同或不同; R3,R4各自独立地为氢; 任选取代的烷基,芳基或杂芳基; n为1至8。

    Substituted Rylene Derivatives
    7.
    发明申请
    Substituted Rylene Derivatives 有权
    取代的Rylene衍生物

    公开(公告)号:US20080167467A1

    公开(公告)日:2008-07-10

    申请号:US11994719

    申请日:2006-07-06

    CPC classification number: C07D493/06 C07D471/06 C08K5/0041 C08K5/3437

    Abstract: Rylene derivatives of the general formula I in which the variables are each defined as follows: Rylene is a polycyclic conjugated ring system which comprises at least one perylene unit may comprise heteroatoms as ring atoms, may be functionalized by moieties comprising —CO— groups and/or may bear further substituents other than the A radicals; A is a radical of the formula X is oxygen or sulfur; R are identical or different radicals: optionally substituted alkyl, cycloalkyl, aryl, hetaryl, —U-aryl where U is an —O—, —S—, —NR2—, —CO—, —SO— or —SO2— moiety, or C1-C12-alkoxy, C1-C6-alkylthio, —C≡CR2, —CR2═CR22, hydroxy, mercapto, halogen, cyano, nitro, —NR3R4, —NR3COR4, —CONR3R4, —SO2NR3R4, —COOR3 or —SO3R3; R′ are identical or different radicals: hydrogen or one of the R radicals; R2 is hydrogen or alkyl, where the R2 radicals may be the same or different when they occur more than once; R3, R4 are each independently hydrogen; optionally substituted alkyl, aryl or hetaryl; n is from 1 to 8.

    Abstract translation: 通式I的亚芳基衍生物各自定义如下:Rylene是多环共轭环系,其包含至少一个苝单元可以包含杂原子作为环原子,可以由包含-CO-基团和/ 或者可以承担除了A基团之外的其它取代基; A是式X的基团是氧或硫; R是相同或不同的基团:任选取代的烷基,环烷基,芳基,杂芳基,-U-芳基,其中U是-O - , - S - , - NR 2 - , - CO-, - SO - 或-SO 2 - 部分,或C 1 -C 12 - 烷氧基,C 1 -C -C≡CR2,-CR 2 -CR 2,2 - , - 羟基,巯基,卤素,氰基,硝基,-NR 3,R 4,-NR 3,COR 4, SO 2,SO 2,SO 2,SO 2,SO 3,SO 4,SO 2, >,-COOR 3或-SO 3 R 3; R'是相同或不同的基团:氢或R基团之一; R 2是氢或烷基,其中R 2个基团当它们不止一次出现时可以相同或不同; R 3,R 4各自独立地为氢; 任选取代的烷基,芳基或杂芳基; n为1至8。

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