Polymers containing functionalized carbon nanotubes

    公开(公告)号:US08992799B2

    公开(公告)日:2015-03-31

    申请号:US11259989

    申请日:2005-10-26

    Abstract: A polymer composite composed of a polymerized mixture of functionalized carbon nanotubes and monomer which chemically reacts with the functionalized nanotubes. The carbon nanotubes are functionalized by reacting with oxidizing or other chemical media through chemical reactions or physical adsorption. The reacted surface carbons of the nanotubes are further functionalized with chemical moieties that react with the surface carbons and selected monomers. The functionalized nanotubes are first dispersed in an appropriate medium such as water, alcohol or a liquefied monomer and then the mixture is polymerized. The polymerization results in polymer chains of increasing weight bound to the surface carbons of the nanotubes. The composite may consists of some polymer chains imbedded in the composite without attachment to the nanotubes. The resulting composite yields superior chemical, physical and electrical properties over polymer composites that are only physically mixed and without binding to the surface carbons of the nanotubes.

    Polyvinylidene fluoride composites and methods for preparing same
    2.
    发明授权
    Polyvinylidene fluoride composites and methods for preparing same 失效
    聚偏二氟乙烯复合材料及其制备方法

    公开(公告)号:US07998369B2

    公开(公告)日:2011-08-16

    申请号:US11841640

    申请日:2007-08-20

    Abstract: An electrically conductive composite comprising a polyvinylidene fluoride polymer or copolymer and carbon nanotubes is provided. Preferably, carbon nanotubes may be present in the range of about 0.5-20% by weight of the composite.The composites are prepared by dissolving the polymer in a first solvent to form a polymer solution and then adding the carbon nanotubes into the solution. The solution is mixed using an energy source such as a sonicator or a Waring blender. A precipitating component is added to precipitate out a composite comprising the polymer and the nanotubes. The composite is isolated by filtering the solution and drying the composite.

    Abstract translation: 提供了包含聚偏二氟乙烯聚合物或共聚物和碳纳米管的导电复合材料。 优选地,碳纳米管可以以该复合材料的约0.5-20重量%的范围存在。 通过将聚合物溶解在第一溶剂中以形成聚合物溶液,然后将碳纳米管加入到溶液中来制备复合材料。 使用诸如超声波发生器或Waring混合器的能量源将溶液混合。 加入沉淀组分以沉淀出包含聚合物和纳米管的复合材料。 通过过滤溶液并干燥复合物来分离复合物。

    Nanowire structures comprising carbon
    4.
    发明授权
    Nanowire structures comprising carbon 有权
    包含碳的纳米线结构

    公开(公告)号:US07939218B2

    公开(公告)日:2011-05-10

    申请号:US11601842

    申请日:2006-11-20

    Applicant: Chunming Niu

    Inventor: Chunming Niu

    Abstract: The present invention is directed to nanowire structures and interconnected nanowire networks comprising such structures, as well as methods for their production. The nanowire structures comprise a nanowire core, a carbon-based layer, and in additional embodiments, carbon-based structures such as nanographitic plates consisting of graphenes formed on the nanowire cores, interconnecting the nanowire structures in the networks. The networks are porous structures that can be formed into membranes or particles. The nanowire structures and the networks formed using them are useful in catalyst and electrode applications, including fuel cells, as well as field emission devices, support substrates and chromatographic applications.

    Abstract translation: 本发明涉及包括这种结构的纳米线结构和互连的纳米线网络,以及它们的生产方法。 纳米线结构包括纳米线芯,碳基层,并且在另外的实施方案中,碳基结构例如由形成在纳米线芯上的石墨烯组成的纳米尺度板,互连网络中的纳米线结构。 网络是可以形成膜或颗粒的多孔结构。 使用它们形成的纳米线结构和网络可用于催化剂和电极应用,包括燃料电池,以及场致发射器件,支撑衬底和色谱应用。

    POLYVINYLIDENE FLUORIDE COMPOSITES AND METHODS FOR PREPARING SAME
    6.
    发明申请
    POLYVINYLIDENE FLUORIDE COMPOSITES AND METHODS FOR PREPARING SAME 失效
    聚亚苄基氟化物复合材料及其制备方法

    公开(公告)号:US20080224101A1

    公开(公告)日:2008-09-18

    申请号:US11841640

    申请日:2007-08-20

    Abstract: An electrically conductive composite comprising a polyvinylidene fluoride polymer or copolymer and carbon nanotubes is provided. Preferably, carbon nanotubes may be present in the range of about 0.5-20% by weight of the composite.The composites are prepared by dissolving the polymer in a first solvent to form a polymer solution and then adding the carbon nanotubes into the solution. The solution is mixed using an energy source such as a sonicator or a Waring blender. A precipitating component is added to precipitate out a composite comprising the polymer and the nanotubes. The composite is isolated by filtering the solution and drying the composite.

    Abstract translation: 提供了包含聚偏二氟乙烯聚合物或共聚物和碳纳米管的导电复合材料。 优选地,碳纳米管可以以该复合材料的约0.5-20重量%的范围存在。 通过将聚合物溶解在第一溶剂中以形成聚合物溶液,然后将碳纳米管加入到溶液中来制备复合材料。 使用诸如超声波发生器或Waring混合器的能量源将溶液混合。 加入沉淀组分以沉淀出包含聚合物和纳米管的复合材料。 通过过滤溶液并干燥复合物来分离复合物。

    Electroconductive Carbon Fibril-based Inks and Coatings
    8.
    发明申请
    Electroconductive Carbon Fibril-based Inks and Coatings 有权
    导电碳纤维基油墨和涂料

    公开(公告)号:US20080111110A1

    公开(公告)日:2008-05-15

    申请号:US11841812

    申请日:2007-08-20

    Abstract: The present invention relates to electroconductive inks and methods of making and using the same. The electroconductive inks include carbon fibrils and a liquid vehicle. The electroconductive ink may further include a polymeric binder. The electroconductive filler used is carbon fibrils which may be oxidized. The ink has rheological properties similar to that of commercially available electroconductive inks that use carbon black as their filler. The ink can be screen-printed, slot-coated, sprayed, brushed or dipped onto a wide variety of substrates to form an electroconductive coating.

    Abstract translation: 本发明涉及导电油墨及其制造和使用方法。 导电油墨包括碳纤维和液体载体。 导电油墨还可以包括聚合物粘合剂。 所用的导电填料是可被氧化的碳原子纤维。 油墨具有类似于使用炭黑作为填料的市售导电油墨的流变性能。 油墨可以丝网印刷,槽涂,喷涂,刷涂或浸在各种基材上以形成导电涂层。

    Nano-Enabled Memory Devices and Anisotropic Charge Carrying Arrays
    10.
    发明申请
    Nano-Enabled Memory Devices and Anisotropic Charge Carrying Arrays 审中-公开
    具有纳米功能的存储器件和各向异性电荷携带阵列

    公开(公告)号:US20080026532A1

    公开(公告)日:2008-01-31

    申请号:US11850127

    申请日:2007-09-05

    Abstract: Methods and apparatuses for nanoenabled memory devices and anisotropic charge carrying arrays are described. In an aspect, a memory device includes a substrate, a source region of the substrate, and a drain region of the substrate. A population of nanoelements is deposited on the substrate above a channel region, the population of nanolements in one embodiment including metal quantum dots. A tunnel dielectric layer is formed on the substrate overlying the channel region, and a metal migration barrier layer is deposited over the dielectric layer. A gate contact is formed over the thin film of nanoelements. The nanoelements allow for reduced lateral charge transfer. The memory device may be a single or multistate memory device. In a multistate memory device which comprises one or more quantum dots or molecules having a plurality of discrete energy levels, a method is disclosed for charging and/or discharging the device which comprises filling each of the plurality of discrete energy levels of each dot or molecule with one or more electrons, and subsequently removing individual electrons at a time from each discrete energy level of the one or more dots or molecules.

    Abstract translation: 描述了用于纳米存储器件和各向异性带电载体阵列的方法和装置。 在一方面,存储器件包括衬底,衬底的源极区域和衬底的漏极区域。 纳米元素的群体沉积在通道区域上方的衬底上,在一个实施方案中纳米的群体包括金属量子点。 隧道介电层形成在覆盖沟道区的衬底上,金属迁移势垒层沉积在电介质层上。 在纳米元件的薄膜上形成栅极接触。 纳米元件允许减少横向电荷转移。 存储器件可以是单个或多个存储器件。 在包括具有多个离散能级的一个或多个量子点或分子的多状态存储器件中,公开了一种用于对该器件进行充电和/或放电的方法,该方法包括填充每个点或分子的多个离散能级中的每一个 与一个或多个电子,并随后从一个或多个点或分子的每个离散能级一次去除单个电子。

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