摘要:
In accordance with the present invention, there is provided a solid organoaluminoxy product prepared by reacting an organoaiuminoxane with an oxygen-containing compound selected from the group consisting of organic peroxide, alkylene oxide, or organic carbonate. Further there is provided olefin polymerization catalyst systems comprising the solid organoaluminoxy product and a transition metal-containing catalyst. Still further there is provided processes for the polymerization of olefins using the catalyst systems.
摘要:
The present invention relates to new trichlorosilylamino-alanes, new aluminosilazane compounds, new oligo or polyaluminosilazane compounds having the structural feature .tbd.Si--NH--Al, a silicon-aluminium nitride ceramic powder, ceramic material based on SiN and AlN, processes for the preparation of these substances and the use of the polyaluminosilazanes and of the ceramic materials.
摘要:
A preceramic polymetalosilazane substantially free of Si-O groups is produced by reacting a polysilazane with a metal alkoxide in the presence of an alkylsilazane or alkylsilane. The preceramic polymer gives a high strength and heat resistant ceramic body which remains amorphous when calcined at 1,600.degree. C. for 10 hours in the atmosphere of nitrogen.
摘要:
Glassy coatings are made by curing in situ a coating of a sol gel of tetraethoxysilicon, water, alcohol, and the alkoxides of: Al, Ti and Na; or of Na and Zr.The coating may be applied to teeth as a dental fissure sealant or varnish to protect restorations, or (if filled) as an inherently coloured cosmetic coating, or as a prophylactic coating.
摘要:
Polymethylaluminoxane compositions having increased solution stability in organic solvent and, in some cases, increased polymerization activity, which comprise moieties derived from an organic compound containing an electron-rich heteroatom (e.g., from Group V and/or Group VI of the Periodic Table) and a hydrocarbyl moiety. These compositions can be formed by reaction of trimethylaluminum, the organic compound, and water. They can also be formed by reaction of pre-formed polymethylaluminoxane the organic compound, which can be a hydrocarbyl group-containing compound containing an electron-rich heteroatom (e.g., oxygen, nitrogen, or sulfur), either with or without an active hydrogen atom connected to the heteroatom. The organic compound, in some embodiments, has also been found to be effective in increasing the catalytic activity of modified polymethylaluminoxane which, in addition to methyl, contain C.sub.2 and higher alkyl groups for enhanced solution stability.
摘要:
An aluminum-nitrogen polymer is prepared by reacting an organic nitrile with a dialkylaluminum hydride to form an organoaluminum imine, and heating the imine to a temperature of 50.degree. to 200.degree. C. The polymeric product can be subjected to an additional heat treatment to form a more highly cross-linked polymer. After either heat treatment the polymeric product can be further reacted with a primary amine or ammonia. The organoaluminum imine as well as the aminated or non-aminated polymers can be pyrolyzed to form an aluminum nitride-containing ceramic.
摘要:
The present invention relates to polymeric boro- and aluminosilazanes corresponding to the general formula[(SiL.sub.2).sub.a (AlL.sub.2).sub.1-a L.sub.2 ].sub.xand[(SiL.sub.2).sub.a (BL).sub.1-a L.sub.2 ].sub.x,whereina=0-1whereinL means half a bridging --NR-group, or an organoamino (--NR) group, when L is attached to a silicon or aluminum atom, and wherein L means a hydrogen atom, half a bridging --NR-- group or an organoamino (--NR) group, when L is attached to a boron atom,in which each silicon and aluminum atom is triply coordinated by four nitrogen atoms and each boron atom by at least two nitrogen and at most one hydrogen atom, a process for the preparation of these polymers and their use as precursor compounds for ceramic high performance materials.
摘要:
An organic-inorganic polycondensate characterized by the fact that it satisfies the following formula:C.sub.v H.sub.w O.sub.x Si.sub.y Me.sub.zwhere:v=4 to 48w=5 to 52x=5 to 48y=2 to 16z=1the ratio v/(y+z) being less than 7;C.sub.v H.sub.w being a carbon-containing chain carried by silicon; andMe being a metal or a mixture of metals chosen from groups IVA, VA, VIA, IIIB, and IVB of the periodic table of elements.
摘要翻译:其特征在于其满足下式的有机 - 无机缩聚物:CvHwOxSiyMez其中:v = 4至48w = 5至52×= 5至48y = 2至16z = 1 v /(y + z )小于7; CvHw是由硅承载的含碳链; 和Me是选自元素周期表IVA,VA,VIA,IIIB和IVB族的金属或金属的混合物。
摘要:
Copolymers comprising 1-50 mole % of sulfur dioxide and 50-99 mole % of trialkylgermylstyrene, having a weight average molecular weight of 500-10,000,000 and exhibiting a high sensitivity to light, electron beam, and X-ray, as well as having an excellent anti-dry etching resistance, and their application as a positive resisting material.
摘要:
This invention relates to a new class of novel inorganic-organic hybrid polymers that are formed from linear inorganic-organic hybrid polymers of varying molecular weight. These new high temperature oxidatively stable thermosetting polymers are formed from linear polymeric materials having repeat units that contain at least one alkynyl group for cross-linking purposes and at least one bis(silyl or siloxanyl)carboranyl group. These novel organoboron thermoset polymers contain an unsaturated cross-linked hydrocarbon moiety.