公开(公告)号：US20110177255A1

公开(公告)日：2011-07-21

申请号：US12085985

申请日：2006-03-24

Applicant: Jas Pal Singh Badyal ,  James McGettrick ,  Wayne Christopher Edward Schofield

Inventor： Jas Pal Singh Badyal ,  James McGettrick ,  Wayne Christopher Edward Schofield

IPC: B05D3/06

CPC classification number: B05D1/62 ,  C23C18/1851 ,  C23C18/2006 ,  C23C18/42 ,  D06M10/025 ,  D06M10/08 ,  D06M14/18 ,  D06M14/20 ,  D06M14/26 ,  G01N33/54353 ,  G01N33/54393

Abstract: A method is provided for applying a reactive aldehyde containing coating to a substrate. The method includes subjecting a substrate to a plasma discharge in the presence of a compound of formula (I): Where X is an optionally substituted straight or branched alkylene chain(s) or aryl group(s); R1, R2 or R3 are optionally substituted hydrocarbyl or heterocyclic groups, and m is an integer greater than 0.

Abstract translation: 提供了一种将含活性醛的涂层施加到基底上的方法。 该方法包括在式（I）化合物存在下对衬底进行等离子体放电：其中X是任选取代的直链或支链亚烷基链或芳基; R1，R2或R3是任选取代的烃基或杂环基，m是大于0的整数。

公开(公告)号：US20110045200A1

公开(公告)日：2011-02-24

申请号：US12545664

申请日：2009-08-21

Applicant: Tien-Hsiang Hsueh ,  Mien-Win Wu ,  Chi-Fong Ai

Inventor： Tien-Hsiang Hsueh ,  Mien-Win Wu ,  Chi-Fong Ai

IPC: C08J7/18

CPC classification number: B05D3/142 ,  C08J7/18 ,  C08J2427/12 ,  D06M10/025 ,  D06M14/18 ,  D06M14/22 ,  D06M14/26 ,  D06M14/28 ,  D06M14/32 ,  D06M14/34 ,  D06M2200/11 ,  D06M2200/12

Abstract: The present invention fabricates a hydrophobic and oleophobic polymer fabric through two stages of modification using atmospheric plasmas. The modified fabric has a rough surface and a fluorocarbon functional group having the lowest surface free energy. The fabric has a grafted fluorocarbon monomer layer to enhance the graft efficiency of the fluorocarbon functional groups and its wash fastness. The atmospheric plasmas can be mass produced and less expensively. Hence, the present invention can rapidly modify surfaces of polymeric materials with low cost and good environment protection.

Abstract translation: 本发明通过使用大气等离子体的两个修改阶段制造疏水和疏油聚合物织物。 改性织物具有粗糙表面和具有最低表面自由能的氟碳官能团。 织物具有接枝的氟碳单体层，以提高碳氟化合物官能团的接枝效率及其耐洗牢度。 大气等离子体可以批量生产，而且成本较低。 因此，本发明可以以低成本和良好的环境保护快速地改变聚合物材料的表面。

公开(公告)号：US20100189915A1

公开(公告)日：2010-07-29

申请号：US12754943

申请日：2010-04-06

Applicant: Douglas Eugene Weiss ,  Clinton Pierce Waller, JR.

Inventor： Douglas Eugene Weiss ,  Clinton Pierce Waller, JR.

IPC: C08F2/54

CPC classification number: B32B5/24 ,  B01D39/1623 ,  B01D39/1692 ,  B01D67/0018 ,  B01D67/0093 ,  B01D71/34 ,  B01D2239/0414 ,  B01D2239/0478 ,  B01D2239/10 ,  B01D2323/02 ,  B01D2323/30 ,  B01D2323/34 ,  B05D1/42 ,  B05D3/068 ,  B05D7/04 ,  B05D7/52 ,  B05D7/56 ,  B32B5/022 ,  B32B7/06 ,  B32B27/08 ,  B32B27/12 ,  B32B27/304 ,  B32B27/36 ,  B32B2262/0223 ,  B32B2262/0238 ,  B32B2307/728 ,  C08J7/16 ,  C08J7/18 ,  C08J9/405 ,  C08J2327/16 ,  D01D5/0985 ,  D01F6/12 ,  D01F6/30 ,  D01F6/34 ,  D04H1/56 ,  D06M14/02 ,  D06M14/08 ,  D06M14/10 ,  D06M14/18 ,  D06M14/20 ,  D06M14/26 ,  D06M14/28 ,  Y10T428/249987 ,  Y10T428/249991 ,  Y10T428/249992 ,  Y10T428/249993

Abstract: Functionalized substrates, methods of making functionalized substrates, and methods of using functionalized substrates are disclosed.

Abstract translation: 公开了功能化基材，制备官能化基材的方法和使用官能化基材的方法。

公开(公告)号：US20090170391A1

公开(公告)日：2009-07-02

申请号：US12161038

申请日：2007-01-19

Applicant: Stephen Coulson

Inventor： Stephen Coulson

IPC: B32B27/12 ,  D06M10/10 ,  B32B37/00

CPC classification number: D06M10/003 ,  B05D1/62 ,  B05D2256/00 ,  D06M10/025 ,  D06M13/03 ,  D06M14/18 ,  D06M15/227 ,  D06M15/263 ,  D06M23/00 ,  D06M2200/25 ,  Y10T442/2762 ,  Y10T442/2861

Abstract: An item selected from a piece of fashion clothing, a clothing accessory or a household textile having a polymeric coating, formed by exposing said item or a material or yarn from which the item is subsequently constructed, to a pulsed plasma comprising a compound of formula (I) where R1, R2, R3 and l4 are defined in the specification for a sufficient period of time to allow a polymeric layer to form on the surface of the item or yarn. Items of this type are protected from contamination by a wide number of liquids, including environmental hazards such as rain water and water-based liquids as well as some oily liquids. They are also fade and odour resistant.

Abstract translation: 选自具有聚合物涂层的一件时尚服装，衣服配件或家用纺织品的物品，其通过将所述物品或随后构建该物品的材料或纱线暴露于包含式（ I）其中R1，R2，R3和14在说明书中限定足够的时间以允许聚合物层在物品或纱线的表面上形成。 这种类型的物品可以免受大量液体的污染，包括诸如雨水和水性液体等环境危害以及一些油性液体。 它们也具有褪色和抗气味。

公开(公告)号：US20080107822A1

公开(公告)日：2008-05-08

申请号：US11556130

申请日：2006-11-02

Applicant: Gary S. Selwyn ,  Matthew R. Barnes ,  Caterina Vidoli ,  Heathcliff L. Vaz

Inventor： Gary S. Selwyn ,  Matthew R. Barnes ,  Caterina Vidoli ,  Heathcliff L. Vaz

IPC: H05H1/00 ,  B05B5/00

CPC classification number: C23C16/50 ,  D06B19/00 ,  D06C29/00 ,  D06M10/10 ,  D06M14/18 ,  D06M15/277 ,  D21H19/16 ,  D21H19/32 ,  D21H23/44 ,  D21H25/04

Abstract: An apparatus and method for plasma finishing of fibrous materials including paper and knitted, woven and non-woven fibrous substrates such that desired characteristics are imparted are described. The method includes depositing a monomer comprising at least one fluorocarbon monomer with chemical additives, as required, at atmospheric pressure onto the paper or knitted, woven or non-woven substrate; exposing the monomer on a single surface of the fibrous material to an inert gas, atmospheric-pressure plasma, thereby causing polymerization of the monomer species; and repeating this sequence using multiple sequential deposition and plasma discharge steps to create a layered surface having durability against abrasion for both water-based laundry methods and dry-cleaning methods, and normal wear, without affecting the feel, drape, appearance or breathability of the substrate material. The present method uses a high-power, continuously operating plasma that is 104 times more powerful than the prior art plasma sources utilized in the textile industry, and produces a durable finish with between 0.5 and 2 s of plasma exposure. This is sufficiently rapid to meet commercial fabric processing throughput, and repeated cleaning of the electrodes is not required.

Abstract translation: 描述了赋予纤维材料的等离子体整理的装置和方法，包括纸和针织，机织和非织造纤维基材，从而赋予所需的特性。 该方法包括在大气压下将包含至少一种碳氟单体的单体与化学添加剂按需要沉积到纸或针织，机织或非编织基材上; 将单体在纤维材料的单个表面上暴露于惰性气体，大气压等离子体，从而引起单体物质的聚合; 并且使用多个顺序沉积和等离子体放电步骤重复该顺序，以产生具有耐水性的洗涤方法和干洗方法和正常磨损的耐磨性的层压表面，而不会影响鞋底的手感，悬垂性，外观或透气性 基材。 本发明的方法使用比在纺织工业中使用的现有技术的等离子体源强大10倍以上的大功率，连续工作的等离子体，并产生0.5秒和2秒之间的耐久光洁度 等离子体暴露 这足以快速满足商业织物加工产量，并且不需要反复清洁电极。

公开(公告)号：US20070202315A1

公开(公告)日：2007-08-30

申请号：US11568910

申请日：2005-05-13

Applicant: Paul Duffield ,  Andrew Goodwin ,  Stuart Leadley ,  Malcolm McKechine ,  Liam O'Neill ,  Simon Pugh

Inventor： Paul Duffield ,  Andrew Goodwin ,  Stuart Leadley ,  Malcolm McKechine ,  Liam O'Neill ,  Simon Pugh

IPC: C23C8/00 ,  B32B27/00

CPC classification number: D06M10/025 ,  A47L13/16 ,  A61L2/18 ,  A61L2/186 ,  A61L2202/11 ,  A61L2202/17 ,  C11D17/049 ,  D06B19/00 ,  D06M10/04 ,  D06M10/08 ,  D06M10/10 ,  D06M13/463 ,  D06M13/477 ,  D06M14/18 ,  D06M14/26 ,  D06M14/32 ,  D06M16/00 ,  D06M23/02 ,  D06M23/12 ,  Y10T428/249953 ,  Y10T428/31504

Abstract: A method is provided for forming an active material containing coating on a substrate. The substrate is suitably a wipe, cloth or sponge for household use, or a water-soluble household cleaning unit dose product. The method comprises the steps of: i) introducing one or more gaseous or atomised liquid and/or solid coating-forming materials which undergo chemical bond forming reactions within a plasma environment and one or more active materials which substantially do not undergo chemical bond forming reactions within a plasma environment, into an atmospheric or low pressure plasma discharge and/or an excited gas stream resulting therefrom, and ii) exposing the substrate to the resulting mixture of atomised coating-forming and at least one active material which are deposited onto the substrate surface to form a coating.

Abstract translation: 提供了一种用于在基底上形成含有活性材料的涂层的方法。 基材适合用于家用的擦拭物，布或海绵，或水溶性家用清洁剂剂量产品。 该方法包括以下步骤：i）引入在等离子体环境内进行化学键形成反应的一种或多种气态或雾化的液体和/或固体涂层形成材料以及基本上不经历化学键形成反应的一种或多种活性材料 在等离子体环境中进入大气压或低压等离子体放电和/或由此产生的激发气流，以及ii）将基底暴露于所形成的雾化涂层形成的混合物和沉积在基底上的至少一种活性材料 表面形成涂层。

公开(公告)号：US20070093076A1

公开(公告)日：2007-04-26

申请号：US11633995

申请日：2006-12-05

Applicant: Michael Mikhael ,  Richard Ellwanger ,  Angelo Yializis

Inventor： Michael Mikhael ,  Richard Ellwanger ,  Angelo Yializis

IPC: H01L21/47

CPC classification number: B05D1/62 ,  B05D1/60 ,  B05D3/0254 ,  B05D3/0263 ,  B05D3/06 ,  B05D3/067 ,  B05D3/068 ,  B05D3/142 ,  B05D3/147 ,  B05D5/083 ,  B05D7/04 ,  B05D2252/02 ,  C23C16/30 ,  C23C16/509 ,  D06M10/025 ,  D06M10/08 ,  D06M10/10 ,  D06M14/18 ,  D21H21/16 ,  D21H23/50 ,  H01J37/32009 ,  H01J37/32018 ,  H01J37/3244 ,  H01J37/32449 ,  H01J37/32532 ,  H01J37/32724 ,  H01J37/32825 ,  H01L21/312 ,  H05H1/2406 ,  H05H2001/2412

Abstract: A plasma is produced in a treatment space (58) by diffusing a plasma gas at atmospheric pressure and subjecting it to an electric field created by two metallic electrodes (54,56) separated by a dielectric material (64), and a precursor material is introduced into the treatment space to coat a substrate film or web (14) by vapor deposition or atomized spraying at atmospheric pressure. The deposited precursor exposed to an electromagnetic field (AC, DC, or plasma) and then it is cured by electron-beam, infrared-light, visible-light, or ultraviolet-light radiation, as most appropriate for the particular material being deposited. Additional plasma post-treatment may be used to enhance the properties of the resulting coated products.

Abstract translation: 在处理空间（58）中产生等离子体，通过在大气压下扩散等离子体气体并使其受到由电介质材料（64）分开的两个金属电极（54,56）产生的电场，前体材料是 通过在大气压下气相沉积或雾化喷雾而引入处理空间以涂覆基底膜或网（14）。 暴露于电磁场（AC，DC或等离子体）中的沉积的前驱物，然后通过电子束，红外光，可见光或紫外光辐射固化，最适合于沉积的特定材料。 可以使用额外的等离子体后处理来增强所得涂覆产品的性能。

公开(公告)号：US07157117B2

公开(公告)日：2007-01-02

申请号：US10830608

申请日：2004-04-23

Applicant: Michael G. Mikhael ,  Angelo Yializis

Inventor： Michael G. Mikhael ,  Angelo Yializis

IPC: C23C16/00

CPC classification number: B01D71/022 ,  B01D39/1623 ,  B01D39/18 ,  B01D39/2017 ,  B01D39/2065 ,  B01D67/0072 ,  B01D67/0088 ,  B01D67/009 ,  B01D71/02 ,  B01D2239/0241 ,  B01D2239/0414 ,  B01D2239/0421 ,  B01D2239/0428 ,  B01D2239/045 ,  B01D2239/0457 ,  B01D2239/0478 ,  B01D2239/0492 ,  B01D2239/065 ,  B01D2239/10 ,  B01D2239/1291 ,  B01D2325/04 ,  B01D2325/26 ,  B01D2325/30 ,  B01D2325/36 ,  B01D2325/38 ,  B05D1/60 ,  B05D3/142 ,  B05D3/144 ,  C23C8/02 ,  C23C8/20 ,  C23C8/80 ,  C23C28/00 ,  C23C30/00 ,  D04H1/42 ,  D06M10/025 ,  D06M10/08 ,  D06M14/18 ,  Y10T428/249953 ,  Y10T428/249956 ,  Y10T428/249987 ,  Y10T428/24999

Abstract: A porous substrate is pretreated in a plasma field and a functionalizing monomer is immediately flash-evaporated, deposited and cured over the porous substrate in a vacuum vapor-deposition chamber. By judiciously controlling the process so that the resulting polymer coating adheres to the surface of individual fibers in ultra-thin layers (approximately 0.02–3.0 μm) that do not extend across the pores in the material, the porosity of the porous substrate is essentially unaffected while the fibers and the final product acquire the desired functionality. The resulting polymer layer is also used to improve the adherence and durability of metallic and ceramic coatings.

公开(公告)号：US20060257642A9

公开(公告)日：2006-11-16

申请号：US10830608

申请日：2004-04-23

Applicant: Michael Mikhael ,  Angelo Yializis

Inventor： Michael Mikhael ,  Angelo Yializis

IPC: B05D1/08 ,  B32B3/26 ,  B32B9/00

CPC classification number: B01D71/022 ,  B01D39/1623 ,  B01D39/18 ,  B01D39/2017 ,  B01D39/2065 ,  B01D67/0072 ,  B01D67/0088 ,  B01D67/009 ,  B01D71/02 ,  B01D2239/0241 ,  B01D2239/0414 ,  B01D2239/0421 ,  B01D2239/0428 ,  B01D2239/045 ,  B01D2239/0457 ,  B01D2239/0478 ,  B01D2239/0492 ,  B01D2239/065 ,  B01D2239/10 ,  B01D2239/1291 ,  B01D2325/04 ,  B01D2325/26 ,  B01D2325/30 ,  B01D2325/36 ,  B01D2325/38 ,  B05D1/60 ,  B05D3/142 ,  B05D3/144 ,  C23C8/02 ,  C23C8/20 ,  C23C8/80 ,  C23C28/00 ,  C23C30/00 ,  D04H1/42 ,  D06M10/025 ,  D06M10/08 ,  D06M14/18 ,  Y10T428/249953 ,  Y10T428/249956 ,  Y10T428/249987 ,  Y10T428/24999

Abstract: A porous substrate is pretreated in a plasma field and a functionalizing monomer is immediately flash-evaporated, deposited and cured over the porous substrate in a vacuum vapor-deposition chamber. By judiciously controlling the process so that the resulting polymer coating adheres to the surface of individual fibers in ultra-thin layers (approximately 0.02-3.0 μm) that do not extend across the pores in the material, the porosity of the porous substrate is essentially unaffected while the fibers and the final product acquire the desired functionality. The resulting polymer layer is also used to improve the adherence and durability of metallic and ceramic coatings.

Abstract translation: 多孔基材在等离子体场中进行预处理，并且在真空气相沉积室中立即将功能化单体快速蒸发，沉积并固化在多孔基材上。 通过明智地控制该方法，使得所得到的聚合物涂层附着在不延伸穿过材料孔隙的超薄层（大约0.02-3.0μm）中的单个纤维的表面上，多孔基材的孔隙率基本上不受影响 而纤维和最终产品获得所需的功能。 所得聚合物层也用于改善金属和陶瓷涂层的粘附性和耐久性。

公开(公告)号：US20060240648A1

公开(公告)日：2006-10-26

申请号：US11448966

申请日：2006-06-07

Applicant: Michael Mikhael ,  Angelo Yializis ,  Richard Ellwanger

Inventor： Michael Mikhael ,  Angelo Yializis ,  Richard Ellwanger

IPC: H01L21/20

CPC classification number: H01L21/02118 ,  B05D1/60 ,  B05D1/62 ,  B05D3/0254 ,  B05D3/0263 ,  B05D3/06 ,  B05D3/067 ,  B05D3/068 ,  B05D3/142 ,  B05D3/147 ,  B05D5/083 ,  B05D7/04 ,  B05D2252/02 ,  C23C16/30 ,  C23C16/509 ,  D06M10/025 ,  D06M10/08 ,  D06M10/10 ,  D06M14/18 ,  D21H21/16 ,  D21H23/50 ,  H01J37/32009 ,  H01J37/32018 ,  H01J37/3244 ,  H01J37/32449 ,  H01J37/32532 ,  H01J37/32724 ,  H01J37/32825 ,  H01L21/02274 ,  H01L21/0234 ,  H01L21/02345 ,  H01L21/02348 ,  H01L21/02351 ,  H01L21/312 ,  H05H1/2406 ,  H05H2001/2412

Abstract: A plasma is produced in a treatment space (58) by diffusing a plasma gas at atmospheric pressure and subjecting it to an electric field created by two metallic electrodes (54,56) separated by a dielectric material (64), a precursor material is introduced into the treatment space to coat a substrate film or web (14) by vapor deposition or atomized spraying at atmospheric pressure. The deposited precursor is cured by electron-beam, infrared-light, visible-light, or ultraviolet-light radiation, as most appropriate for the particular material being deposited. Additional plasma post-treatment may be used to enhance the properties of the resulting coated products.

Abstract translation: 在处理空间（58）中产生等离子体，通过在大气压下扩散等离子体气体并使其受到由介电材料（64）分开的两个金属电极（54,56）产生的电场，引入前体材料 进入处理空间以通过气相沉积或在大气压下的雾化喷涂来涂覆基底膜或网（14）。 沉积的前体通过电子束，红外光，可见光或紫外光辐射固化，最适合于沉积的特定材料。 可以使用额外的等离子体后处理来增强所得涂覆产品的性能。