摘要:
A novel class of organometallic complexes can be used as an ingredient of a catalyst system. The catalyst system can be used in polymerizations of ethylenically unsaturated hydrocarbon monomers that include both olefins and polyenes.
摘要:
A method for preparing a functionalized polymer, the method comprising the steps of: (i) polymerizing monomer with a coordination catalyst to form a reactive polymer; and (ii) reacting the reactive polymer with a nitroso compound.
摘要:
A method for preparing a functionalized polymer, the method comprising the steps of: (i) polymerizing monomer to form a reactive polymer; and (ii) reacting the reactive polymer with a protected hydrazone compound containing an acyl group.
摘要:
A method of making a heterogenously supported catalyst useful in dimerization, oligomerization or polymerization is provided in which a catalyst precursor containing a metal and an aromatic group are alkylated onto an oligomeric support having at least one terminal unsaturated group by Friedel Crafts alkylation.
摘要:
The present invention provides a method for synthesizing a polybutadiene more efficiently and stably which is possible to obtain a rubber composition and a tire excellent in durability (fracture resistance, wear resistance and crack growth resistance). A method for producing a polybutadiene, where a butadiene monomer is polymerized with the existence of rare-earth element compounds represented by the following formula (i): M-(NQ)1(NQ)2(NQ)3 (i) (in the formula, M is at least one selected from lanthanides, scandium and yttrium; (NQ)1, (NQ)2 and (NQ)3 are amide groups which may be the same or different to each other, and have M-N bonds).
摘要:
The present invention provides rubber compositions for tires capable of providing tire components and pneumatic tires having low-temperature properties and abrasion resistance that are equivalent to those of tire components and pneumatic tires formed from conventional synthetic rubber, respectively, while meeting the demand for a sound material-cycle society. The present invention relates to rubber compositions for tires containing a biomass-derived rubber obtained by polymerizing a biomass-derived monomer component, the biomass-derived rubber having a pMC (percent modern carbon) value of 1% or greater as determined in conformity with ASTM D6866-10, and having a Tg (glass transition temperature) value of −120° C. to −80° C.
摘要:
A process for preparing a polydiene, the process comprising the step of: polymerizing conjugated diene monomer in the presence of a (hydrocarbyloxyhydrocarbyl)amine, where said step of polymerizing employs a lanthanide-based catalyst system.
摘要:
A cured elastomer is formed by partially crosslinking an elastomer compound containing first and second free radical initiators at a first crosslinking temperature T1, then further crosslinking at a second crosslinking temperature T2. Either: (i) the first free radical initiator's half-life is about 0.2-5 minutes at T1, the second free radical initiator's half-life is about 0.2-5 minutes at T2, and T2 is higher than T1 by at least about 30° C.; or (ii) the second free radical initiator's one-minute half-life temperature is higher than the first free radical initiator's one-minute half-life temperature by at least about 30° C., T1 is within about 20° C. of the first one-minute half-life temperature, and T2 is within about 20° C. of the second one-minute half-life temperature.
摘要:
The invention relates to a high-molecular-weight, linear, neodymium-catalysed polybutadiene having a high proportion, >95%, of cis-1,4 units having a low proportion,
摘要:
The invention relates to a high-molecular-weight, linear, neodymium-catalysed polybutadiene having a high proportion, >95%, of cis-1,4 units having a low proportion,