公开(公告)号：US20170354961A1

公开(公告)日：2017-12-14

申请号：US15179032

申请日：2016-06-10

Applicant: ExxonMobil Research and Engineering Company

Inventor： Paul Podsiadlo ,  Quanchang Li ,  David C. Calabro ,  Kiara M. Benitez ,  Machteld M.W. Mertens ,  Scott J. Weigel ,  Doron Levin ,  Randall D. Partridge

IPC: B01J31/26 ,  C10G47/16 ,  C10G45/54 ,  B01J29/70 ,  B01J31/12 ,  B01J35/00 ,  B01J37/00 ,  C10G45/64

CPC classification number: B01J31/26 ,  B01J29/40 ,  B01J29/44 ,  B01J29/70 ,  B01J29/703 ,  B01J29/7038 ,  B01J29/7461 ,  B01J29/7476 ,  B01J31/125 ,  B01J31/127 ,  B01J35/0006 ,  B01J37/0009 ,  B01J2229/32 ,  B01J2229/36 ,  B01J2229/42 ,  B01J2231/641 ,  B01J2231/646 ,  C10G45/54 ,  C10G45/64 ,  C10G47/16

Abstract: Catalysts including at least one microporous material (e.g., zeolite), an organosilica material binder, and at least one catalyst metal are provided herein. Methods of making the catalysts, preferably without surfactants and processes of using the catalysts, e.g., for aromatic hydrogenation, are also provided herein.

公开(公告)号：US20170326536A1

公开(公告)日：2017-11-16

申请号：US15458437

申请日：2017-03-14

Applicant: KING FAHD UNIVERSITY OF PETROLEUM AND MINERALS

Inventor： Abiola Azeez JIMOH ,  Abdul Malik Peedikakkal

IPC: B01J31/12 ,  C07F3/06 ,  C07F1/08 ,  C07C51/285 ,  C07C45/29 ,  C07C27/16 ,  B01J35/10 ,  C07F15/02

CPC classification number: B01J31/123 ,  B01J35/002 ,  B01J35/1023 ,  B01J35/1028 ,  B01J35/1057 ,  B01J35/1061 ,  C07C27/16 ,  C07C29/48 ,  C07C45/28 ,  C07C45/294 ,  C07C51/285 ,  C07C2101/14 ,  C07C2601/14 ,  C07F1/08 ,  C07F3/06 ,  C07F15/025 ,  C07C35/08 ,  C07C49/403 ,  C07C47/54 ,  C07C63/06

Abstract: A metal organic framework comprising zinc (II) ions and second metal ions, such as iron (II) ions, cobalt (II) ions, and copper (II) ions as nodes or clusters and coordinated 1,3,5-benzenetricarboxylic acid struts or linkers between them forming a porous coordination network in the form of polyhedral crystals that are isostructural to HKUST-1. Transmetallation processes for producing the metal organic frameworks, as well as methods for applications of the metal organic frameworks as catalysts, specifically catalysts for the oxidation of cyclic hydrocarbons, such as toluene, cyclohexane, and methylcyclohexane.

公开(公告)号：US20170283356A1

公开(公告)日：2017-10-05

申请号：US15627515

申请日：2017-06-20

Applicant: Chevron Phillips Chemical Company LP

Inventor： Mark L. Hlavinka ,  Max P. McDaniel ,  Pasquale Iacono

IPC: C07C51/15 ,  B01J31/22 ,  C07C51/377 ,  C07C57/04 ,  B01J31/14 ,  B01J31/38 ,  C07C51/09 ,  B01J31/26 ,  B01J31/12

CPC classification number: C07C51/15 ,  B01J31/128 ,  B01J31/143 ,  B01J31/2234 ,  B01J31/2295 ,  B01J31/26 ,  B01J31/38 ,  B01J2231/321 ,  B01J2231/46 ,  B01J2531/847 ,  C07C51/09 ,  C07C51/377 ,  C07C57/04

Abstract: Processes for producing an α,β-unsaturated carboxylic acid, such as acrylic acid, or a salt thereof, using treated solid oxides are disclosed. The treated solid oxides can be calcined solid oxides, metal-treated solid oxides, or metal-treated chemically-modified solid oxides, illustrative examples of which can include sodium-treated alumina, calcium-treated alumina, zinc-treated alumina, sodium-treated sulfated alumina, sodium-treated fluorided silica-coated alumina, and similar materials.

公开(公告)号：US09751981B2

公开(公告)日：2017-09-05

申请号：US14917219

申请日：2014-10-30

Applicant: LG CHEM, LTD.

Inventor： Sung-Kyoung Kim ,  Seung Young Park ,  Hyun Ju Cho

IPC: C08G64/34 ,  C07C51/41 ,  B01J31/12 ,  C08K5/00

CPC classification number: C08G64/34 ,  B01J31/12 ,  C07C51/412 ,  C08K5/0091

Abstract: The present invention relates to a manufacturing method of an organic zinc catalyst having more uniform and finer particle size and showing a more improved activity in a polymerization process for manufacturing a polyalkylene carbonate resin, and a manufacturing method of the polyalkylene carbonate resin using the organic zinc catalyst obtained by the manufacturing method of the organic zinc catalyst, the manufacturing method of an organic zinc catalyst including: forming a zinc dicarboxylate-based catalyst by reacting a zinc precursor with C3-C20 dicarboxylic acid, wherein the reaction step is performed under a condition in which the number of moles of the dicarboxylic acid is more than that of the zinc precursor in a reaction system, throughout the entire reaction step.

公开(公告)号：US09725393B2

公开(公告)日：2017-08-08

申请号：US15091794

申请日：2016-04-06

Applicant: Chevron Phillips Chemical Company LP

Inventor： Mark L. Hlavinka ,  Max P. McDaniel ,  Pasquale Iacono

IPC: C07C51/15 ,  C07C51/377 ,  B01J31/12 ,  B01J31/14 ,  B01J31/22 ,  B01J31/26 ,  B01J31/38 ,  C07C51/09

CPC classification number: C07C51/15 ,  B01J31/128 ,  B01J31/143 ,  B01J31/2234 ,  B01J31/2295 ,  B01J31/26 ,  B01J31/38 ,  B01J2231/321 ,  B01J2231/46 ,  B01J2531/847 ,  C07C51/09 ,  C07C51/377 ,  C07C57/04

Abstract: Processes for producing an α,β-unsaturated carboxylic acid, such as acrylic acid, or a salt thereof, using treated solid oxides are disclosed. The treated solid oxides can be calcined solid oxides, metal-treated solid oxides, or metal-treated chemically-modified solid oxides, illustrative examples of which can include sodium-treated alumina, calcium-treated alumina, zinc-treated alumina, sodium-treated sulfated alumina, sodium-treated fluorided silica-coated alumina, and similar materials.

公开(公告)号：US09701704B2

公开(公告)日：2017-07-11

申请号：US15074545

申请日：2016-03-18

Applicant: CALIFORNIA INSTITUTE OF TECHNOLOGY

Inventor： Choon Woo Lee ,  Robert H. Grubbs ,  Pablo E. Guzman ,  Tonia S. Ahmed ,  T. Patrick Montgomery

IPC: C07F15/00 ,  B01J31/28 ,  C07C67/30 ,  C07D313/00 ,  C07C67/475 ,  B01J31/12

CPC classification number: C07F15/0046 ,  B01J31/122 ,  B01J31/28 ,  B01J2231/543 ,  B01J2531/821 ,  C07B2200/09 ,  C07C67/293 ,  C07C67/30 ,  C07C67/333 ,  C07C67/475 ,  C07C2601/10 ,  C07D313/00 ,  C08F2500/25 ,  C08G61/08 ,  C08G2261/3322 ,  C08G2261/418 ,  C07C69/74 ,  C07C69/16 ,  C07C69/78 ,  C07C69/76

Abstract: This invention relates generally to olefin metathesis catalyst compounds, to the preparation of such compounds, and the use of such catalysts in the metathesis of olefins and olefin compounds, more particularly, in the use of such catalysts in (E)-selective olefin metathesis reactions. The invention has utility in the fields of catalysis, organic synthesis, polymer chemistry, and industrial and fine chemicals chemistry.

公开(公告)号：US09687834B2

公开(公告)日：2017-06-27

申请号：US12864261

申请日：2009-01-23

Applicant: Steven J. Malcolmson ,  Amir H. Hoveyda ,  Simon J. Meek ,  Richard R. Schrock

Inventor： Steven J. Malcolmson ,  Amir H. Hoveyda ,  Simon J. Meek ,  Richard R. Schrock

IPC: C07D487/18 ,  C07D211/02 ,  C07D233/04 ,  C07D487/04 ,  C07D471/04 ,  C07F7/18 ,  C07D309/18 ,  C07D309/20 ,  B01J31/12 ,  B01J31/18 ,  B01J31/22 ,  C07F11/00

CPC classification number: B01J31/1805 ,  B01J31/181 ,  B01J31/2208 ,  B01J31/2265 ,  B01J2231/54 ,  B01J2531/64 ,  B01J2531/66 ,  C07F11/005

Abstract: The present invention provides compositions comprising metal complexes, and related methods. In some embodiments, metal complexes of the invention may be useful as catalysts for chemical reactions, including metathesis reactions, wherein the catalysts exhibit enhanced activity and stereoselectivity. In some embodiments, the invention may advantageously provide metal complexes comprising a stereogenic metal atom. Such metal complexes may be useful in enantioselective catalysis.

公开(公告)号：US20170166501A1

公开(公告)日：2017-06-15

申请号：US15325895

申请日：2014-12-09

Applicant: CHANGSHU 3F FLUORINE CHEMICAL CO., LTD.

Inventor： Linxu SI ,  Pingzhong ZHANG ,  Hexiang GU

IPC: C07C21/18 ,  B01J31/12

CPC classification number: C07C21/18 ,  B01J31/12 ,  B01J31/121 ,  C07C17/23

Abstract: A process for preparing trifluorochloroethylene including: in a multi-tubular reactor, hydrogenation reacting 1,1,2-trifluoro-1,2,2-trichloroethane directly with a catalyst potassium zinc trihydride to obtain trifluorochloroethylene, wherein the catalytic reaction is performed at a temperature of 250-350° C. and a pressure of 0.7-1.0 MPa for 10-20 seconds. The conventional process in which zinc powder is used for dechlorination or hydrogen is used for dechlorination through hydrogenation with the action of a noble metal catalyst is avoided in the process disclosed herein. The present process substantially reduces the production cost of trifluorochloroethylene, and substantially increases the product yield, which can be up to 99% or more.

公开(公告)号：US09663728B2

公开(公告)日：2017-05-30

申请号：US14525477

申请日：2014-10-28

Applicant: Pallassana S. Venkataraman ,  Gordon F. Stuntz ,  Jonathan Martin McConnachie ,  Faiz Pourarian

Inventor： Pallassana S. Venkataraman ,  Gordon F. Stuntz ,  Jonathan Martin McConnachie ,  Faiz Pourarian

IPC: B01J21/06 ,  B01J21/08 ,  B01J29/076 ,  C10G45/00 ,  C10G45/22 ,  C10L1/00 ,  C10G49/04 ,  B01J31/12 ,  C10G45/60 ,  C10G47/02 ,  C10G1/00 ,  C10G45/04 ,  C10G45/06 ,  C10G49/02

CPC classification number: C10G49/04 ,  B01J31/121 ,  B01J2231/64 ,  B01J2531/0222 ,  B01J2531/42 ,  B01J2531/48 ,  B01J2531/52 ,  B01J2531/56 ,  C10G1/002 ,  C10G45/04 ,  C10G45/06 ,  C10G45/60 ,  C10G47/02 ,  C10G49/02 ,  C10G2300/1011 ,  Y02E50/13 ,  Y02P30/20

Abstract: The present invention relates to the processing of hydrocarbon-containing feedstreams in the presence of an interstitial metal hydride comprised of at least one chemical element selected from Groups 3-11 (including the lanthanides, atomic numbers 58 to 71), and at least one chemical element selected from Groups 13-15 from the IUPAC Periodic Table of Elements. These interstitial metal hydrides, their catalysts and processes using these interstitial metal hydrides and catalysts of the present invention improve overall hydrogenation, product conversion, as well as sulfur reduction in hydrocarbon feedstreams.

公开(公告)号：US09604903B2

公开(公告)日：2017-03-28

申请号：US14383348

申请日：2013-03-18

Applicant: CRODA INTERNATIONAL PLC

Inventor： Bastiaan Wels ,  Hans Ridderikhoff ,  Tanja Van Bergen-Brenkman ,  Dessy Liminto

IPC: C07C67/475 ,  C07C6/04 ,  C07C6/02 ,  B01J31/12 ,  B01J31/14 ,  B01J31/22 ,  C07C1/213 ,  C07C51/373 ,  C07C67/27 ,  C11C3/00

CPC classification number: C11C3/00 ,  B01J31/128 ,  B01J31/146 ,  B01J31/2273 ,  B01J31/2278 ,  B01J2231/54 ,  B01J2531/821 ,  C07C1/213 ,  C07C6/02 ,  C07C6/04 ,  C07C51/373 ,  C07C67/27 ,  C07C67/475 ,  C07C2527/135 ,  C07C2531/12 ,  C07C2531/22 ,  C07C2531/30 ,  C10G2300/1014 ,  C07C11/02 ,  C07C69/593

Abstract: A process of metathesizing a feedstock in the presence of a metathesis catalyst and at least one catalyst enhancer. The catalyst enhancer can be selected from a sacrificial catalyst or a non-catalyst enhancer. The process exhibits improved reaction times and/or the metathesis catalyst can be used at very low concentrations.