摘要:
The present invention relates to phosphorescent copolymers comprising trifunctional triplet emitters. The polymers according to the invention are highly soluble, readily accessible synthetically and more suitable for use in organic light-emitting diodes than are comparative materials in accordance with the prior art.
摘要:
A modified polymer complex, which is obtained by intermolecular and/or intramolecular crosslinking of a polymer complex via side chains thereof, wherein the polymer complex is a copolymer of a complex monomer meeting the following conditions (i) to (iii) and a comonomer expressed by the following general formula (1): R02R03═R01E (The definitions of R01, R02, R03 and E are omitted.)(i) the complex monomer has two or more transition metal atoms;(ii) the complex monomer has a polydentate ligand containing three or more coordinating atoms that are coordinately bonded to the transition metal atoms; and(iii) the polydentate ligand has one or more polymerizable functional groups.
摘要:
A composite material engineered from metal and resin and a production method of the composite material. The composite material includes a metal portion composed of metal; a resin portion composed of resin; a polar functional group imparted to a surface of the metal portion; and an adhesion modifying agent mixed in the resin and including an adhesive functional group which interacts with the polar functional group. The metal portion and the resin portion are bonded by the interaction between the polar functional group and the adhesive functional group.
摘要:
Disclosed is a coordination polymer crystal with porous metal-organic frameworks (MOFs), in which, while a crystal state of the coordination polymer crystal is maintained, an additional material selected from the group consisting of an organic compound, a metal cluster, and an organometallic compound is chemically bonded to the coordination polymer crystal. Therefore it is possible easily adsorb and store more guest molecules regardless of a change in an ambient temperature or pressure due to the chemically bonded additional material.
摘要:
Disclosed is an adjuvant capable of imparting a hydrophilic or superhydrophilic function to various materials or interfaces. The hydrophilic adjuvant comprises: a composite metal oxide containing Si and at least one metal element selected from the group consisting of Ti(IV), Zr(IV), Sn(IV) and Al(III); and a hydrophilic group-containing organic compound physically or chemically bonded with the Ti(IV), Zr(IV), Sn(IV) or Al of the composite metal oxide.
摘要:
A silicone resin composition containing (i) a silicone resin and (ii) fine metal oxide particles without having a reactive functional group or with a protected reactive functional group on the surface thereof (fine metal oxide particles B), wherein the silicone resin is obtained by carrying out a polymerization reaction between a silicone derivative having an alkoxysilyl group at an end of a molecule and a molecular weight of from 200 to 3000, and fine metal oxide particles having a reactive functional group on the surface thereof (fine metal oxide particles A), and wherein the fine metal oxide particles B are dispersed in the silicone resin (Embodiment 1); a silicone resin composition obtained by carrying out a polymerization reaction between a silicone derivative having a trifunctional alkoxysilyl group at an end of a molecule, and fine metal oxide particles having a reactive functional group on the surface thereof, wherein the silicone derivative contains two or more kinds of silicone derivatives each having a trifunctional alkoxysilyl group at an end of a molecule, and wherein the silicone derivative is added in two or more divided stages in the presence of the fine metal oxide particles in the polymerization reaction (Embodiment 2); and a silicone resin composition obtained by carrying out a polymerization reaction between a silicone derivative having an alkoxysilyl group at an end of a molecule or in a side chain thereof, and fine metal oxide particles having a reactive functional group on the surface thereof, wherein the alkoxysilyl group contains a silyl group having an alkoxy group and an aromatic group as functional groups directly bonded to a silicon atom (Embodiment 3). The silicone resin composition of the present invention can be suitably used as, for example, materials for encapsulating photosemiconductor elements for use in backlights for liquid crystal displays, traffic lights, outdoor big displays, advertisement sign boards, and the like.
摘要:
A method of making a stable photoresist solution containing a polymer from a solution of a polymer containing trace metals, said method comprising the steps of: (a) providing a polymer solution containing a polymer, a first solvent and trace metals; (b) passing said polymer solution through an acidic cation ion exchange material to remove said trace metals therefrom and thereby forming a polymer solution containing free acid radicals; (c) precipitating said polymer from said polymer solution of step b by contacting with a second solvent wherein the polymer is substantially insoluble therein; (d) filtering said solution and said second solvent to thereby form a solid polymer cake; (e) contacting said cake from step d with sufficient quantities of additional said second solvent in order to remove free acid radicals therefrom; (f) adding a compatible photoresist solvent to said solid polymer cake from step e and mixing the two in order to dissolve said polymer in said photoresist solvent and thereby forming a photoresist solution; and (g) removing any residual first and second solvents from said photoresist solution containing said polymer to form a stable photoresist solution.
摘要:
Cyclic esters are polymerized in the presence of a catalytic amount of a Group 4 transition metal hydride. The method is capable of producing high molecular weight polyesters with low polydispersities. These high molecular weight polyesters exhibit improved mechanical properties and are useful in a variety of product applications.
摘要:
The invention relates to regioregular polyselenophenes, to their use as semiconductors or charge transport materials, in optical, electro-optical or electronic devices, and to optical, electro-optical or electronic devices comprising them.
摘要:
A metallized polymer having a backbone having an acetylenic repeat unit and —SiR2—(O—SiR2)n— and/or —SiR2—(O—SiR2)n-[Cb-SiR2—(O—SiR2)n]m—. At least one of the acetylenic repeat units contains a (MLx)y-acetylene complex. M is a metal, L is a ligand, x and y are positive integers, R is an organic group, Cb is a carborane, and n and m are greater than or equal to zero. A composition containing a siloxane polymer and a metallic compound. The siloxane polymer has a backbone having one or more acetylene groups and —SiR2—(O—SiR2)n— and/or —SiR2—(O—SiR2)n-[Cb-SiR2—(O—SiR2)n]m—. The metallic compound is capable of reacting with the acetylene group to form a (MLx)y-acetylene complex.