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公开(公告)号：US20090062110A1
公开(公告)日：2009-03-05
申请号：US12278180
申请日：2007-01-01
CPC分类号： B01J31/2243 , B01J31/1815 , B01J31/223 , B01J35/002 , B01J37/082 , B01J2531/0205 , B01J2531/0241 , B01J2531/025 , B01J2531/16 , B01J2531/56 , B01J2531/72 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07D257/10
摘要： A polynuclear metal complex having in each molecule not only at least one large cyclic ligand having 5 to 15 coordinating atoms but also multiple metal atoms is subjected to any of heating treatment, radiation exposure treatment and electric discharge treatment, thereby providing a polynuclear metal complex exhibiting a ratio of weight loss by the treatment of 5 to 90 wt. % and a carbon content after the treatment of 5 wt. % or more.
摘要翻译： 在每个分子中不仅具有至少一个具有5至15个配位原子的大环配体，而且具有多个金属原子的多核金属络合物经受加热处理，辐射暴露处理和放电处理中的任一种，从而提供多核金属络合物， 通过处理5至90wt。的重量损失比率。 ％，处理后的碳含量为5wt。 ％ 或者更多。
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公开(公告)号：US20090011929A1
公开(公告)日：2009-01-08
申请号：US12278188
申请日：2007-02-07
IPC分类号： B01J31/18 , C08F214/18 , C07F13/00 , C07D403/14
CPC分类号： C07D235/14 , B01J31/183 , B01J31/2243 , B01J2231/62 , B01J2531/0216 , B01J2531/0258 , B01J2531/16 , B01J2531/72 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07D403/14 , C07D405/14 , C07F1/005 , C07F9/65583 , C07F13/005 , C07F15/025 , C07F15/045 , C07F15/065 , C08F4/26 , C08F4/40
摘要： To provide a multinuclear complex including at least one ligand L satisfying the following requirements (i) r (ii) and (iii), and a plurality of metal atoms in a molecule: (i) having a group having polymerizable reactive multiple bonds, and/or a ring-opening polymerizable ring, (ii) having five or more coordination atoms bonding to the metal atoms, and (iii) being soluble in a solvent.
摘要翻译： 提供包含满足以下要求（i）r（ii）和（iii））的至少一种配体L和分子中多个金属原子的多核络合物：（i）具有可聚合反应性多重键的基团，以及 /或可开环聚合的环，（ii）具有五个或更多个配位原子键合到金属原子上，和（iii）可溶于溶剂。
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公开(公告)号：US20120211706A1
公开(公告)日：2012-08-23
申请号：US13504275
申请日：2010-10-25
CPC分类号： C07D233/64 , C07D235/14 , C07D417/12 , C07F5/003 , C07F5/022 , C07F9/65583 , C09K11/06 , C09K2211/1011 , C09K2211/1014 , C09K2211/1044
摘要： The present invention provides a metal complex that has excellent durability, and a device and the like having excellent durability that uses such a metal complex. Specifically, the present invention provides a metal complex comprising (a) a polydentate ligand having denticity of five or more that includes a heteroaromatic ring which contains two or more atoms selected from the group consisting of a nitrogen atom, an oxygen atom, and a sulfur atom, and (b) an ion of a metal selected from the group consisting of cerium, praseodymium, ytterbium, and lutetium; a composition comprising the metal complex and a charge transport material; an organic thin film obtained by using the metal complex or composition; and a device obtained by using the metal complex, composition, or organic thin film.
摘要翻译： 本发明提供了耐久性优异的金属络合物和使用这种金属络合物的耐久性优良的装置等。 具体地说，本发明提供一种金属配合物，其特征在于，具有（a）具有5以上的牙齿的多齿配体，所述多齿配体包括含有选自氮原子，氧原子和硫原子中的2个以上的原子的杂芳香环 原子，和（b）选自铈，镨，镱和镥的金属离子; 包含金属络合物和电荷输送材料的组合物; 通过使用金属络合物或组合物获得的有机薄膜; 以及通过使用金属络合物，组合物或有机薄膜获得的器件。
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公开(公告)号：US07988944B2
公开(公告)日：2011-08-02
申请号：US11993892
申请日：2006-06-20
CPC分类号： B01J31/2243 , B01J23/30 , B01J23/34 , B01J31/1815 , B01J31/183 , B01J31/2239 , B01J2531/0216 , B01J2531/025 , B01J2531/0258 , B01J2531/16 , B01J2531/72 , B01J2531/842 , B01J2531/845
摘要： An object of the present invention is to provide a catalyst which decomposes a peroxide effectively and economically under a high temperature while suppressing generation of free radicals, and the present invention provides a peroxide decomposition catalyst containing a base metal atom, wherein a value A indicating a free radical generation amount represented by the (equation 1) is not more than 0.20, and a value B indicating a reaction rate represented by the (equation 2), which can be easily applied to utility such as an agent for preventing deterioration of a polymer electrolyte-type fuel cell and a water electrolysis apparatus, and an antioxidant for medicaments, agrochemicals and foods. A=(Mw(S)/Mw)−1 (equation 1) (wherein Mw is a weight average molecular weight of poly(sodium 4-styrenesulfonate) after a hydrogen peroxide decomposition test in the test at 80° C. in the presence of poly(sodium 4-styrenesulfonate), and Mw(S) is a weight average molecular weight of poly(sodium 4-styrenesulfonate) before the test) B=N(PO)/N(cat) (equation 2) (wherein N(po) is a mole number of hydrogen peroxide decomposed per 20 minutes in a hydrogen peroxide decomposition test in the (equation 1), and N(cat) is a mole number per metal atom of a catalyst used).
摘要翻译： 本发明的目的在于提供一种在高温下有效且经济地分解过氧化物同时抑制自由基产生的催化剂，本发明提供了含有贱金属原子的过氧化物分解催化剂，其中A表示 由（式1）表示的自由基产生量不大于0.20，表示由（式2）表示的反应速度的值B，其可以容易地应用于防止聚合物劣化的试剂 电解质型燃料电池和水电解装置，以及用于药物，农药和食品的抗氧化剂。 A =（Mw（S）/ Mw）-1（式1）（式中，Mw是在80℃下在过氧化氢分解试验中聚（4-苯乙烯磺酸钠）的重均分子量， 的聚（4-苯乙烯磺酸钠），Mw（S）是试验前的聚（4-苯乙烯磺酸钠）的重均分子量）B = N（PO）/ N（cat）（式2）（式中，N （po）是在（式1）的过氧化氢分解试验中每20分钟分解的过氧化氢的摩尔数，N（cat）是使用的催化剂的每个金属原子的摩尔数）。
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5.发明申请MODIFIED POLYMER COMPLEX, COMPLEX MONOMER, POLYMER COMPLEX, AND REDOX,CATALYST 审中-公开改性聚合物复合物，复合单体，聚合物复合物和还原剂，催化剂公开(公告)号：US20100197886A1
公开(公告)日：2010-08-05
申请号：US12671066
申请日：2008-08-05
IPC分类号： C08G79/00 , C07D233/61
CPC分类号： C07D233/54 , B01J31/1805 , B01J31/183 , B01J31/2208 , B01J2531/0238 , B01J2531/16 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07D235/04 , C07D235/14 , C07F1/08 , C07F13/005 , C07F15/025 , C07F15/045 , C07F15/065 , C08F12/26 , C08F12/32 , C08F12/34 , C08F212/32 , C08F220/06 , C08F220/44 , C08F212/34 , C08F212/14
摘要： A modified polymer complex, which is obtained by intermolecular and/or intramolecular crosslinking of a polymer complex via side chains thereof, wherein the polymer complex is a copolymer of a complex monomer meeting the following conditions (i) to (iii) and a comonomer expressed by the following general formula (1): R02R03═R01E (The definitions of R01, R02, R03 and E are omitted.)(i) the complex monomer has two or more transition metal atoms;(ii) the complex monomer has a polydentate ligand containing three or more coordinating atoms that are coordinately bonded to the transition metal atoms; and(iii) the polydentate ligand has one or more polymerizable functional groups.
摘要翻译： 通过其侧链通过聚合物配合物的分子间和/或分子内交联获得的改性聚合物络合物，其中所述聚合物配合物是满足以下条件（i）至（iii）的共轭单体和表达的共聚单体的共聚物 通过以下通式（1）表示：R02R03 = R01E（R01，R02，R03和E的定义被省略。）（i）复合单体具有两个以上的过渡金属原子; （ii）复合单体具有多齿配体，其含有三个或更多个与过渡金属原子配位键合的配位原子; 和（iii）多齿配体具有一个或多个可聚合官能团。
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公开(公告)号：US20090036687A1
公开(公告)日：2009-02-05
申请号：US12278415
申请日：2007-02-08
IPC分类号： C07D403/14 , C07F7/10
CPC分类号： C07F15/025 , B01J31/183 , B01J31/2243 , B01J2231/62 , B01J2531/0216 , B01J2531/0258 , B01J2531/16 , B01J2531/72 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07F7/1804
摘要： A multinuclear complex comprising a plurality of metal atoms and a ligand L coordinating to the metal atoms, and satisfying the following conditions (i), (ii), (iii) and (iv):(i) The ligand L has a monovalent group represented by the following general formula (1) and/or a divalent group represented by the following general formula (2), (ii) The ligand L has at least 5 coordination atoms bonding to the metal atom, (iii) At least one of the coordination atoms bonds to two of the metal atoms, or the minimum number of covalent bonds between any two selected coordination atoms is 1-5, and (iv) The ligand L is soluble in the solvent.
摘要翻译： 包含多个金属原子的多核络合物和与金属原子配位的配位体L，并满足下列条件（i），（ii），（iii）和（iv）：（i）配体L具有一价基团 由下述通式（1）表示的化合物和/或由以下通式（2）表示的二价基团，（ii）配体L具有至少5个与金属原子键合的配位原子，（iii）至少一个 配位原子与两个金属原子键合，或任意两个选定的配位原子之间的最小共价键数为1-5，和（ⅳ）配体L可溶于溶剂中。
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公开(公告)号：US20080219916A1
公开(公告)日：2008-09-11
申请号：US11993892
申请日：2006-06-20
CPC分类号： B01J31/2243 , B01J23/30 , B01J23/34 , B01J31/1815 , B01J31/183 , B01J31/2239 , B01J2531/0216 , B01J2531/025 , B01J2531/0258 , B01J2531/16 , B01J2531/72 , B01J2531/842 , B01J2531/845
摘要： An object of the present invention is to provide a catalyst which decomposes a peroxide effectively and economically under a high temperature while suppressing generation of free radicals, and the present invention provides a peroxide decomposition catalyst containing a base metal atom, wherein a value A indicating a free radical generation amount represented by the (equation 1) is not more than 0.20, and a value B indicating a reaction rate represented by the (equation 2), which can be easily applied to utility such as an agent for preventing deterioration of a polymer electrolyte-type fuel cell and a water electrolysis apparatus, and an antioxidant for medicaments, agrochemicals and foods. A=(Mw(S)/Mw)−1 (equation 1) (wherein Mw is a weight average molecular weight of poly(sodium 4-styrenesulfonate) after a hydrogen peroxide decomposition test in the test at 80° C. in the presence of poly(sodium 4-styrenesulfonate), and Mw(S) is a weight average molecular weight of poly(sodium 4-styrenesulfonate) before the test) B=N(PO)/N(cat) (equation 2) (wherein N(po) is a mole number of hydrogen peroxide decomposed per 20 minutes in a hydrogen peroxide decomposition test in the (equation 1), and N(cat) is a mole number per metal atom of a catalyst used)
摘要翻译： 本发明的目的在于提供一种在高温下有效且经济地分解过氧化物同时抑制自由基产生的催化剂，本发明提供了含有贱金属原子的过氧化物分解催化剂，其中A表示 由（式1）表示的自由基产生量不大于0.20，表示由（式2）表示的反应速度的值B，其可以容易地应用于防止聚合物劣化的试剂 电解质型燃料电池和水电解装置，以及用于药物，农药和食品的抗氧化剂。 A =（Mw（S）/ Mw）-1（等式1）<？in-line-formula description =“In-line-formula description =”In-line-formula description = （式中，Mw是在80℃下在聚（4-苯乙烯磺酸钠）存在下的过氧化氢分解试验后的聚（4-苯乙烯磺酸钠）的重均分子量， 苯乙烯磺酸盐），Mw（S）是测试前的聚（4-苯乙烯磺酸钠）的重均分子量）<？在线公式描述=“在线公式”end =“lead”→> B = N（PO）/ N（cat）（式2）<？in-line-formula description =“In-line Formulas”end =“tail”？>（其中N（po）是每分解的过氧化氢的摩尔数 （式1）中的过氧化氢分解试验为20分钟，N（cat）为所用催化剂的每个金属原子的摩尔数）
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