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41.发明授权Method for hydro-upgrading inferior gasoline via ultra-deep desulfurization and octane number recovery 有权通过超深度脱硫和辛烷值回收加氢改质劣质汽油的方法公开(公告)号：US08603324B2
公开(公告)日：2013-12-10
申请号：US12725939
申请日：2010-03-17
Applicant: Yu Fan , Xiaojun Bao , Gang Shi , Haiyan Liu
Inventor： Yu Fan , Xiaojun Bao , Gang Shi , Haiyan Liu
IPC: C10G51/06
CPC classification number: C10G45/38 , C10G45/08 , C10G45/64 , C10G45/68 , C10G65/00 , C10G65/043 , C10G65/046 , C10G65/06 , C10G2300/104 , C10G2300/1044 , C10G2300/202 , C10G2300/305 , C10G2300/4018 , C10G2400/02
Abstract: The present invention relates to a method of hydro-upgrading inferior gasoline through ultra-deep desulfurization and octane number recovery. The method comprises the following steps: cutting inferior full-range gasoline into light fraction gasoline and heavy fraction gasolines; contacting the light fraction gasoline successively with a catalyst for selective diene removal and a catalyst for desulfurization and hydrocarbon multi-branched-chain hydroisomerization; contacting the heavy fraction gasoline with the catalyst for selective hydrodesulfurization in a first reactor, and contacting the reaction effluent from the first reactor with a catalyst for supplemental desulfurization and hydrocarbon aromatization/single-branched-chain hydroisomerization in a second reactor; and blending the treated light fraction gasoline and the heavy fraction gasoline to obtain the ultra-clean gasoline product. The hydro-upgrading method of the invention is suitable for hydro-upgrading inferior gasoline, especially for hydro-upgrading inferior FCC gasoline with ultra-high sulfur content and high olefin content to obtain excellent hydro-upgrading effects.
Abstract translation: 本发明涉及通过超深脱硫和辛烷值回收来升级劣质汽油的方法。 该方法包括以下步骤：将低级全程汽油切割成轻馏分汽油和重馏分汽油; 将轻馏分汽油依次与用于选择性二烯除去的催化剂和用于脱硫和烃多支链加氢异构化的催化剂接触; 使重馏分汽油与第一反应器中的选择性加氢脱硫催化剂接触，并使来自第一反应器的反应流出物与第二反应器中用于补充脱硫和烃芳构化/单支链加氢异构化的催化剂接触; 并混合处理的轻馏分汽油和重馏分汽油，得到超清洁汽油产品。 本发明的加氢改质方法适用于加氢改质劣质汽油，特别是用于加氢改质超高硫含量和高烯烃含量的低级FCC汽油，以获得优异的加氢改质效果。
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公开(公告)号：US20130281756A1
公开(公告)日：2013-10-24
申请号：US13976701
申请日：2011-12-28
Applicant: Shinichiro Yanagawa , Masahide Kobayashi , Yasuyuki Iwasa , Ryoji Ida
Inventor： Shinichiro Yanagawa , Masahide Kobayashi , Yasuyuki Iwasa , Ryoji Ida
IPC: C10G11/05
CPC classification number: C10G11/05 , B01J29/40 , B01J29/65 , B01J29/703 , B01J29/7042 , B01J29/7046 , B01J29/80 , B01J29/82 , B01J29/87 , B01J35/10 , B01J37/0009 , B01J37/04 , B01J2229/18 , B01J2229/20 , B01J2229/42 , C10G11/18 , C10G45/68 , C10G69/04 , C10G2300/1037 , C10G2300/301 , C10G2400/30
Abstract: In the production method of monocyclic aromatic hydrocarbons, oil feedstock having a 10 volume % distillation temperature of 140° C. or higher and a 90 volume % distillation temperature of 380° C. or lower is brought into contact with a catalyst for producing monocyclic aromatic hydrocarbons that includes a mixture containing a first catalyst which contains crystalline aluminosilicate containing gallium and/or zinc and phosphorus and a second catalyst which contains crystalline aluminosilicate containing phosphorus.
Abstract translation: 在单环芳烃的制造方法中，使具有140℃或更高的10体积％蒸馏温度和380℃或更低的90体积％蒸馏温度的油原料与用于制备单环芳族化合物的催化剂接触 包括含有含有含有镓和/或锌和磷的结晶硅铝酸盐的第一催化剂和含有含磷结晶硅铝酸盐的第二催化剂的混合物的烃。
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43.发明申请公开(公告)号：US20120264987A1
公开(公告)日：2012-10-18
申请号：US13461223
申请日：2012-05-01
Applicant: Machteld M. Mertens , An Verberckmoes , Ivy D. Johnson
Inventor： Machteld M. Mertens , An Verberckmoes , Ivy D. Johnson
CPC classification number: C07C2/58 , B01J29/7026 , B01J35/002 , B01J2231/20 , C01B39/48 , C07C2/12 , C07C2529/70 , C10G3/49 , C10G11/05 , C10G35/065 , C10G45/12 , C10G45/64 , C10G45/68 , C10G47/16 , C10G49/08 , C10G50/00 , C10G2400/20 , C10G2400/22 , Y02P30/20 , Y10S585/906 , C07C9/16
Abstract: A crystalline molecular sieve of MFS framework type manufactured by the method disclosed herein. A hydrocarbon conversion process using the crystalline molecular sieve is disclosed.
Abstract translation: 由本文公开的方法制造的MFS框架型结晶分子筛。 公开了使用结晶分子筛的烃转化方法。
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44.发明授权Molecular sieve composition (EMM-10), its method of making, and use for hydrocarbon conversions 有权分子筛组成（EMM-10），其制备方法和用于碳氢化合物转化公开(公告)号：US08110176B2
公开(公告)日：2012-02-07
申请号：US11824742
申请日：2007-07-02
Applicant: Wieslaw J. Roth , Thomas Yorke , Douglas Lewis Dorset , Mohan Kalyanaraman , Michael Charles Kerby , Simon Christopher Weston
Inventor： Wieslaw J. Roth , Thomas Yorke , Douglas Lewis Dorset , Mohan Kalyanaraman , Michael Charles Kerby , Simon Christopher Weston
CPC classification number: B01J29/70 , B01J29/7038 , B01J29/7276 , B01J35/002 , B01J2229/18 , B01J2229/20 , C01B39/48 , C07C2/66 , C07C2/864 , C07C4/06 , C07C5/02 , C07C5/10 , C07C5/412 , C07C5/52 , C07C7/13 , C07C2529/70 , C07C2529/72 , C07C2529/74 , C10G29/205 , C10G45/68 , C10G47/02 , C10G49/08 , C10G50/00 , Y10S208/02
Abstract: This invention relates to a crystalline molecular sieve, in its ammonium exchanged form or in its calcined form, comprising unit cells with MWW topology, said crystalline molecular sieve is characterized by diffraction streaking from the unit cell arrangement in the c direction. The crystalline molecular sieve is further characterized by the arced hk0 patterns of electron diffraction pattern. The crystalline molecular sieve is further characterized by the unit cells streaking along c direction. This invention also relates to a method of making thereof.
Abstract translation: 本发明涉及以铵交换形式或其煅烧形式的包含具有MWW拓扑结构的单元电池的结晶分子筛，所述结晶分子筛的特征在于沿c方向从单元电池排列衍射衍射。 结晶分子筛的特征还在于电子衍射图案的弧形hk0图案。 结晶分子筛的特征还在于沿c方向分布的单位细胞。 本发明还涉及其制备方法。
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公开(公告)号：US20100285948A1
公开(公告)日：2010-11-11
申请号：US12808781
申请日：2008-01-16
Applicant: Yan Liu , Toru Nishimura
Inventor： Yan Liu , Toru Nishimura
CPC classification number: B01J29/076 , B01J29/48 , B01J29/7876 , B01J29/90 , B01J38/04 , B01J2229/186 , B01J2229/34 , B01J2229/40 , C07C2/76 , C07C2529/48 , C10G45/68 , Y02P20/584 , C07C15/02
Abstract: A process for the pre-treatment of Mo/ZSM-5 and Mo/MCM-22 catalysts is provided, which process comprises heating the catalyst at 500° C. in the presence of propane. The treated catalyst, when used in the non-oxidative dehydrogenation of methane demonstrates improved benzene yield and catalyst stability as compared to catalysts pre-treated with He, methane or H2.
Abstract translation: 提供了用于预处理Mo / ZSM-5和Mo / MCM-22催化剂的方法，该方法包括在丙烷存在下在500℃下加热催化剂。 当用于甲烷的非氧化脱氢反应时，处理的催化剂与用He，甲烷或H 2预处理的催化剂相比，显示出苯产率和催化剂稳定性的改善。
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Patent Agency Ranking
公开(公告)号：US07816570B2
公开(公告)日：2010-10-19
申请号：US11948006
申请日：2007-11-30
Applicant: William L. Roberts, IV , H. Henry Lamb , Larry F. Stikeleather , Timothy L. Turner
Inventor： William L. Roberts, IV , H. Henry Lamb , Larry F. Stikeleather , Timothy L. Turner
CPC classification number: C07C1/22 , C10G1/006 , C10G3/47 , C10G3/50 , C10G3/56 , C10G45/58 , C10G45/68 , C10G47/00 , C10G2300/1014 , C10G2300/1018 , C10G2300/4081 , C10G2300/44 , C10G2300/805 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C11C3/10 , Y02E50/13 , Y02P30/20 , Y02T50/678
Abstract: A process for the direct conversion of lipid biomass fuel stock to combustible fuels include the steps of hydrolyzing a lipid biomass to form free fatty acids, catalytically deoxygenating the free fatty acids to from n-alkanes, and reforming at least a portion of the n-alkanes into a mixture of compounds having the correct chain length, conformations and ratio to be useful as transportation fuels. The process exhibits an overall energy efficiency of at least about 75%, wherein energy efficiency is calculated as the lower heating value of the produced transportation fuel over the sum of the lower heating value of the process reactants and the total energy input into the process.
Abstract translation: 将脂质生物质燃料原料直接转化为可燃性燃料的方法包括以下步骤：水解脂质生物质以形成游离脂肪酸，将游离脂肪酸催化脱氧为从正烷烃，并重整至少一部分正链烷烃; 烷烃变成具有正确链长度，构象和比例的化合物的混合物，可用作运输燃料。 该方法表现出至少约75％的总能量效率，其中，将能量效率计算为所生产的运输燃料的较低热值超过工艺反应物的较低热值与输入到该方法中的总能量之和的总和。
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公开(公告)号：US20100160702A1
公开(公告)日：2010-06-24
申请号：US12617451
申请日：2009-11-12
Applicant: An-Hsiang WU
Inventor： An-Hsiang WU
CPC classification number: B01J29/90 , B01J23/96 , B01J29/62 , B01J37/24 , B01J37/26 , B01J38/12 , B01J38/44 , B01J38/46 , B01J38/54 , B01J2229/42 , C10G45/68
Abstract: A method of preparing a fresh catalyst comprises impregnating a metal to a catalyst support to produce an impregnated catalyst, dispersing the metal in the impregnated catalyst to produce an impregnated, dispersed catalyst, contacting the impregnated, dispersed catalyst with an activating composition to produce an impregnated, dispersed, activated catalyst, and thermally treating the impregnated, dispersed, activated catalyst to produce the fresh catalyst wherein the activating composition is in the gas phase.
Abstract translation: 制备新鲜催化剂的方法包括将金属浸渍到催化剂载体以产生浸渍的催化剂，将金属分散在浸渍的催化剂中以产生浸渍的分散的催化剂，使浸渍的分散的催化剂与活化组合物接触以产生浸渍的 ，分散的活化催化剂，并热处理浸渍的，分散的活化的催化剂以产生新鲜的催化剂，其中活化组合物处于气相。
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公开(公告)号：US20090177020A1
公开(公告)日：2009-07-09
申请号：US12376656
申请日：2007-08-02
Applicant: Yushi Suzuki , Tsuyoshi Asano
Inventor： Yushi Suzuki , Tsuyoshi Asano
IPC: C07C15/00
CPC classification number: C10G50/00 , C07C2/84 , C07C2529/87 , C10G35/095 , C10G45/68 , C10G2300/4025 , C10G2400/30 , C07C15/00
Abstract: The present invention provides a process for producing aromatic hydrocarbons at a sufficiently high yield, from a light hydrocarbon containing mainly hydrocarbons having 7 or fewer carbon atoms. The process of the present invention comprises bringing a feedstock containing mainly light hydrocarbons having 2 to 7 carbon atoms into contact with a catalyst composition comprising at least a gallium-containing crystalline aluminosilicate wherein a reaction step for converting the feedstock to aromatic hydrocarbons comprises at least two or more reaction layers formed of the catalyst composition, arranged in series and heating means arranged either between or in the reaction layers, the amount of the catalyst in the first stage reaction layer is 30 percent by volume or less of the total catalyst volume, and/or the yield of the aromatics in the product outflowing from the first reaction layer is from 0.5 to 30 percent by mass.
Abstract translation: 本发明提供了一种以足够高的产率从主要含有具有7个或更少碳原子的烃的轻烃生产芳烃的方法。 本发明的方法包括使主要含有2-7个碳原子的轻质原料与包含至少含镓结晶硅铝酸盐的催化剂组合物接触，其中用于将原料转化成芳族烃的反应步骤包括至少两个 或更多的由催化剂组合物形成的反应层和排列在反应层之间或反应层中的加热装置，第一级反应层中的催化剂的量为总催化剂体积的30体积％或更少，以及 /或从第一反应层流出的产物中的芳族化合物的收率为0.5〜30质量％。
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49.发明授权公开(公告)号：US07431828B2
公开(公告)日：2008-10-07
申请号：US11174597
申请日：2005-07-06
Applicant: Michael G. Hunter , Rasmus G. Egeberg , Kim G. Knudsen
Inventor： Michael G. Hunter , Rasmus G. Egeberg , Kim G. Knudsen
CPC classification number: C10G45/02 , C10G45/68 , C10G65/043 , C10G65/046
Abstract: A two-stage hydrotreating process is disclosed wherein a hydrocarbon stream is first desulphurized followed by a dehydrogenation step, which process comprises in combination contacting the feed and hydrogen over a hydrotreating catalyst at hydrotreating conditions, heating the hydrotreated effluent and hydrogen-rich gas from the hydrotreating reactor and contacting said effluent and hydrogen gas over a hydrotreating catalyst in a post-treatment reactor at a temperature sufficient to increase the polyaromatic hydrocarbon content and lower the hydrogen content of said effluent.
Abstract translation: 公开了两阶段加氢处理方法，其中烃流首先被脱硫，随后脱氢步骤，该方法包括在加氢处理条件下将加料处理的催化剂与进料和氢气组合在一起，将加氢处理的流出物和富氢气体从 加氢处理反应器，并将所述流出物和氢气在后处理反应器中的加氢处理催化剂上接触，所述温度足以增加所述多芳族烃含量并降低所述流出物的氢含量。
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50.发明申请Molecular sieve composition (EMM-10), its method of making, and use for hydrocarbon conversions 有权分子筛组成（EMM-10），其制备方法和用于碳氢化合物转化公开(公告)号：US20080027256A1
公开(公告)日：2008-01-31
申请号：US11824742
申请日：2007-07-02
Applicant: Wieslaw Roth , Thomas Yorke , Douglas Dorsei , Mohan Kalyanaraman , Michael Kerby , Simon Weston
Inventor： Wieslaw Roth , Thomas Yorke , Douglas Dorsei , Mohan Kalyanaraman , Michael Kerby , Simon Weston
CPC classification number: B01J29/70 , B01J29/7038 , B01J29/7276 , B01J35/002 , B01J2229/18 , B01J2229/20 , C01B39/48 , C07C2/66 , C07C2/864 , C07C4/06 , C07C5/02 , C07C5/10 , C07C5/412 , C07C5/52 , C07C7/13 , C07C2529/70 , C07C2529/72 , C07C2529/74 , C10G29/205 , C10G45/68 , C10G47/02 , C10G49/08 , C10G50/00 , Y10S208/02
Abstract: This invention relates to a crystalline molecular sieve, in its ammonium exchanged form or in its calcined form, comprising unit cells with MWW topology, said crystalline molecular sieve is characterized by diffraction streaking from the unit cell arrangement in the c direction. The crystalline molecular sieve is further characterized by the arced hk0 patterns of electron diffraction pattern. The crystalline molecular sieve is further characterized by the unit cells streaking along c direction. This invention also relates to a method of making thereof.
Abstract translation: 本发明涉及以铵交换形式或其煅烧形式的包含具有MWW拓扑结构的单元电池的结晶分子筛，所述结晶分子筛的特征在于沿c方向从单元电池排列衍射衍射。 结晶分子筛的特征还在于电子衍射图案的弧形hk0图案。 结晶分子筛的特征还在于沿c方向分布的单位细胞。 本发明还涉及其制备方法。
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