METALLOCENE COMPLEX AND OLEFIN POLYMERIZATION METHOD
    49.
    发明申请
    METALLOCENE COMPLEX AND OLEFIN POLYMERIZATION METHOD 有权
    金属络合物和烯烃聚合方法

    公开(公告)号:US20150266914A1

    公开(公告)日:2015-09-24

    申请号:US14435819

    申请日:2013-10-28

    Abstract: Provided are a metallocene complex that facilitates copolymerization of olefin monomers including propylene at a higher uptake rate of comonomers, i.e., ethylene and α-olefin, manufacture of a rubber component having a higher molecular weight, and manufacture of homopolypropylene having a higher melting point through homopolymerization of propylene, compared to traditional metallocene catalysts, and a method of olefin polymerization in the presence of such a metallocene complex. Also provided are, for example, a metallocene complex represented by general formula [I] (e.g., a metallocene complex having a substituent at position 6 of one or each indenyl ring and an optionally substituted furyl or thienyl group at position 2 of one or each indenyl ring), an olefin polymerization catalyst containing the metallocene complex, and a method of olefin polymerization involving olefin polymerization or copolymerization in the presence of the olefin polymerization catalyst.

    Abstract translation: 提供了一种茂金属络合物,其促进烯烃单体(包括丙烯)以更高的共聚单体(即乙烯和α-烯烃)的吸收速率的共聚,制备具有较高分子量的橡胶组分,以及制造具有较高熔点的均聚丙烯 与传统的茂金属催化剂相比,丙烯的均聚,以及在这种茂金属络合物存在下烯烃聚合的方法。 还提供了例如由通式[I]表示的茂金属络合物(例如,在一个或每个茚基环的6位上具有取代基的金属茂络合物和位置2上任选取代的呋喃基或噻吩基的一个或多个 茚基环),含有茂金属络合物的烯烃聚合催化剂,以及在烯烃聚合催化剂存在下进行烯烃聚合或共聚的烯烃聚合方法。

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