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公开(公告)号:US20150266914A1
公开(公告)日:2015-09-24
申请号:US14435819
申请日:2013-10-28
Applicant: JAPAN POLYPROPYLENE CORPORATION
Inventor: Masami Kashimoto , Takayoshi Takahashi , Naoshi Iwama , Masato Nakano , Toshinori Suzuki
IPC: C07F17/00 , C08F293/00
CPC classification number: C07F17/00 , C08F4/65912 , C08F4/65916 , C08F10/06 , C08F293/00 , C08F297/083 , C08F4/65927 , C08F4/6492 , C08F110/06 , C08F2500/12 , C08F210/06 , C08F210/02 , C08F2500/21 , C08F2500/01
Abstract: Provided are a metallocene complex that facilitates copolymerization of olefin monomers including propylene at a higher uptake rate of comonomers, i.e., ethylene and α-olefin, manufacture of a rubber component having a higher molecular weight, and manufacture of homopolypropylene having a higher melting point through homopolymerization of propylene, compared to traditional metallocene catalysts, and a method of olefin polymerization in the presence of such a metallocene complex. Also provided are, for example, a metallocene complex represented by general formula [I] (e.g., a metallocene complex having a substituent at position 6 of one or each indenyl ring and an optionally substituted furyl or thienyl group at position 2 of one or each indenyl ring), an olefin polymerization catalyst containing the metallocene complex, and a method of olefin polymerization involving olefin polymerization or copolymerization in the presence of the olefin polymerization catalyst.
Abstract translation: 提供了一种茂金属络合物,其促进烯烃单体(包括丙烯)以更高的共聚单体(即乙烯和α-烯烃)的吸收速率的共聚,制备具有较高分子量的橡胶组分,以及制造具有较高熔点的均聚丙烯 与传统的茂金属催化剂相比,丙烯的均聚,以及在这种茂金属络合物存在下烯烃聚合的方法。 还提供了例如由通式[I]表示的茂金属络合物(例如,在一个或每个茚基环的6位上具有取代基的金属茂络合物和位置2上任选取代的呋喃基或噻吩基的一个或多个 茚基环),含有茂金属络合物的烯烃聚合催化剂,以及在烯烃聚合催化剂存在下进行烯烃聚合或共聚的烯烃聚合方法。
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公开(公告)号:US09963522B2
公开(公告)日:2018-05-08
申请号:US15126344
申请日:2015-03-17
Applicant: JAPAN POLYPROPYLENE CORPORATION
Inventor: Toshinori Suzuki , Masami Kashimoto , Masato Nakano , Hideshi Uchino , Takao Tayano
IPC: C07F17/00 , C08F4/6592 , C08F10/06 , C08F210/06 , C08F4/659 , C08F10/00
CPC classification number: C08F4/65916 , C07F17/00 , C08F4/65912 , C08F4/65927 , C08F10/00 , C08F2420/06 , C08F210/06 , C08F210/16 , C08F2500/12 , C08F4/6492
Abstract: The present invention provides a metallocene complex capable of producing a homopolypropylene having a high melting point in the homopolymerization of propylene, and a production method of an olefin polymer using the same. The metallocene complex of the present invention is represented by formula [I].
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公开(公告)号:US09902749B2
公开(公告)日:2018-02-27
申请号:US14435819
申请日:2013-10-28
Applicant: JAPAN POLYPROPYLENE CORPORATION
Inventor: Masami Kashimoto , Takayoshi Takahashi , Naoshi Iwama , Masato Nakano , Toshinori Suzuki
IPC: C07F17/00 , C08F10/06 , C08F297/08 , C08F293/00 , C08F4/659
CPC classification number: C07F17/00 , C08F4/65912 , C08F4/65916 , C08F10/06 , C08F293/00 , C08F297/083 , C08F4/65927 , C08F4/6492 , C08F110/06 , C08F2500/12 , C08F210/06 , C08F210/02 , C08F2500/21 , C08F2500/01
Abstract: Provided are a metallocene complex that facilitates copolymerization of olefin monomers including propylene at a higher uptake rate of comonomers, i.e., ethylene and α-olefin, manufacture of a rubber component having a higher molecular weight, and manufacture of homopolypropylene having a higher melting point through homopolymerization of propylene, compared to traditional metallocene catalysts, and a method of olefin polymerization in the presence of such a metallocene complex. Also provided are, for example, a metallocene complex represented by general formula [I] (e.g., a metallocene complex having a substituent at position 6 of one or each indenyl ring and an optionally substituted furyl or thienyl group at position 2 of one or each indenyl ring), an olefin polymerization catalyst containing the metallocene complex, and a method of olefin polymerization involving olefin polymerization or copolymerization in the presence of the olefin polymerization catalyst.
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