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340 条记录 (耗时 0.023 秒)

    Process for the synthesis of methanol
    32.
    发明授权
    Process for the synthesis of methanol 有权
    合成甲醇的方法

    公开(公告)号：US08785506B2

    公开(公告)日：2014-07-22

    申请号：US13581709

    申请日：2012-02-14

    申请人： Timothy Douglas Gamlin

    发明人： Timothy Douglas Gamlin

    IPC分类号： C07C27/00 ,  B01J35/04 ,  B01J8/04 ,  C07C29/152 ,  B01J19/24 ,  B01J8/06

    CPC分类号： C07C29/152 ,  B01J8/0415 ,  B01J8/0496 ,  B01J8/067 ,  B01J19/2485 ,  B01J35/04 ,  B01J2208/00814 ,  B01J2219/00038 ,  B01J2219/0004 ,  Y02P20/52 ,  C07C31/04

    摘要： In a process for converting synthesis gas to methanol, gas is introduced through an inlet of a tubular reactor. Reactants pass downwardly through at least one reactor tube to an upper surface of a catalyst carrier and into a passage defined by an inner perforated wall of a carrier container before passing radially through the catalyst bed towards a perforated outer container wall. Reaction occurs as synthesis gas contacts the catalyst. Unreacted reactant and product pass out of the container through the outer container wall and then upwardly between the inner surface of a container skirt and an outer annular container wall, and then over the end of the skirt and downwardly between the outer surface of the skirt and the inner surface of the reactor tube where heat transfer takes place. The steps are repeated at any subsequent catalyst carrier and then product is removed from the reactor outlet.

    摘要翻译： 在将合成气转化为甲醇的方法中，通过管式反应器的入口引入气体。 反应物通过至少一个反应器管到催化剂载体的上表面并进入由载体容器的内部穿孔壁限定的通道中，然后在径向通过催化剂床之前穿过穿孔的外部容器壁。 当合成气与催化剂接触时，会发生反应。 未反应的反应物和产物通过外部容器壁从容器中流出，然后在容器裙部的内表面和外部环形容器壁之间向上，然后在裙部的端部之上，并且在裙部的外表面和 反应器管的内表面发生热传递。 在任何随后的催化剂载体上重复这些步骤，然后从反应器出口除去产物。

    Methane/methanol producing system
    35.
    发明授权
    Methane/methanol producing system 失效
    甲烷/甲醇生产系统

    公开(公告)号：US06913735B2

    公开(公告)日：2005-07-05

    申请号：US10175874

    申请日：2002-06-21

    申请人： Kazuo Imasaki ,  Masahiro Mori ,  Hiroyuki Nagayama

    发明人： Kazuo Imasaki ,  Masahiro Mori ,  Hiroyuki Nagayama

    IPC分类号： C07C1/04 ,  C07C1/12 ,  C07C9/04 ,  C07C29/151 ,  C07C29/152 ,  C07C31/04 ,  H01L31/04 ,  H01M8/06 ,  H01S3/091 ,  B01J19/08

    CPC分类号： C07C29/1518 ,  C07C29/152 ,  Y02E10/542 ,  Y02P70/521 ,  Y10S204/03 ,  C07C31/04

    摘要： A methane or methanol producing system is proposed in which laser beams are generated in space by excitation of sunlight, transmitted onto land or sea without loss to obtain optical energy with high efficiency, and irradiated on a hydrogen producing device to produce industrially inexpensive hydrogen with high efficiency, thereby producing methane or methanol. A laser generating device for generating laser beams by exciting radiant light in laser rods by irradiation of sunlight is installed in space. The laser beams generated are transmitted to a light-receiving facility on land or on sea, and irradiated on a hydrogen generating device having a semiconductor electrode with a wavelength suitable for absorbing by the semiconductor electrode or by converting or shifting to a suitable wavelength. Using the hydrogen, methane or methanol is produced by a methane or methanol producing unit.

    摘要翻译： 提出了一种甲烷或甲醇生产系统，其中通过太阳光的激发在空间中产生激光，在没有损失的情况下传输到陆地或海洋上，以高效率获得光能，并且在氢气生产装置上照射产生工业上便宜的氢，具有高的 从而产生甲烷或甲醇。 激光产生装置用于通过在太阳光照射下激发激光束中的辐射光来产生激光束。 所产生的激光束被传送到陆上或海上的光接收设备，并且照射在具有适于由半导体电极吸收的波长的半导体电极的氢生成装置上，或通过转换或转换到合适的波长。 使用氢气，甲烷或甲醇由甲烷或甲醇生产装置生产。

    Process for the preparation of methanol
    37.
    发明授权
    Process for the preparation of methanol 有权
    甲醇制备方法

    公开(公告)号：US06881759B2

    公开(公告)日：2005-04-19

    申请号：US10806443

    申请日：2004-03-23

    申请人： Poul Erik Højlund Nielsen ,  Cecilia Jaksland ,  Jens Perregaard

    发明人： Poul Erik Højlund Nielsen ,  Cecilia Jaksland ,  Jens Perregaard

    IPC分类号： C07C29/152 ,  C07B61/00 ,  C07C29/151 ,  C07C31/04 ,  C07C27/00

    CPC分类号： C07C29/1512 ,  Y02P20/52 ,  C07C31/04

    摘要： The present invention is a novel process for methanol production in a liquid phase reactor from a synthesis gas comprising of hydrogen, carbon dioxide and carbon monoxide. The liquid phase reactor contains a solid catalyst suspended in methanol. In this innovation, methanol acts both as a product and as a suspension medium for the catalyst. The new innovation exploits the condensing conditions for methanol production. By operating at condensing conditions, the methanol partial pressure at equilibrium is higher than the boiling pressure of methanol at the given temperature. Hence the produced methanol of the equilibrium composition condenses creating the potential of more gas to be converted. Since equilibrium is not a limiting factor, high conversions can be obtained.

    摘要翻译： 本发明是由氢，二氧化碳和一氧化碳组成的合成气体在液相反应器中生产甲醇的新方法。 液相反应器含有悬浮在甲醇中的固体催化剂。 在这项创新中，甲醇既作为产品又作为催化剂的悬浮介质。 新的创新利用甲醇生产的冷凝条件。 通过在冷凝条件下操作，平衡时的甲醇分压高于在给定温度下甲醇的沸腾压力。 因此，产生的平衡组合物的甲醇会凝结，从而产生更多的待转化气体的潜力。 由于平衡不是限制因素，因此可以获得高转化率。

    Method for carrying out heterogeneous catalysis
    38.
    发明授权
    Method for carrying out heterogeneous catalysis 失效
    进行非均相催化的方法

    公开(公告)号：US5925685A

    公开(公告)日：1999-07-20

    申请号：US943212

    申请日：1997-10-06

    申请人： John R. Adams ,  Thomas P. Hickey

    发明人： John R. Adams ,  Thomas P. Hickey

    IPC分类号： B01J8/22 ,  B01D3/00 ,  B01J8/02 ,  B01J10/00 ,  C07B61/00 ,  C07C27/06 ,  C07C29/151 ,  C07C29/152 ,  C07C29/80 ,  C07C31/04 ,  C07C27/00 ,  B01J8/04

    CPC分类号： C07C29/1512 ,  B01D3/009 ,  B01J8/0242 ,  B01J2208/00274 ,  B01J2208/00283 ,  Y02P20/127

    摘要： Catalytic distillation reactions are improved by having an inert condensing component present in the reaction which is boiling and condensing within the reaction which washes the catalyst in the system and, in the case of gaseous reactants, occludes a portion of the reactants to facilitate the reaction without unduly high pressures. The inert condensing component is boiling at the conditions within the reactor and is taken overhead for condensation and return as reflux. The inert condensing component may occlude the gaseous reactants allowing for better contact with the catalyst and provides the benefits of concurrent reaction and distillation, for example, the reaction of CO and H.sub.2 over a copper catalyst to produce methanol using propane as the inert condensing component.

    摘要翻译： 催化蒸馏反应通过在反应中存在的惰性缩合组分得到改善，该反应在反应中沸腾和冷凝，其在系统中洗涤催化剂，并且在气态反应物的情况下，封闭一部分反应物以促进反应而没有 压力过高 惰性冷凝组分在反应器内的条件下沸腾，并在塔顶馏去冷凝并作为回流返回。 惰性冷凝组分可以堵塞气态反应物，从而允许更好地与催化剂接触，并且提供同时反应和蒸馏的优点，例如CO和H 2在铜催化剂上的反应，以使用丙烷作为惰性冷凝组分来生产甲醇。

    Process for carrying out chemical equilibrium reactions
    39.
    发明授权
    Process for carrying out chemical equilibrium reactions 失效
    进行化学平衡反应的方法

    公开(公告)号：US5712313A

    公开(公告)日：1998-01-27

    申请号：US550135

    申请日：1996-02-26

    申请人： Gert Jan Kramer ,  Jean Paul Lange

    发明人： Gert Jan Kramer ,  Jean Paul Lange

    IPC分类号： B01J8/04 ,  C07C29/152 ,  C07C29/151

    CPC分类号： B01J8/0453 ,  C07C29/152 ,  B01J2208/00283 ,  Y02P20/582

    摘要： A process for carrying out a chemical equilibrium reaction is disclosed in which, in a first stage, one or more reactants are contacted with a fixed arrangement of a catalyst under conditions such that the reactants and the products of the reaction are gaseous, the unconverted reactants and products of the first stage being passed to a second stage, in which they are contacted with a fixed arrangement of a catalyst and the reaction allowed to proceed in the presence of an absorbent capable of absorbing a product of the reaction. There is specifically disclosed a process for the synthesis of methanol from carbon monoxide and hydrogen, in which, in a first stage, carbon monoxide and hydrogen are contacted with a fixed arrangement of a catalyst active in catalyzing the synthesis of methanol under conditions such that the methanol formed is present as a gas under the prevailing reaction conditions, the unconverted carbon monoxide and hydrogen and methanol produced in the first stage being passed to a second stage, in which they are contacted with a fixed arrangement of a catalyst active in catalyzing the synthesis of methanol and the reaction allowed to proceed in the presence of an absorbent capable of absorbing methanol.

    摘要翻译： 公开了一种用于进行化学平衡反应的方法，其中在第一阶段中，一种或多种反应物在反应物和反应产物是气态的条件下与固定排列的催化剂接触，未转化的反应物 并且将第一阶段的产物送至第二阶段，在第二阶段中它们与固定的催化剂排列物接触，并且使反应在能够吸收反应产物的吸收剂存在下进行。 具体公开了一种从一氧化碳和氢气合成甲醇的方法，其中在第一阶段中，将一氧化碳和氢气与催化甲醇合成的催化剂的固定排列物接触， 在主要反应条件下，形成的甲醇作为气体存在，将未转化的一氧化碳和在第一阶段中产生的氢气和甲醇转移到第二阶段，在第二阶段中，它们与催化活性的催化剂的固定排列物接触 的甲醇，使反应在能够吸收甲醇的吸收剂存在下进行。

    Catalytic reactor
    40.
    发明授权
    Catalytic reactor 失效
    催化反应器

    公开(公告)号：US5266281A

    公开(公告)日：1993-11-30

    申请号：US780246

    申请日：1991-10-22

    申请人： Richard L. Kao ,  Sarabjit S. Randhava ,  Surjit S. Randhava ,  Shaw-Yaw Kang

    发明人： Richard L. Kao ,  Sarabjit S. Randhava ,  Surjit S. Randhava ,  Shaw-Yaw Kang

    IPC分类号： B01J8/06 ,  C07C29/151 ,  C07C29/152

    CPC分类号： C07C29/1518 ,  B01J8/067 ,  C07C29/152 ,  B01J2208/00212

    摘要： An improved double tube reactor having a plurality of inner and outer tube assemblies each of the assemblies having a reaction annular volume between the inner tube and outer tube and a closed center plug within the inner tube forming an annular thermal exchange volume between the center plug and the inner tube to obtain desired temperature control of exothermic and endothermic catalytic chemical reactions. In one embodiment of the invention, the improved double tube reactor is used in a process for production of high purity methanol from process gas produced by steam reforming hydrocarbon feedstocks in a tube type reformer followed by removing substantially all CO.sub.2 and H.sub.2 O from the process gas, adjusting the H.sub.2 /CO molar ratio to about 2 when necessary, and feeding the adjusted process gas to a methanol synthesis reactor contacting a methanol forming catalyst not requiring CO.sub.2 activation at about 200.degree. to about 300.degree. C. to produce product gas comprising methanol, and recovering liquid methanol having purity greater than about 99.85% pure by cooling the product gas to a temperature below the boiling point of methanol and separating the liquid methanol from gaseous components of the product gas. In a preferred embodiment, process gas of H.sub.2 /CO molar ratio of about 2.0 to about 2.5 is passed through an annular thermal exchange volume between a center plug and an inner tube followed by passing the gas in contact with a catalyst in a catalyst bed between the inner tube and an outer tube of a double tube reactor assembly promoting the direct reaction of H.sub.2 and CO to product methanol.

    摘要翻译： 一种改进的双管反应器，具有多个内管组件和外管组件，每个组件在内管和外管之间具有反应环形体积，内管内的封闭中心塞形成中心塞和中心塞之间的环形热交换体积 内管获得所需的放热和吸热催化化学反应的温度控制。 在本发明的一个实施方案中，改进的双管反应器用于从管式重整器中的蒸汽重整烃原料生产的工艺气体生产高纯度甲醇的方法，随后从工艺气体中除去基本上所有的CO 2和H 2 O， 在必要时将H 2 / CO摩尔比调节至约2，并将经调节的处理气体送入甲醇合成反应器，甲醇合成反应器在约200℃至约300℃下接触不需要CO 2活化的甲醇形成催化剂以产生包含甲醇的产物气体， 并通过将产物气体冷却至低于甲醇沸点的温度并将液体甲醇与产物气体的气体组分分离来回收纯度大于约99.85％纯度的液体甲醇。 在优选的实施方案中，将H 2 / CO摩尔比为约2.0至约2.5的工艺气体通过中心塞和内管之间的环形热交换体积，然后使气体与催化剂接触，催化剂床在 内管和双管反应器组件的外管，其促进H 2和CO与产物甲醇的直接反应。