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    System unit for desorbing carbon dioxide from methanol
    1.
    发明申请
    System unit for desorbing carbon dioxide from methanol 有权
    从甲醇中解吸二氧化碳的系统单元

    公开(公告)号：US20060107690A1

    公开(公告)日：2006-05-25

    申请号：US10520292

    申请日：2003-04-19

    申请人： William Davey ,  Manfred Meyer

    发明人： William Davey ,  Manfred Meyer

    IPC分类号： F25J3/00

    CPC分类号： C10K1/165 ,  B01D53/1425 ,  Y10S62/928

    摘要： The invention relates to a system unit for desorbing carbon dioxide and other impurities from highly pressurized methanol. Said system unit comprises at least one or more expansion vessels arranged in succession, at least one heat exchanger, and at least one liquid/gas separator. The inventive system unit contains: a) a line (1) through which the intensely cooled methanol leaving expansion vessel (C) is introduced into the heat exchanger (E) from underneath, and; b) a line (2), though which the heated methanol is drawn out of the heat exchanger (E) from the top, and which serves to connect said heat exchanger to a liquid/gas separator inside of which the remaining carbon dioxide still contained in the methanol is desorbed and separated out to the greatest possible extent. This system unit enables the cold due to evaporation, said cold resulting during the desorption of carbon dioxide, to be obtained inside a heat exchanger and constitutes an important cold energy source for carrying out absorption.

    摘要翻译： 本发明涉及一种用于从高压甲醇中解吸二氧化碳和其他杂质的系统单元。 所述系统单元包括连续排列的至少一个或多个膨胀容器，至少一个热交换器和至少一个液/气分离器。 本发明的系统单元包含：a）一条管线（1），离开膨胀容器（C）的强烈冷却的甲醇通过该管路从下面引入到热交换器（E）中; b）线（2），其中加热的甲醇从顶部从热交换器（E）引出，并且用于将所述热交换器连接到液体/气体分离器，其中剩余的二氧化碳仍然含有 在甲醇中解吸并分离出最大可能的程度。 该系统单元能够在热交换器内由于蒸发而导致冷，所述冷却在二氧化碳解吸期间获得，并且构成用于进行吸收的重要的冷能源。

    System unit for desorbing carbon dioxide from methanol
    4.
    发明授权
    System unit for desorbing carbon dioxide from methanol 有权
    从甲醇中解吸二氧化碳的系统单元

    公开(公告)号：US07461521B2

    公开(公告)日：2008-12-09

    申请号：US10520292

    申请日：2003-04-19

    申请人： William Davey ,  Manfred Meyer

    发明人： William Davey ,  Manfred Meyer

    IPC分类号： F25J3/00

    CPC分类号： C10K1/165 ,  B01D53/1425 ,  Y10S62/928

    摘要： The invention relates to a system unit for desorbing carbon dioxide and other impurities from highly pressurized methanol. Said system unit comprises at least one or more expansion vessels arranged in succession, at least one heat exchanger, and at least one liquid/gas separator. The inventive system unit contains: a) a line (1) through which the intensely cooled methanol leaving expansion vessel (C) is introduced into the heat exchanger (E) from underneath, and; b) a line (2), though which the heated methanol is drawn out of the heat exchanger (E) from the top, and which serves to connect said heat exchanger to a liquid/gas separator inside of which the remaining carbon dioxide still contained in the methanol is desorbed and separated out to the greatest possible extent. This system unit enables the cold due to evaporation, said cold resulting during the desorption of carbon dioxide, to be obtained inside a heat exchanger and constitutes an important cold energy source for carrying out absorption.

    摘要翻译： 本发明涉及一种用于从高压甲醇中解吸二氧化碳和其他杂质的系统单元。 所述系统单元包括连续排列的至少一个或多个膨胀容器，至少一个热交换器和至少一个液/气分离器。 本发明的系统单元包含：a）一条管线（1），离开膨胀容器（C）的强烈冷却的甲醇通过该管路从下面引入到热交换器（E）中; b）线（2），其中加热的甲醇从顶部从热交换器（E）引出，并且用于将所述热交换器连接到液体/气体分离器，其中剩余的二氧化碳仍然含有 在甲醇中解吸并分离出最大可能的程度。 该系统单元能够在热交换器内由于蒸发而导致冷，所述冷却在二氧化碳解吸期间获得，并且构成用于进行吸收的重要的冷能源。

    Coproduction Of Methanol And Ammonia From Natural Gas
    5.
    发明申请
    Coproduction Of Methanol And Ammonia From Natural Gas 失效
    从天然气共同生产甲醇和氨

    公开(公告)号：US20070299144A1

    公开(公告)日：2007-12-27

    申请号：US10593925

    申请日：2005-02-10

    申请人： William Davey ,  Thomas Wurzel

    发明人： William Davey ,  Thomas Wurzel

    IPC分类号： C07C29/151 ,  C01C1/04

    CPC分类号： C07C29/1518 ,  C01B3/025 ,  C01B3/382 ,  C01B3/52 ,  C01B2203/0244 ,  C01B2203/0261 ,  C01B2203/0415 ,  C01B2203/044 ,  C01B2203/047 ,  C01B2203/0475 ,  C01B2203/048 ,  C01B2203/061 ,  C01B2203/068 ,  C01B2203/0844 ,  C01B2203/142 ,  C01B2203/82 ,  C01C1/0488 ,  Y02P20/52 ,  C07C31/04

    摘要： The invention relates to a method for the coproduction of methanol and ammonia having the following steps: 1. Natural gas (stream 1), steam and oxygen are mixed together in a reactor A, wherein the natural gas is partially oxidized and further reformed with the aid of catalysts, 2. The gas mixture taken from reactor A is divided into stream (stream 2) for the methanol synthesis in a unit E and another stream (stream 3) for hydrogen production, 3. The carbon monoxide present in the stream (stream 3) for the hydrogen production is converted into carbon dioxide with aid from catalysts and intermediate cooling stages, 4. Remaining impurities such as methane, traces of carbon monoxide and argon are washed out in a purification unit D, and hydrogen (streams 6, 8) is fed to the methanol synthesis in the unit E and the ammonia synthesis in a unit F, 5. The methanol synthesis gas (stream 7) is converted into methanol (stream 9) in a unit E with the help of a catalyst, and the methanol is brought to the required purity by distillation, 6. The ammonia synthesis gas (stream 8) is compressed and with the help of a catalyst is converted to ammonia (stream 10) in unit F, and the ammonia is separated from the recovered synthesis gas by partial condensation.

    摘要翻译： 本发明涉及一种用于共同生产甲醇和氨的方法，其具有以下步骤：1.天然气（流1），蒸汽和氧气在反应器A中混合在一起，其中天然气被部分氧化并进一步用 从反应器A获取的气体混合物被分成用于在单元E中进行甲醇合成的流（流2）和用于产氢的另一流（流3）。3.存在于流中的一氧化碳 在催化剂和中间冷却阶段的帮助下，用于氢气生产的物流3）转化为二氧化碳。4.在净化单元D中清洗剩余的杂质如甲烷，一氧化碳和氩的痕量，并将氢（流6， 8）在单元E中进料到甲醇合成中，并在单元F，5中进行氨合成。借助于催化剂，将甲醇合成气（流7）以单元E转化为甲醇（物流9） 甲醇是 通过蒸馏得到所需的纯度。6.氨合成气（料流8）被压缩，借助于催化剂将其转化为单元F中的氨（流10），并将氨从回收的合成气中分离出来 部分冷凝。

    ATMOSPHERIC PRESSURE GASIFICATION PROCESS AND SYSTEM
    7.
    发明申请
    ATMOSPHERIC PRESSURE GASIFICATION PROCESS AND SYSTEM 审中-公开
    大气压力气化过程和系统

    公开(公告)号：US20110173885A1

    公开(公告)日：2011-07-21

    申请号：US13009511

    申请日：2011-01-19

    申请人： William Davey ,  Michael Trovant

    发明人： William Davey ,  Michael Trovant

    IPC分类号： B01J7/00 ,  B65G33/08

    CPC分类号： C10J3/00 ,  C10J3/30 ,  C10J3/50 ,  C10J2200/15 ,  C10J2200/158

    摘要： A fuel supply system for supplying pulverized feedstock to a gasifier includes a feedstock storage apparatus for storing pulverized feedstock. The feedstock storage apparatus operates at a first pressure. The fuel supply system also includes a mechanical conveyance apparatus linking the feedstock storage apparatus to a fuel distribution apparatus. The mechanical conveyance apparatus is operable to continuously convey the pulverized feedstock from the feedstock storage apparatus to the fuel distribution apparatus at a first flow rate. The fuel distribution apparatus operates at a second pressure that is greater than the first pressure. The fuel distribution apparatus includes at least one outlet communicably connected to at least one burner on the gasifier for transferring pulverized feedstock from the fuel distribution apparatus to the at least one burner.

    摘要翻译： 用于将粉碎的原料供给到气化器的燃料供给系统包括用于储存粉碎原料的原料储存装置。 原料储存装置在第一压力下操作。 燃料供给系统还包括将原料储存装置连接到燃料分配装置的机械输送装置。 该机械输送装置可操作以使第一流量将粉碎的原料从原料储存装置输送到燃料分配装置。 燃料分配装置在大于第一压力的第二压力下操作。 燃料分配装置包括至少一个出口，其可通信地连接到气化器上的至少一个燃烧器，用于将粉碎的原料从燃料分配装置传送到至少一个燃烧器。

    Method for the production of urea from natural gas
    8.
    发明授权
    Method for the production of urea from natural gas 失效
    从天然气生产尿素的方法

    公开(公告)号：US07674932B2

    公开(公告)日：2010-03-09

    申请号：US11665278

    申请日：2005-08-18

    申请人： William Davey ,  Thomas Wurzei

    发明人： William Davey ,  Thomas Wurzei

    IPC分类号： C07C273/02 ,  C07C237/04

    CPC分类号： C07C273/10 ,  C01C1/0488 ,  C07C273/04 ,  Y02P20/52

    摘要： Disclosed is a method for the production of urea from natural gas, wherein a) natural gas undergoes partial oxidation or autothermal reformation with a gas containing oxygen in a first step and the raw synthesis gas thus arising, consisting essentially of carbon monoxide, carbon dioxide, methane and hydrogen, can be transformed by catalytic conversion of CO and H2O to form CO2 and H2, whereupon carbon monoxide and methane are removed in a multistep gas cleaning process and the hydrogen is converted into ammonia upon addition of nitrogen, and subsequently, b) the ammonia is recombined with the previously separated carbon dioxide in a second step and the ammonia is thus fully converted into urea.

    摘要翻译： 公开了一种从天然气生产尿素的方法，其中a）天然气在第一步中用含氧气体进行部分氧化或自热重整，由此产生的原始合成气基本上由一氧化碳，二氧化碳， 甲烷和氢气可以通过CO和H 2 O的催化转化来转化以形成CO 2和H 2，从而在多步骤气体清洗过程中除去一氧化碳和甲烷，并且在加入氮气时将氢气转化成氨，随后b） 在第二步骤中氨与先前分离的二氧化碳重组，因此氨完全转化为尿素。

    Coproduction of methanol and ammonia from natural gas
    9.
    发明授权
    Coproduction of methanol and ammonia from natural gas 失效
    从天然气共同生产甲醇和氨

    公开(公告)号：US07521483B2

    公开(公告)日：2009-04-21

    申请号：US10593925

    申请日：2005-02-10

    申请人： William Davey ,  Thomas Wurzel

    发明人： William Davey ,  Thomas Wurzel

    IPC分类号： C07C27/14

    CPC分类号： C07C29/1518 ,  C01B3/025 ,  C01B3/382 ,  C01B3/52 ,  C01B2203/0244 ,  C01B2203/0261 ,  C01B2203/0415 ,  C01B2203/044 ,  C01B2203/047 ,  C01B2203/0475 ,  C01B2203/048 ,  C01B2203/061 ,  C01B2203/068 ,  C01B2203/0844 ,  C01B2203/142 ,  C01B2203/82 ,  C01C1/0488 ,  Y02P20/52 ,  C07C31/04

    摘要： The invention relates to a method for the coproduction of methanol and ammonia from natural gas involving the following steps: 1. Natural gas (flow 1) , steam and oxygen are mixed with one another in a reactor A during which the natural gas is partially oxidized and additionally reformed with the aid of catalysts; 2. The gas mixture removed from reactor A is split into a flow (flow 2) for synthesizing methanol in a unit E and into another flow (flow 3) for producing hydrogen; 3. The carbon monoxide present in flow (flow 3) for producing hydrogen is converted into carbon dioxide inside reactor B with the aid of catalysts and intermediate cooling stages; 4. Remaining impurities such as methane, traces of carbon monoxide and argon are washed out in a cleaning unit D, and hydrogen (flows 6, 8) is fed to the methanol synthesis in unit E and to the ammonia synthesis in unit F; 5. The methanol synthesis gas (flow 7) is converted into methanol (flow 9) with the aid of a catalyst, and the methanol is brought to the required level of purity by distillation; 6. The ammonia synthesis gas,(flow 8) is compressed in unit F and converted into ammonia (flow 10) with the aid of a catalyst, and the ammonia is separated from the recovered synthesis gas by partial condensation.

    摘要翻译： 本发明涉及一种从天然气共同生产甲醇和氨的方法，包括以下步骤：1.天然气（流量1），蒸汽和氧气在反应器A中彼此混合，在该反应器中天然气被部分氧化 并借助催化剂进一步改性; 从反应器A中除去的气体混合物被分成用于合成单元E中的甲醇的流（流2）和用于产生氢的另一流（流3） 在催化剂和中间冷却阶段的帮助下，存在于流动（流动3）中用于产生氢的一氧化碳转化为反应器B内的二氧化碳; 剩余的杂质如甲烷，痕量一氧化碳和氩气在清洗装置D中洗掉，氢气（6,8）加入到单位E的甲醇合成物和单元F中的氨合成中; 5.使用催化剂将甲醇合成气（流程7）转化为甲醇（流程9），通过蒸馏使甲醇达到要求的纯度; 氨合成气（流8）在单元F中被压缩并借助于催化剂转化为氨（流10），氨通过部分冷凝与回收的合成气分离。