COATED LITHIUM-ION SIEVE AND PREPARATION METHOD THEREOF

    公开(公告)号:US20240165579A1

    公开(公告)日:2024-05-23

    申请号:US17777012

    申请日:2021-10-09

    摘要: The present invention disclosures a preparation method for a coated lithium ion sieve, the method comprises: S01: calcining manganese salt in an air atmosphere for 2 h˜10 h to form Mn2O3; S02: mixing Mn2O3 with lithium salt and grinding, reacting in a high-pressure reaction kettle at 100° C.˜200° C. for 36 h˜72 h to form a product of LiMnO2; wherein, the molar ratio of Mn2O3 and Li/Mn in the lithium salt is 1:1˜10:1; S03: adding LiMnO2 to a metal coating reagent and ultrasonic mixing for 2 h˜10 h, drying for 6 h˜24 h, and then calcining at 400° C.˜600° C. for 2 h˜10 h to form an oxide-coated Li1.6Mn1.6O4 lithium ion adsorbent; Wherein, the molar ratio of the metal coating reagent to LiMnO2 is 0.01:1˜0.08:1; S04: performing an acid treatment to the oxide-coated Li1.6Mn1.6O4 lithium-ion adsorbent to form an acidified product, washing the acidified product and drying to form the coated lithium-ion sieve. The cell structure of the coated lithium-ion sieve of the present invention is more stabler and can be reused for many cycles, which solves a problem that traditional HMn2O4 lithium-ion sieve is easy to dissolve.