Abstract:
The invention is directed to an electrochemical separator structure. The structure is formed of a material that includes manganese-stabilized beta″-alumina. The manganese is present at a level of about 1% by weight to about 20% by weight. Another embodiment is directed to an energy storage device that includes the electrochemical separator structure.
Abstract:
A coating method is provided. The coating method includes applying, via electrophoretic deposition or slurry deposition, an overcoat composition on an outer surface of a thermal barrier coating system on a substrate. The overcoat composition includes a coating material comprising a plurality of particles having a particle size of less than 1000 nm. The method includes sintering the overcoat composition in the presence of one or more sintering aids to form an overcoat layer having a surface roughness of less than 1 micrometer.
Abstract:
A composition comprising a rare earth solid solution, at least one of HfO2 and CaZrO3/MgZrO3; and balance ZrO2. The rare earth solid solution may include Gd2O3 and Lu2O3. In another example, the rare earth solid solution may include Gd2O3, Lu2O3, and at least one of Yb2O3 and Sm2O3.
Abstract:
An electrochemical cell is described, including an anodic chamber and a cathodic chamber separated by an electrolyte separator tube, all contained within a cell case. The cell also includes an electrically insulating ceramic collar positioned at an opening of the cathodic chamber, and defining an aperture in communication with the opening; along with a cathode current collector assembly; and at least one metallic ring that has a coefficient of thermal expansion (CTE) in the range of about 3 to about 7.5 ppm/° C., contacting at least a portion of a metallic component within the cell, and an adjacent ceramic component. An active braze alloy composition attaches and hermetically seals the ring to the metallic component and the collar. Sodium metal halide batteries that contain this type of cell are also described, along with methods for sealing structures within the cell.
Abstract:
A braze alloy composition is disclosed, containing nickel, about 5% to about 40% of at least one refractory metal selected from niobium, tantalum, or molybdenum; about 2% to about 32% chromium; and about 0.5% to about 10% of at least one active metal element. An electrochemical cell that includes two components joined to each other by such a braze composition is also described. A method for joining components such as those within an electrochemical cell is also described. The method includes the step of introducing a braze alloy composition between a first component and a second component to be joined, to form a brazing structure. In many instances, one component is formed of a ceramic, while the other is formed of a metal or metal alloy.
Abstract:
A composite composition that includes an MCrAlX alloy and a nano-oxide ceramic is disclosed. In the formula, M includes nickel, cobalt, iron, or a combination thereof, and X includes yttrium, hafnium, or a combination thereof, from about 0.001 percent to about 2 percent by weight of the alloy. The amount of the nano-oxide ceramic is greater than about 40 percent, by volume of the composition. A protective covering that includes the composite composition is also disclosed. The protective covering can be attached to a tip portion of a blade with a braze material. A method for joining a protective covering to a tip portion of a blade, and a method for repair of a blade, are also provided.
Abstract:
The present application provides for ceramic collars and metal rings for active brazing in sodium-based thermal batteries. The ceramic collar may be an alpha-alumina collar configured for active brazing, and thereby sealing, to outer and inner Ni rings for use in NaMx cells. The portions of the alpha-alumina collar active brazed to the outer and inner Ni rings may be outwardly facing and include inwardly extending recesses. The portions of the outer and inner Ni rings active brazed to the outwardly facing portions of the collar may be inwardly facing. The alpha-alumina collar may include a greater coefficient of thermal expansion than each of the outer and inner Ni rings, and the alpha-alumina collar and outer and inner Ni rings may be configured such that a portion of the outer and inner Ni rings is deformed into the inwardly extending recesses of the alpha-alumina collar after active brazing thereof.
Abstract:
An energy storage cell is disclosed, including an anodic chamber for containing an anodic material and a cathodic chamber for containing a cathodic material, separated from each other by an electrolyte separator tube, and all contained within a case for the cell. The cell further includes a ceramic collar positioned at an opening of the cathodic chamber, defining an aperture in communication with the opening, and a current collector brazed to the ceramic collar, extending into the cathodic chamber. The current collector is in the form of a porous, metallic mesh, and the case and the ceramic collar are hermetically sealed to each other by an active braze material. Sodium metal halide batteries based on a number of these cells are also disclosed.