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    High temperature sodium battery with high energy efficiency
    1.
    发明授权
    High temperature sodium battery with high energy efficiency 有权
    高能量钠电池，能效高

    公开(公告)号：US09431681B2

    公开(公告)日：2016-08-30

    申请号：US14478676

    申请日：2014-09-05

    申请人： CERAMATEC, INC.

    发明人： Ashok V. Joshi ,  Sai Bhavaraju

    IPC分类号： H02J7/00 ,  H01M10/39 ,  H01M10/46

    CPC分类号： H01M10/3909 ,  H01M10/3918 ,  H01M10/465 ,  H01M2300/0028 ,  H01M2300/0045 ,  H01M2300/0054

    摘要： A molten sodium secondary cell charges at a high temperature and discharges at a relatively lower temperature. The cell includes a sodium anode and a cathode. A sodium ion conductive solid membrane separates the cathode from the sodium anode and selectively transports sodium ions. A solar energy source includes a photovoltaic system to provide an electric charging potential to the sodium anode and the cathode and a solar thermal concentrator to provide heat to the cathode and catholyte composition to cause the molten sodium secondary cell to charge at a temperature in the range from about 300 to 800° C. The cell has a charge temperature and a charge voltage and a discharge temperature and a discharge voltage. The charge temperature is substantially higher than the discharge temperature, and the charge voltage is lower than the discharge voltage.

    摘要翻译： 熔融的钠二次电池在高温下充电并在相对较低的温度下放电。 电池包括钠阳极和阴极。 钠离子导电固体膜将阴极与钠阳极分开并选择性地输送钠离子。 太阳能源包括为钠阳极和阴极提供充电电势的光伏系统和向阴极和阴极电解液组合物提供热量的太阳能热收集器，以使熔融钠二次电池在范围内的温度下充电 约300至800℃。电池具有充电温度和充电电压以及放电温度和放电电压。 充电温度显着高于放电温度，充电电压低于放电电压。

    Sodium Secondary Battery
    3.
    发明申请
    Sodium Secondary Battery 审中-公开
    钠二次电池

    公开(公告)号：US20160049658A1

    公开(公告)日：2016-02-18

    申请号：US14824500

    申请日：2015-08-12

    申请人： SK Innovation Co., Ltd. ,  Ceramatec, Inc.

    发明人： JeHyun Chae ,  JeongSoo Kim ,  JongSeon Kim ,  Sai Bhavaraju

    IPC分类号： H01M4/58 ,  H01M10/39

    CPC分类号： H01M10/0568 ,  H01M10/0569 ,  H01M10/3918 ,  H01M10/3954 ,  H01M2300/0028 ,  H01M2300/0068

    摘要： Provided is a sodium secondary battery including: an anode containing sodium; a cathode containing sulfur; a cathode electrolyte solution being in contact with the cathode and capable of conducting sodium ions into and from a solid electrolyte membrane; and a solid electrolyte separating the anode and the cathode electrolyte solution and having sodium ion conductivity. The sodium secondary battery of the present invention overcomes the problems of thermal management and heat sealing due to a high operating temperature, possessed by the existing sodium-sulfur battery or sodium-nickel chloride battery (so called, a ZEBRA battery), and may achieve high a charge and discharge mechanism characteristic.

    摘要翻译： 提供一种钠二次电池，其包括：含有钠的阳极; 含硫的阴极; 阴极电解质溶液与阴极接触并能够将钠离子导入固体电解质膜和从固体电解质膜中导出钠离子; 以及分离阳极和阴极电解质溶液并具有钠离子传导性的固体电解质。 本发明的钠二次电池克服了由于现有的钠硫电池或钠 - 氯化镍电池（所谓的ZEBRA电池）具有的高工作温度下的热管理和热封的问题，并且可以实现 高放电机理特点。

    SODIUM-CHALCOGEN CELL
    4.
    发明申请
    SODIUM-CHALCOGEN CELL 审中-公开
    钠溶细胞

    公开(公告)号：US20140011096A1

    公开(公告)日：2014-01-09

    申请号：US13992664

    申请日：2011-10-20

    申请人： Andre Moc ,  Ulrich Eisele ,  Alan Logeat

    发明人： Andre Moc ,  Ulrich Eisele ,  Alan Logeat

    IPC分类号： H01M10/39 ,  H01M10/38

    CPC分类号： H01M10/3918 ,  H01M4/38 ,  H01M10/38 ,  H01M10/399 ,  H01M2300/0071 ,  Y10T29/49108

    摘要： A sodium-chalcogen cell is described which is operable at room temperature, in particular a sodium-sulfur or sodium-oxygen cell, the anode and cathode of which are separated by a solid electrolyte which is conductive for sodium ions and nonconductive for electrons. The cathode of the sodium-chalcogen cell includes a solid electrolyte which is conductive for sodium ions and electrons. Moreover, a manufacturing method for this type of sodium-chalcogen cell is described.

    摘要翻译： 描述了在室温下可操作的钠 - 硫族元素电池，特别是钠 - 硫或钠 - 氧电池，其阳极和阴极被固定电解质分离，固体电解质对于钠离子是导电的，而对于电子是不导电的。 钠 - 硫族元素电池的阴极包括对钠离子和电子是导电的固体电解质。 此外，描述了这种类型的钠 - 硫族元素电池的制造方法。

    LOW TEMPERATURE MOLTEN SODIUM SECONDARY CELL WITH SODIUM ION CONDUCTIVE ELECTROLYTE MEMBRANE
    6.
    发明申请
    LOW TEMPERATURE MOLTEN SODIUM SECONDARY CELL WITH SODIUM ION CONDUCTIVE ELECTROLYTE MEMBRANE 有权
    低温硅酸钠二次电池与钠离子电导膜

    公开(公告)号：US20120219833A1

    公开(公告)日：2012-08-30

    申请号：US13290716

    申请日：2011-11-07

    申请人： W. Grover Coors ,  Chett Boxley ,  Mathew Robins ,  Alexis Eccleston

    发明人： W. Grover Coors ,  Chett Boxley ,  Mathew Robins ,  Alexis Eccleston

    IPC分类号： H01M10/02 ,  H01M10/42

    CPC分类号： H01M10/39 ,  H01B1/122 ,  H01M4/32 ,  H01M4/362 ,  H01M4/381 ,  H01M4/48 ,  H01M4/52 ,  H01M10/054 ,  H01M10/0562 ,  H01M10/38 ,  H01M10/3918 ,  H01M2300/002 ,  H01M2300/0094

    摘要： The present invention provides a molten sodium secondary cell. In some cases, the secondary cell includes a sodium metal negative electrode, a positive electrode compartment that includes a positive electrode disposed in a liquid positive electrode solution, and a sodium ion conductive electrolyte membrane that separates the negative electrode from the positive electrode solution. In such cases, the electrolyte membrane can comprise any suitable material, including, without limitation, a NaSICON-type membrane. Furthermore, in such cases, the liquid positive electrode solution can comprise any suitable positive electrode solution, including, but not limited to, an aqueous sodium hydroxide solution. Generally, when the cell functions, the sodium negative electrode is molten and in contact with the electrolyte membrane. Additionally, the cell is functional at an operating temperature between about 100° C. and about 170° C. Indeed, in some instances, the molten sodium secondary cell is functional between about 110° C. and about 130° C.

    摘要翻译： 本发明提供一种熔融钠二次电池。 在一些情况下，二次电池包括钠金属负极，包括设置在液体正极溶液中的正极的正电极室和将负极与正极溶液分离的钠离子导电电解质膜。 在这种情况下，电解质膜可以包括任何合适的材料，包括但不限于NaSICON型膜。 此外，在这种情况下，液体正极溶液可以包括任何合适的正极溶液，包括但不限于氢氧化钠水溶液。 通常，当电池发挥功能时，钠负极熔融并与电解质膜接触。 此外，电池在约100℃至约170℃的工作温度下起作用。实际上，在一些情况下，熔融钠二次电池在约110℃至约130℃之间起作用。

    ELECTROCHEMICAL CELL
    7.
    发明申请
    ELECTROCHEMICAL CELL 有权
    电化学细胞

    公开(公告)号：US20120164540A1

    公开(公告)日：2012-06-28

    申请号：US13218310

    申请日：2011-08-25

    申请人： Hyun-Ki Park ,  Dong-Hee Han ,  Jeong-Doo Yi ,  Ju-Yong Kim

    发明人： Hyun-Ki Park ,  Dong-Hee Han ,  Jeong-Doo Yi ,  Ju-Yong Kim

    IPC分类号： H01M10/0562 ,  C04B35/10

    CPC分类号： H01M10/3918 ,  H01M10/054 ,  H01M10/0562 ,  H01M10/3927 ,  H01M2300/0088 ,  H01M2300/0091

    摘要： A solid electrolyte is disclosed. The solid electrolyte includes a main portion that includes β-alumina or β″-alumina, and an edge portion integrally provided with the main portion. The edge portion has a mixed portion that includes α-alumina and includes β alumina or β″-alumina. A concentration gradient of the α-alumina in the edge portion decreases in a first direction from the edge portion to the main portion.

    摘要翻译： 公开了一种固体电解质。 固体电解质包括主要部分，其包括“氧化铝”和“氧化铝”，以及与主要部分一体地设置的边缘部分。 边缘部分具有包括α-氧化铝的混合部分，并且包括＆lt; bgr; 氧化铝或“氧化铝”。 边缘部分中的α-氧化铝的浓度梯度在从边缘部分到主要部分的第一方向上减小。

    SOLID-STATE SODIUM-BASED SECONDARY CELL HAVING A SODIUM ION CONDUCTIVE CERAMIC SEPARATOR
    9.
    发明申请
    SOLID-STATE SODIUM-BASED SECONDARY CELL HAVING A SODIUM ION CONDUCTIVE CERAMIC SEPARATOR 有权
    具有钠离子导电陶瓷分离器的固体状态的钠基二次电池

    公开(公告)号：US20110104526A1

    公开(公告)日：2011-05-05

    申请号：US12940864

    申请日：2010-11-05

    申请人： Chett Boxley ,  W. Grover Coors ,  John Joseph Watkins

    发明人： Chett Boxley ,  W. Grover Coors ,  John Joseph Watkins

    IPC分类号： H01M2/00 ,  H01M10/02

    CPC分类号： H01M10/0569 ,  H01M2/1646 ,  H01M4/38 ,  H01M4/381 ,  H01M4/40 ,  H01M4/52 ,  H01M10/05 ,  H01M10/054 ,  H01M10/056 ,  H01M10/0562 ,  H01M10/0567 ,  H01M10/30 ,  H01M10/3909 ,  H01M10/3918 ,  H01M2300/0028 ,  H01M2300/0045 ,  H01M2300/0071 ,  Y02E60/12

    摘要： The present invention provides a solid-state sodium-based secondary cell (or rechargeable battery). While the secondary cell can include any suitable component, in some cases, the secondary cell comprises a solid sodium metal negative electrode that is disposed in a non-aqueous negative electrolyte solution that includes an ionic liquid. Additionally, the cell comprises a positive electrode that is disposed in a positive electrolyte solution. In order to separate the negative electrode and the negative electrolyte solution from the positive electrolyte solution, the cell includes a sodium ion conductive electrolyte membrane. Because the cell's negative electrode is in a solid state as the cell functions, the cell may operate at room temperature. Additionally, where the negative electrolyte solution contains the ionic liquid, the ionic liquid may impede dendrite formation on the surface of the negative electrode as the cell is recharged and sodium ions are reduced onto the negative electrode.

    摘要翻译： 本发明提供了一种固态钠基二次电池（或可再充电电池）。 虽然二次电池可以包括任何合适的组分，但在一些情况下，二次电池包括固体钠金属负极，其设置在包含离子液体的非水性负电解质溶液中。 此外，电池包括设置在正电解质溶液中的正电极。 为了将负极和负极电解质溶液与正极电解质溶液分离，电池包括钠离子传导性电解质膜。 因为电池的负极在电池起作用时处于固态，电池可以在室温下运行。 此外，当负电解质溶液含有离子液体时，当电池被再充电并且钠离子被还原到负极上时，离子液体可能阻碍负极表面上的枝晶形成。