Acidic aqueous composition for electrolytically depositing a copper deposit

    公开(公告)号:US12054843B2

    公开(公告)日:2024-08-06

    申请号:US17920509

    申请日:2021-04-22

    摘要: The invention relates to an acidic aqueous composition for electrolytic copper plating, the composition comprising

    (i) copper (II) ions,
    (ii) one or more than one suppressor consisting of or comprising

    one single N-heteroaromatic mono-ring, said mono-ring comprising at least two ring nitrogen atoms and more than one substituent covalently connected to one of said ring nitrogen atoms and/or a ring carbon atom, wherein said substituent independently is or comprises
    one or more than one linear or branched polyalkylene glycol moiety, and/or
    one or more than one linear or branched polyalkylene glycol block polyalkylene glycol, or random polyalkylene glycol moiety,
    with the proviso that
    if said suppressor comprises a OH group, then it is a terminal OH group of said polyalkylene glycol moiety, polyalkylene glycol block polyalkylene glycol, and random polyalkylene glycol moiety, respectively, and
    said suppressor does not comprise NH2 groups, halogen atoms, and sulfur atoms;

    a method of electrolytic copper plating using the acidic aqueous composition; and specific suppressors as defined above.

    Method for improving mechanical properties by changing gradient nanotwinned structure of metallic material

    公开(公告)号:US12000057B2

    公开(公告)日:2024-06-04

    申请号:US17044617

    申请日:2018-09-20

    摘要: A method for improving mechanical properties by changing a gradient nanotwinned structure of metallic materials is the technical field of nanostructured metallic materials. The method uses the inherent principles of microstructure and mechanical properties of metallic materials to improve materials mechanical properties. The metallic materials has a gradient nanotwinned structure. The principles of microstructure and mechanical properties of the metallic materials mean that the mechanical properties of the metallic materials are adjusted by changing the structural gradient scale of the nanotwinned structure. The method combines two strengthening methods of nanotwins and gradient structure, and can obviously improve the mechanical properties of the metallic materials. For pure copper materials of the gradient nanotwinned structure prepared by an electrodeposition technology: the yield strength is 481±15 MPa, the tensile strength is 520±12 MPa, the uniform elongation can be 7±0.5%, and the elongation to failure can be 11.7±1.3%.

    ROUGHENED COPPER FOIL, COPPER-CLAD LAMINATE AND PRINTED WIRING BOARD

    公开(公告)号:US20240175162A1

    公开(公告)日:2024-05-30

    申请号:US18284630

    申请日:2022-03-17

    IPC分类号: C25D1/04 C25D5/00 H05K1/09

    CPC分类号: C25D1/04 C25D5/605 H05K1/09

    摘要: Provided is a roughened copper foil capable of achieving both excellent transmission characteristics and suppression of powdering. This roughened copper foil includes a roughened surface on at least one side. The roughened surface has a roughness slope tan θ of 0.58 or less as calculated based on a mean height Rc (μm) and a mean width RSm (μm) of profile elements by formula Rc/(0.5×RSm), and a sharpness index Rc×Sku of 2.35 or less that is a product of the mean height Rc (μm) and a kurtosis Sku. Rc and RSm are values measured in accordance with JIS B0601-2013 under a condition of not performing a cutoff by a cutoff value λs and a cutoff value λc, and Sku is a value measured in accordance with ISO 25178 under a condition of not performing a cutoff using an S filter and an L filter.