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    Aliphatic polyester polyols from cyclohexane oxidation byproduct streams as precursors for polyurethane and polyisocyanurate polymers
    2.
    发明授权
    Aliphatic polyester polyols from cyclohexane oxidation byproduct streams as precursors for polyurethane and polyisocyanurate polymers 有权
    来自环己烷氧化副产物流的脂肪族聚酯多元醇作为聚氨酯和聚异氰脲酸酯聚合物的前体

    公开(公告)号：US09056940B2

    公开(公告)日：2015-06-16

    申请号：US13493840

    申请日：2012-06-11

    申请人： Richard P. Beatty ,  Carina Araullo McAdams ,  Yanhui Sun ,  Thomas A. Micka

    发明人： Richard P. Beatty ,  Carina Araullo McAdams ,  Yanhui Sun ,  Thomas A. Micka

    IPC分类号： C07C35/00 ,  C05G3/00 ,  C08G18/42 ,  C08G18/10 ,  C09D175/06 ,  C05C9/00 ,  C07C31/18 ,  C08G101/00

    CPC分类号： C08G18/4222 ,  C05C9/005 ,  C05G3/0029 ,  C07C31/18 ,  C08G18/10 ,  C08G18/4286 ,  C08G2101/00 ,  C08G2105/02 ,  C09D175/06

    摘要： The invention provides polyester polyol compositions and resin blends, useful as components of polyurethane and polyisocyanurate polymers, produced from cyclohexane oxidation reaction byproducts, such as water extracts and non-volatile distillation residues from the reaction. Such byproducts of industrial processes for preparation of adipic acid and caprolactam, important intermediates in the production of various types of nylon, have hitherto largely been used only as fuels. The present invention provides value-added products, methods for making, and methods for using the byproduct-derived polyester polyol compositions. For example, the invention provides polyurethane (PU) and/or polyisocyanurate (PIR) polymers made using the polyol compositions and polyfunctional isocyanates. The PU and PIR polymers can be used as adhesives, binders (e.g., for wood fibers), coatings (e.g., for controlled release fertilizers), and foams.

    摘要翻译： 本发明提供聚酯多元醇组合物和树脂共混物，其可用作由环己烷氧化反应副产物如水提取物和来自反应的非挥发性蒸馏残余物产生的聚氨酯和聚异氰脲酸酯聚合物的组分。 用于制备己二酸和己内酰胺的工业方法的这种副产物，各种类型的尼龙的生产中的重要中间体迄今为止主要仅用作燃料。 本发明提供增值产品，制备方法和使用副产物衍生的聚酯多元醇组合物的方法。 例如，本发明提供使用多元醇组合物和多官能异氰酸酯制备的聚氨酯（PU）和/或聚异氰脲酸酯（PIR）聚合物。 PU和PIR聚合物可用作粘合剂，粘合剂（例如木纤维），涂层（例如用于控释肥料）和泡沫。

    Non-aqueous electrolyte additive for improving safety and lithium ion secondary battery comprising the same
    6.
    发明授权
    Non-aqueous electrolyte additive for improving safety and lithium ion secondary battery comprising the same 有权
    用于改进安全性的非水电解质添加剂和包含该非水电解质添加剂的锂离子二次电池

    公开(公告)号：US07901813B2

    公开(公告)日：2011-03-08

    申请号：US11651463

    申请日：2007-01-10

    申请人： Hong-Kyu Park ,  Jeh-Won Choi ,  Yeon-Hee Lee ,  Young-Tack An ,  Hyeong-Jin Kim

    发明人： Hong-Kyu Park ,  Jeh-Won Choi ,  Yeon-Hee Lee ,  Young-Tack An ,  Hyeong-Jin Kim

    IPC分类号： H01M6/16 ,  C07C33/34 ,  C07C35/00

    CPC分类号： H01M10/4235 ,  H01M4/505 ,  H01M4/525 ,  H01M4/587 ,  H01M10/0567 ,  H01M2300/0025

    摘要： The present invention relates to a non-aqueous electrolyte additive for improving safety and a lithium secondary battery comprising the same, and more particularly to a non-aqueous electrolyte additive that can improve cycle life and safety properties of a lithium ion secondary battery. According to the present invention, an organometallic compound represented by the Chemical Formula 1 is added to a non-aqueous electrolyte of a battery as an additive, and thus if a battery voltage is out of normal operation voltage range due to a short circuit and overcharge of a battery, etc., the non-aqueous electrolyte additive decomposes and a part of the decomposed additive polymerizes to form an insulating film on a cathode surface, and a part of the metal reacts with an insulating film formed on a cathode surface to improve thermal stability of the battery, thereby improving safety of the battery.

    摘要翻译： 本发明涉及一种用于提高安全性的非水电解质添加剂和包含该非水电解质添加剂的锂二次电池，更具体地说涉及一种能够改善锂离子二次电池的循环寿命和安全性能的非水电解质添加剂。 根据本发明，将由化学式1表示的有机金属化合物作为添加剂添加到电池的非水电解质中，因此如果由于短路和过充电而导致电池电压超出正常工作电压范围 的电池等，非水电解质添加剂分解，一部分分解添加剂聚合，在阴极表面形成绝缘膜，一部分金属与阴极表面形成的绝缘膜反应，从而提高 电池的热稳定性，从而提高电池的安全性。

    Fragrance composition
    7.
    发明授权
    Fragrance composition 有权
    香料组成

    公开(公告)号：US07648956B2

    公开(公告)日：2010-01-19

    申请号：US11911751

    申请日：2006-06-29

    申请人： Naotoshi Toki ,  Kosaku Ishida ,  Kazuyuki Fukuda

    发明人： Naotoshi Toki ,  Kosaku Ishida ,  Kazuyuki Fukuda

    IPC分类号： A61K8/18 ,  C07C35/00 ,  A61K8/00

    CPC分类号： C11D3/50 ,  A61K8/34 ,  A61Q13/00 ,  C07B2200/07 ,  C07C29/00 ,  C07C2602/28 ,  C11B9/0053 ,  C11B9/0076 ,  C07C35/36

    摘要： A fragrance composition containing 0.0005 to 10% by mass of a decalin alcohol as component (a) represented by formula (1a) and 90 to 99.9995% by mass of one or more polycyclic woody-amber fragrances as component (b) selected from the group consisting of 7-acetyl-1,2,3,4,5,6,7,8-octahydro-1,1,6,7-tetramethylnaphthalene, 1,2,3,4,4a,5,6,7-octahydro-2,5,5-trimethyl-2-naphthalenol, 1,2,3,4,4a,7,8,8a-octahydro-2,4a,5,8a-tetramethyl-1-naphthyl formate, 3a-ethyldodecahydro-6,6,9a-trimethylnaphtho[2,1-b]furan, and racemic or optically active dodecahydro-3a,6,6,9a-tetramethylnaphtho[2,1-b]furan; and a cosmetic product, a household product and an environmental/sanitary product containing the fragrance composition. The fragrance composition of the present invention is a highly versatile fragrance composition that brings about an odor of natural ambergris and can attain effects to enhance warmth and an odor quality even in a small amount.

    摘要翻译： 作为组分（b）的含有0.0005至10质量％的作为组分（a）的十氢化萘作为组分（1a）和90至99.9995质量％的一种或多种多环琥珀香料的香料组合物，选自组 由7-乙酰基-1,2,3,4,5,6,7,8-八氢-1,1,6,7-四甲基萘，1,2,3,4,4a，5,6,7- 八氢-2,5,5-三甲基-2-萘酚，1,2,3,4,4a，7,8,8a-八氢-2,4a，5,8a-四甲基-1-萘基甲酸酯，3a-乙基十二氢 -6,6,9a-三甲基萘并[2,1-b]呋喃，和外消旋或光学活性十二氢-3a,6,6,9a-四甲基萘并[2,1-b]呋喃; 和化妆品，家用产品和含有香料组合物的环保/卫生产品。 本发明的香料组合物是高度通用的香料组合物，其具有天然琥珀酸的气味，并且即使少量也可获得增强温度和气味质量的效果。

    Process for the preparation of alkynols
    9.
    发明授权
    Process for the preparation of alkynols 失效
    制备炔醇的方法

    公开(公告)号：US07371901B2

    公开(公告)日：2008-05-13

    申请号：US10575757

    申请日：2004-10-14

    申请人： Quirinus Bernardus Broxterman ,  Gerardus Karel Maria Verzijl

    发明人： Quirinus Bernardus Broxterman ,  Gerardus Karel Maria Verzijl

    IPC分类号： C07C27/10 ,  C07C29/10 ,  C07C35/00

    CPC分类号： C12P7/04 ,  C07C29/00 ,  C07C29/095 ,  C12P9/00 ,  C12P41/007 ,  C07C33/042

    摘要： Process for the preparation of an alkynol with formula HC≡C—CH(OH)—R2(formula 2) wherein R2 represents methyl, halomethyl or ethyl, wherein the corresponding silyl-protected alkynol ester with formula 1 wherein R1 represents H, or an optionally substituted alkyl, an optionally substituted alkenyl or an optionally substituted (hetero)aryl group, R2 is as defined above and A3Si represents a trisubstituted silyl group wherein each A independently represents an optionally substituted alkyl or an optionally substituted (hetero)aryl group, in the presence of water and at least an equivalent amount of amine functionalities is converted into the alkynol with formula 2. Preferably, the amount of water is between 0.5 and 3 equivalents calculated with respect to the amount of silyl-protected alkynol ester with formula (1).

    摘要翻译： 其中R 2代表甲基，卤代甲基或乙基的具有式HC≡C-CH（OH）-R 2（式2）的炔醇的方法，其中 相应的具有式1的甲硅烷基保护的炔醇酯，其中R 1表示H，或任选取代的烷基，任选取代的烯基或任选取代的（杂）芳基，R 2 O >如上所定义，并且A 3 Si表示三取代的甲硅烷基，其中每个A独立地表示任选取代的烷基或任选取代的（杂）芳基，在水存在下和至少相当于 胺官能团的量被转化为具有式2的炔醇。优选地，相对于式（1）的甲硅烷基保护的炔醇酯的量，水的量为0.5-3当量。

    Preparation of chlorohydrins
    10.
    发明授权
    Preparation of chlorohydrins 失效
    氯菊酯的制备

    公开(公告)号：US3845145A

    公开(公告)日：1974-10-29

    申请号：US27601572

    申请日：1972-07-28

    申请人： OLIN CORP

    发明人： WOJTOWICZ J ,  PUAR M

    IPC分类号： C01B11/04 ,  C07C29/66 ,  C07C31/34 ,  C07C35/00

    CPC分类号： C01B11/04 ,  C07C29/66 ,  C07C2601/14 ,  C07C2601/20 ,  C07C31/36 ,  C07C31/42 ,  C07C35/48

    摘要： 1. IN A PROCESS FOR PREPARING CHLOROHYDRINS BY REACTING HYPOCHLOROUS ACID WITH AN UNSATURATED ORGANIC COMPOUND HAVING FROM 2 TO ABOUT 20 CARBON ATOMS SELECTED FROM THE GROUP CONSISTING OF OLEFINS, CYCLIC OLEFINS, MONOHYDROXY SUBSTITUTED OLEFINS HALIDES TO FORM A REACTION MIXTURE CONTAINING THE RESULTING CHLOROHYDRINS AND SEPARATING SAID CHLOROOHYDRINS FROM SAID REACTION MIXTURE, THE IMPROVEMENT WHICH COMPRISES: (A) REACTING SAID UNSATURATED ORGANIC COMPOUND AT TEMPERATURES OF -25 TO +60* C., (B) WITH A SOLUTION OFF HYPOCHLOROUS ACID DISSOLVED IN AN ORGANIC SOLVENT SELECTED FROM THE GROUP CONSISTING OF, (1) LOWER ALKYL KETONES, (2) LOWER ALKYL CYANIDES, (3) LOWER ALKYL ESTERS OF LOWER ALKANOIC ACIDS, WHEREIN EACH OF SAID LOWER ALKYLS CONTAIN FROM 1 TO 5 CARBON ATOMS, (1) SAID SOLUTION OF HYPOCHLOROUS ACID BEING ESSENTIALLY FREE OF CHLORIDE IONS BEING OBTAINED BY EXTRACTING HYPOCHLOROUS ACID FROM A HYPOCHLOROUS ACID REACTION MIXTURE WITH SAID ORGANIC SOLVENT, (C) SAID SOLUTION OFF HYPOCHLOROUS ACID CONTAINING FROM ABOUT 0.5 TO 50 PERCENT BY WEIGHT OF HYPOCHLOOUS ACID, AND (D) SAID REACTION MIXTURE CONTAINING THE RESULTING CHLOROHYDRINS CONTAINING FROM 0.1 TO 25 PERCENT BY WEIGHT OF WATER.