摘要:
A polymetalloxane is described having a constituent unit represented by the following general formula (1): wherein R1, R2, R3, M a, b and m are as defined.
摘要:
A radiation-sensitive composition contains: a polymetalloxane including a structural unit represented by formula (1); a radiation-sensitive acid generator; and a solvent. In the following formula (1), M represents a germanium atom, a tin atom or a lead atom; Ar1 represents a substituted or unsubstituted aryl group having 6 to 20 ring atoms or a substituted or unsubstituted heteroaryl group having 5 to 20 ring atoms; R1 represents a monovalent organic group having 1 to 20 carbon atoms, a hydrogen atom, a halogen atom or a hydroxy group; and n is 2 or 3.
摘要:
A modified solid polyalkylaluminoxane is provided, which is capable of providing α-olefin suppressing adhesion of any polymer produced as a by-product onto the reactor wall and the stirrer, and which is capable of providing a highly active olefin oligomerization reaction catalyst. An olefin oligomerization reaction catalyst containing the modified solid polyalkylaluminoxane is also provided. The modified solid polyalkylaluminoxane for olefin oligomerization reactions contains structural units represented by general formula (a) and structural units represented by general formula (b), whose median diameter is equal to or larger than 0.1 μm and equal to or smaller than 50 μm, in which R′ in the general formula (a) represents an alkyl group having 1 to 20 carbon atoms, and R″ in the general formula (b) represents a halogenated alkoxy group having 1 to 20 carbon atoms or a halogenated aryloxy group having 6 to 20 carbon atoms.
摘要:
A method for coupling tin-containing molecules via a Sn--Sn bond is described. The invention employs dehydrocondensation to link the Sn atoms of two molecules to form tin dimers as well as novel high molecular weight organotin polymers. In a preferred embodiment, catenated tin polymers are formed from hydrostannane precursors in the presence of a suitable metal catalyst. A particularly preferred method involves coupling dialkylstannane monomers in the presence of a metallocene catalyst to form polystannanes. Preferred catalysts include electropositive metals, such as Zr and Hf. The polystannanes are photolabile, decomposing readily under room light conditions.
摘要:
CORROSION OF METAL SURFACESIN C ONTACT WITH THERMOPLASTIC POLYMER COMPOSITIONS CONTAINING HALOGENATED HYDROCARBON FLAME RETARDANTS IS SUBSTANTIALLY REDUCED BY THE ADDITION OF ORGANOTIN SALTS OF MERCAPTO-SUBSTITUTED C ARBOXYLIC ACIDS. COLOR OF THE POLYMER COMPOSITION IS IMPROVED BY THE USE OF ORGANOTIN SALTS OF OLEFINICALLY UNSATURATED DIACIDS. INCLUSION OF BOTH TYPES OF ORGANOTIN COMPOUNDS BOTH INHIBITS CORROSION AND STABILIZES POLYMER COLOR.
摘要:
This invention relates to novel compounds, oligomers, and polymers exhibiting at least one direct carbon to tin bond, at least one direct halogen to tin bond, at least one direct oxygen to tin bond, and at least one direct sulfur to tin bond, methods of preparing these novel compounds, and to polymers stabilized against the deteriorative effects of heat and light by two component compositions comprised at least in part of the novel compounds of this invention.