公开(公告)号：US06533903B2

公开(公告)日：2003-03-18

申请号：US09843509

申请日：2001-04-26

申请人： Ryan C. Hayward ,  Hak F. Poon ,  Yi Xiao ,  Dudley A. Saville ,  Ilhan A. Aksay

发明人： Ryan C. Hayward ,  Hak F. Poon ,  Yi Xiao ,  Dudley A. Saville ,  Ilhan A. Aksay

IPC分类号： C07C600

CPC分类号： C30B29/60 ,  C30B5/00 ,  C30B30/00

摘要： A method for assembling patterned crystalline arrays of colloidal particles using ultraviolet illumination of an optically-sensitive semiconducting anode while using the anode to apply an electronic field to the colloidal particles. The ultraviolet illumination increases current density, and consequently, the flow of the colloidal particles. As a result, colloidal particles can be caused to migrate from non-illuminated areas of the anode to illuminated areas of the anode. Selective illumination of the anode can also be used to permanently affix colloidal crystals to illuminated areas of the anode while not affixing them to non-illuminated areas of the anode.

摘要翻译： 一种利用光敏半导体阳极的紫外线照射来组装胶体颗粒的图案化晶体阵列的方法，同时使用阳极将电场施加到胶体颗粒。 紫外线照射增加了电流密度，从而增加了胶体颗粒的流动。 结果，可以使胶体颗粒从阳极的非照射区域迁移到阳极的照明区域。 阳极的选择性照明也可以用于将胶体晶体永久地粘贴到阳极的照明区域，而不将其粘附到阳极的非照明区域。

公开(公告)号：US06696614B2

公开(公告)日：2004-02-24

申请号：US10309145

申请日：2002-12-04

申请人： Paolo Pollesel ,  Caterina Rizzo ,  Carlo Perego ,  Renato Paludetto ,  Gastone Del Piero

发明人： Paolo Pollesel ,  Caterina Rizzo ,  Carlo Perego ,  Renato Paludetto ,  Gastone Del Piero

IPC分类号： C07C600

CPC分类号： C10G11/04 ,  B01J23/002 ,  B01J23/02 ,  B01J2523/00 ,  C01F7/164 ,  C01P2002/70 ,  B01J2523/23 ,  B01J2523/31

摘要： Catalyst for steam cracking reactions consisting of pure mayenite having the general formula: 12CaO.7Al2O3 having an X-ray diffraction spectrum as indicated in Table I, obtained with a preparation process comprising the following steps: dissolution of salts containing calcium and aluminum with water; complexing of the dissolved salts by means of polyfunctional organic hydroxyacids; drying of the solution resulting from the completing in order to obtain a solid precursor product; calcination of the solid precursor product at a temperature ranging from 1300 to 1400° C. for at least two hours.

摘要翻译： 用于蒸汽裂解反应的催化剂，其由具有以下通式的纯钙铝石组成：具有表I所示的X射线衍射光谱，其制备方法包括以下步骤：用水溶解含钙和铝的盐; 通过多官能有机羟基酸溶解的盐;干燥由完成得到的溶液以获得固体前体产物;在1300-1400℃的温度下煅烧固体前体产物至少2小时。

公开(公告)号：US06323381B1

公开(公告)日：2001-11-27

申请号：US08273933

申请日：1994-07-12

申请人： Gerald J. Nacamuli ,  Robert A. Innes ,  Arnold J. Gloyn

发明人： Gerald J. Nacamuli ,  Robert A. Innes ,  Arnold J. Gloyn

IPC分类号： C07C600

CPC分类号： C10G29/16 ,  C10G35/095

摘要： A process is set forth for reacting impure toluene to obtain benzene, toluene and a para-rich xylene stream, which are substantially free of close-boiling non-aromatics. The impure toluene comprises at least 70 wt % toluene and between about 0.2 wt % and about 5 wt % close-boiling non-aromatics. The process may also comprise aromatizing a naphtha over a non-acidic catalyst. The impure toluene from the aromatization step is passed over an acidic intermediate pore zeolite to produce a para-rich xylene stream and chemically pure benzene.

摘要翻译： 阐述了使不纯的甲苯反应以获得基本上不含近沸点非芳族化合物的苯，甲苯和富二甲苯流的方法。 不纯的甲苯包含至少70重量％的甲苯和约0.2重量％至约5重量％的接近沸腾的非芳族化合物。 该方法还可以包括在非酸性催化剂上芳构化石脑油。 来自芳构化步骤的不纯的甲苯通过酸性中间孔沸石以产生富二甲苯流和化学纯的苯。

公开(公告)号：US06593503B1

公开(公告)日：2003-07-15

申请号：US08695482

申请日：1996-08-12

申请人： An-hsiang Wu ,  Charles A. Drake ,  Ralph J. Melton

发明人： An-hsiang Wu ,  Charles A. Drake ,  Ralph J. Melton

IPC分类号： C07C600

CPC分类号： C07C6/10 ,  C07C2529/40 ,  C07C15/02

摘要： A catalyst composition and a process for converting a hydrocarbon stream such as, for example, gasoline to C6 to C8 aromatic hydrocarbons such as toluene and xylenes are disclosed. The catalyst composition includes an alumina, a silica, and a metal wherein the weight ratio of aluminum to silicon is in the range of from about 0.002:1 to about 0.6:1. The process includes contacting a hydrocarbon stream with the catalyst composition under a condition sufficient to effect the conversion of a hydrocarbon to a C6 to C8 aromatic hydrocarbon. Also disclosed is a process for producing the catalyst composition which includes: (1) contacting a zeolite with an effective amount of an acid under a condition sufficient to effect a reduction in aluminum content of the zeolite to produce an acid-leached zeolite; and (2) impregnating the acid-leached zeolite with an effective amount of a metal compound under a condition sufficient to effect the production of a metal-promoted zeolite.

摘要翻译： 公开了一种催化剂组合物和将烃流例如汽油转化为C 6至C 8芳族烃如甲苯和二甲苯的方法。 催化剂组合物包括氧化铝，二氧化硅和金属，其中铝与硅的重量比在约0.002:1至约0.6:1的范围内。 该方法包括使烃流与催化剂组合物在足以使碳氢化合物转化为C 6至C 8芳族烃的条件下接触。 还公开了一种生产催化剂组合物的方法，其包括：（1）在足以使沸石的铝含量降低以产生酸浸出的沸石的条件下使沸石与有效量的酸接触; 和（2）在足以产生金属促进的沸石的条件下，用有效量的金属化合物浸渍酸浸出的沸石。

公开(公告)号：US06437209B1

公开(公告)日：2002-08-20

申请号：US09493255

申请日：2000-01-28

申请人： Dominique Commereuc ,  Paul Mikitenko

发明人： Dominique Commereuc ,  Paul Mikitenko

IPC分类号： C07C600

CPC分类号： C07C6/04 ,  C07C2523/00 ,  C07C2523/28 ,  C07C2523/30 ,  C07C2523/36 ,  C07C2531/14 ,  C07C2531/32 ,  Y02P20/127 ,  Y02P20/582

摘要： Catalytic process for metathesis of olefins in the presence of a catalyst and a stabilizing agent that is injected into the reaction medium. Application in particular to rebalancing between one another the light olefins that are obtained from steam cracking or catalytic cracking (FCC), such as ethylene, propylene, butenes or pentenes.

摘要翻译： 在催化剂和注入反应介质的稳定剂存在下烯烃复分解的催化方法。 尤其适用于从蒸汽裂化或催化裂化（FCC）获得的轻质烯烃（如乙烯，丙烯，丁烯或戊烯）之间的平衡。

公开(公告)号：US06635152B1

公开(公告)日：2003-10-21

申请号：US09589908

申请日：2000-06-07

申请人： Paul A. Cahill ,  Richard N. Steppel

发明人： Paul A. Cahill ,  Richard N. Steppel

IPC分类号： C07C600

CPC分类号： C07C5/31 ,  C07C2603/86

摘要： The present invention relates to a process for driving a non-polymerization solution-phase photochemical transformation. A sensitizer, such as a substituted diaminobenzophenone having a solubility in norbornadiene greater than that of Michler's Ketone, may be added to norbornadiene to form a solution, wherein the sensitizer decreases the induction period at the beginning of the reaction, increases the photon or quantum efficiency of conversion of norbornadiene to quadricyclane, and increases the rate of conversion at the end of the reaction. If the solution is irradiated with light from a metal halide-doped mercury arc lamp to photochemically transform the norbornadiene to quadricyclane, the conversion is more efficient than when other light sources are utilized. Furthermore, the addition of triethylamine to the solution tends to result in the formation of fewer by-products in the transformation reaction.

摘要翻译： 本发明涉及一种驱动非聚合溶液相光化学转化的方法。 可以向降冰片二烯中加入敏化剂，例如在降冰片二烯中的溶解度大于米ler酮的敏感剂形成溶液，其中敏化剂降低反应开始时的诱导期，增加光子或量子效率 降冰片二烯转化为四环素，并且增加反应结束时的转化率。 如果用来自金属卤化物掺杂的水银弧光灯的光照射该溶液以将降冰片二烯光学化学转化为四环体，那么转换比使用其它光源时更有效。 此外，向溶液中加入三乙胺倾向于导致在转化反应中形成更少的副产物。

公开(公告)号：US06572737B2

公开(公告)日：2003-06-03

申请号：US09898965

申请日：2001-07-03

申请人： Robert C. Dalton

发明人： Robert C. Dalton

IPC分类号： C07C600

CPC分类号： B01J19/0073 ,  B01D53/32 ,  B01J19/02 ,  B01J19/12 ,  B01J2219/00141 ,  B01J2219/00146 ,  B01J2219/00155 ,  B01J2219/00159 ,  B01J2219/0204 ,  B01J2219/0209 ,  B01J2219/0218 ,  B01J2219/0236 ,  B01J2219/0268 ,  B01J2219/0286 ,  B01J2219/0854 ,  B01J2219/0875 ,  B01J2219/192 ,  C01B13/10 ,  C01B13/11 ,  Y02P20/149

摘要： A heat transfer process in which a chemical species flow is heated by heat exchange, by providing a source of applied electromagnetic energy that creates heat; directing at least a portion of the chemical species flow over the source of applied electromagnetic energy wherein the chemical species flow absorbs heat from the applied electromagnetic energy source to create a heated chemical species flow; and directing the heated chemical species flow into a device that uses applied electromagnetic energy to react gases within the chemical species flow.

公开(公告)号：US06369286B1

公开(公告)日：2002-04-09

申请号：US09517370

申请日：2000-03-02

申请人： Dennis J. O'Rear

发明人： Dennis J. O'Rear

IPC分类号： C07C600

CPC分类号： C10G2/30 ,  C10G2/332 ,  C10L1/08

摘要： A process for preparing distillate fuel compositions from a C2-6 olefinic fraction and a C20+ fraction via molecular averaging is described. The fractions can be obtained, for example, from Fischer-Tropsch reactions, and/or obtained from the distillation or other processing of crude oil. Molecular averaging converts the fractions to a product that includes a significant fraction in the C5-20 range that can be used for preparing a distillate fuel composition. The product is preferably isomerized to increase the octane value and lower the pour, cloud and smoke point. The product can also be hydrotreated and/or blended with suitable additives for use as a distillate fuel composition.

摘要翻译： 描述了通过分子平均从C2-6烯烃级分和C20 +馏分制备馏出物燃料组合物的方法。 馏分可以例如从费 - 托反应获得，和/或从原油的蒸馏或其它加工得到。 分子平均法将馏分转化成产物，其中可以用于制备馏出物燃料组合物的C5-20范围内的显着部分。 产物优选异构化以增加辛烷值并降低倾吐，云和烟点。 该产品还可以加氢处理和/或与合适的添加剂共混以用作馏出物燃料组合物。

公开(公告)号：US06740788B1

公开(公告)日：2004-05-25

申请号：US10325212

申请日：2002-12-19

申请人： Gregory F. Maher ,  David A. Hamm

发明人： Gregory F. Maher ,  David A. Hamm

IPC分类号： C07C600

CPC分类号： C10G69/08 ,  C07C6/126 ,  C10G2300/1044 ,  C10G2300/4018 ,  C10G2400/30 ,  Y02P20/125 ,  Y02P20/52 ,  C07C15/08 ,  C07C15/04 ,  C07C15/06

摘要： Enabling a transalkylation process to handle both C10 alkylaromatics and unextracted toluene permits the following improvements to be realized. No longer extracting toluene allows a reformate-splitter column to be eliminated. The extraction unit can be moved to the overhead of a benzene column. No longer requiring a rigorous split between C9 and C10 alkylaromatics allows a heavy aromatics column to be eliminated. Such an enabled transalkylation process requires stabilization of a transalkylation catalyst through the introduction of a metal function. A further enhancement to the flow scheme is accomplished through the elimination of clay treaters in favor of selective olefin saturation at the exits of a reforming unit and an isomerization unit. These improvements result in an aromatics complex with savings on inside battery limits curve costs and an improvement on the return on investment in such a complex.

摘要翻译： 实施烷基转移方法来处理C10烷基芳族化合物和未萃取的甲苯允许实现以下改进。 不再提取甲苯可以消除重整分离柱。 提取单元可以移动到苯塔的塔顶。 不再需要C9和C10烷基芳族化合物之间的严格拆分，可以消除重芳烃柱。 这种使能的烷基转移方法需要通过引入金属官能团来稳定烷基转移催化剂。 通过消除粘土处理剂有利于重整单元和异构化单元的出口处的选择性烯烃饱和来实现流程图的进一步改进。 这些改进导致了芳烃复合物，节省了内部电池限制曲线成本，并改善了这种复杂的投资回报。

公开(公告)号：US06706154B1

公开(公告)日：2004-03-16

申请号：US09975117

申请日：2001-10-10

申请人： Wei Yang ,  Li Chen

发明人： Wei Yang ,  Li Chen

IPC分类号： C07C600

CPC分类号： C03C23/002 ,  G02B6/12011 ,  G02B6/12014 ,  G02B6/13 ,  G02B2006/121 ,  G02B2006/12147 ,  G02B2006/1215

摘要： A process for forming an integrated optical device in a substrate, comprising the steps of: providing a substrate having a base index of refraction; providing a UV light beam; focusing the beam on a portion of the substrate in order to form a region of increased refraction; and scanning an elongated region of the glass substrate with the beam in order to define at least one elongated optical channel having an increased index of refraction relative to the base index of refraction, the elongated optical channel for guiding light transmitted there along. The process further includes: forming a plurality of elongated optical channels in the substrate, wherein a first optical channel is operative for transmitting light to the plurality of elongated optical channels such that the transmitted light is divided among the plurality of elongated optical channels, thereby forming an optical beamsplitter.

摘要翻译： 一种在衬底中形成集成光学器件的方法，包括以下步骤：提供具有基准折射率的衬底; 提供UV光束; 将光束聚焦在衬底的一部分上以形成增加折射的区域; 以及用所述光束扫描所述玻璃基板的细长区域，以便限定出相对于所述基本折射率具有增加的折射率的至少一个细长光学通道，所述细长光学通道用于引导沿其传播的光。 该方法还包括：在衬底中形成多个细长光学通道，其中第一光学通道用于将光传输到多个细长光学通道，使得透射光在多个细长光学通道之间被分割，由此形成 光分路器。